Abstract:
The present invention relates to a catalyst for the oxidation of ammonia (AMOX catalyst), wherein the catalyst comprises as components: (a) Pt and/or Pd as one or more platinum group metals, wherein the one or more platinum group metals are supported on a support material; (b) one or more rare earth metal oxides selected from the group of oxides of Pr, Nd, and Ce, including combinations of two or more thereof; (c) one or more transition metal oxides selected from the group consisting of oxides of Mn, Ti, V, Nb, and Ta, including combinations of two or more thereof; (d) one or more zeolitic materials; and (e) optionally one or more binders; wherein the one or more zeolitic materials are loaded with Cu and/or Fe. The present invention also relates to an exhaust gas treatment system comprising the inventive catalyst for the oxidation of ammonia, as well as to a process for the preparation of a catalyst for the oxidation of ammonia, and to the use of the inventive catalyst.
Abstract:
The present invention relates to an exhaust gas treatment system for reducing ammonia emission from a gasoline engine comprising a three-way conversion catalyst (TWC) or a four-way conversion catalyst (FWC), further comprising an ammonia oxidation catalyst (AMOx) or a selective catalytic reduction catalyst (SCR), and a method of treating exhaust gas from a gasoline engine with an exhaust gas treatment system capable of removing ammonia.
Abstract:
A lean NOx trap for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO), and the trapping and reduction of nitrogen oxides (NOx) is disclosed. Nitrogen oxide storage catalysts can comprise a layer on a substrate including ceria-alumina particles having a ceria phase present in a weight percent of the composite in the range of about 20% to about 80% on an oxide basis, an alkaline earth metal component supported on the ceria-alumina particles, wherein the CeO2 is present in the form of crystallites that are hydrothermally stable and have an average crystallite size less than 130 Å after aging at 950° C. for 5 hours in 2% O2 and 10% steam in N2.
Abstract:
Described are catalyst compositions, catalytic articles, methods of manufacturing catalytic articles and exhaust gas treatment systems and methods that utilize the catalytic articles. The catalytic articles include a washcoat of platinum group metal on refractory oxide support particles, and further including a molecular sieve wherein greater than 90% of the molecular sieve particles have a particle size greater than 1 μm.
Abstract:
The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.
Abstract:
The present invention relates to a selective catalytic reduction catalyst for the treatment of an exhaust gas of a diesel engine comprising: a flow-through substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the flow through substrate extending therethrough; a coating disposed on the surface of the internal walls of the substrate, wherein the coating comprises a non-zeolitic oxidic material comprising manganese and one or more of the metals of the groups 4 to 11 and 13 of the periodic table, and further comprises one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron.
Abstract:
A catalyzed soot filter, in particular for the treatment of Diesel engine exhaust, comprises a coating design which ensures soot particulates filtration, assists the oxidation of carbon monoxide (CO), and produces low H2S emissions during normal engine operations and regeneration events.
Abstract:
A lean NOx trap composition for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO), and the trapping and reduction of nitrogen oxides (NOx) is disclosed. The lean NOx trap composition can have a washcoat layer on a carrier substrate including a first support material comprising greater than 50% by weight of a reducible metal oxide; 10 to 30% by weight of alkaline earth metal supported on a second support material comprising a refractory metal oxide and 50% or less by weight of a reducible metal oxide and; and a platinum group metal component supported on at least one of the first support material and/or the second support material. A portion of the first support material may further include 0.5% to 10% by weight of an alkaline earth metal.
Abstract:
A catalyzed soot filter, in particular for the treatment of Diesel engine exhaust, comprises a coating design which ensures soot particulates filtration, assists the oxidation of carbon monoxide (CO), and produces low H2S emissions during normal engine operations and regeneration events.
Abstract:
Described are catalyst compositions, catalytic articles, methods of manufacturing catalytic articles and exhaust gas treatment systems and methods that utilize the catalytic articles. The catalytic articles include a washcoat of platinum group metal on refractory oxide support particles, and further including a molecular sieve wherein greater than 90% of the molecular sieve particles have a particle size greater than 1 μm.