公开(公告)号：US20130084222A1

公开(公告)日：2013-04-04

申请号：US13624524

申请日：2012-09-21

Applicant: BASF SE ,  BASF Corporation

Inventor： Gerd Grubert ,  Torsten Neubauer ,  Alfred Punke ,  Marcus Hilgendorff ,  Torsten Müller-Stach ,  Olga Gerlach ,  Xinyi Wei ,  Jeffrey Hoke ,  Shiang Sung ,  Stanley Roth

IPC: B01J29/04 ,  B01D53/94 ,  B01J23/63

CPC classification number: B01J29/04 ,  B01D53/944 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/9025 ,  B01D2258/012 ,  B01J23/63 ,  B01J29/7007 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0244 ,  B01J37/0246 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/48 ,  B01J2523/49 ,  B01J2523/31 ,  B01J2523/824 ,  B01J2523/828

Abstract: The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.

Abstract translation: 本发明涉及层状柴油氧化催化剂（DOC），其包括：a）载体基材; b）一种柴油氧化催化材料，其包含：b1）位于所述载体基底上的第一层，所述第一层包含浸渍在载体材料上的钯，所述载体材料包含基于载体材料总重量至少45重量％的二氧化铈 ，并且任选地包含铂; b2）位于所述第一层上的第二层，所述第二层包含钯和铂，各自浸渍在包含金属氧化物的载体材料上; 其中第一层的铂与钯的重量比低于第二层的铂与钯的重量比。

公开(公告)号：US11713705B2

公开(公告)日：2023-08-01

申请号：US17483135

申请日：2021-09-23

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: B01J23/10 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/63 ,  B01J33/00 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  F01N3/08 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28 ,  B01D53/94 ,  B01J23/42 ,  B01J35/02

CPC classification number: F01N3/2066 ,  B01D53/9427 ,  B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/63 ,  B01J33/00 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J37/08 ,  B01J37/082 ,  B01J37/088 ,  F01N3/0842 ,  F01N3/101 ,  F01N3/2839 ,  B01D53/945 ,  B01D53/9468 ,  B01D53/9472 ,  B01D2255/1025 ,  B01D2255/2065 ,  B01D2255/9022 ,  B01D2255/9032 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01D2257/402 ,  B01J35/006 ,  B01J35/023 ,  B01J2523/00 ,  Y02C20/10 ,  Y02T10/12 ,  B01J2523/00 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3737 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/375 ,  B01J2523/822

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US20220010714A1

公开(公告)日：2022-01-13

申请号：US17483135

申请日：2021-09-23

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: F01N3/20 ,  B01J37/02 ,  B01J35/00 ,  B01J23/10 ,  B01D53/94 ,  B01J35/10 ,  B01J23/46 ,  B01J23/52 ,  B01J23/63 ,  B01J23/42 ,  B01J23/44 ,  B01J33/00 ,  B01J35/04 ,  B01J37/08 ,  F01N3/08 ,  F01N3/10 ,  F01N3/28

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US11149610B2

公开(公告)日：2021-10-19

申请号：US16838751

申请日：2020-04-02

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: B01J23/10 ,  B01J23/46 ,  B01J23/63 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  F01N3/08 ,  F01N3/20 ,  B01D53/94 ,  B01J23/52 ,  B01J23/42 ,  B01J23/44 ,  B01J33/00 ,  F01N3/10 ,  F01N3/28 ,  B01J35/02

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US10857521B2

公开(公告)日：2020-12-08

申请号：US15548657

申请日：2016-02-08

Applicant: BASF Corporation

Inventor： Shiang Sung ,  Patrick William McCanty ,  Stanley A. Roth ,  Xiaolai Zheng ,  Olga Gerlach ,  Markus Kögel

IPC: B01D53/94 ,  B01J23/656 ,  B01J37/02 ,  B01J37/20 ,  B01J23/63 ,  B01J35/04 ,  B01J29/18 ,  B01J29/74 ,  B01J29/44 ,  B01J29/69 ,  B01J29/068 ,  B01J29/40 ,  B01J29/70 ,  B01J29/08 ,  B01J29/06 ,  B01J29/076 ,  B01J29/26 ,  B01J29/67 ,  B01J29/22 ,  B01J37/10 ,  B01J29/16 ,  B01J29/12 ,  B01J29/48 ,  B01J29/78 ,  B01J23/00 ,  B01J29/65 ,  B01J35/00 ,  B01J37/08 ,  F01N3/10 ,  F01N3/20

Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, described is an oxidation catalyst composite including a first oxidation component comprising a first refractory metal oxide support, palladium (Pd) and platinum (Pt); a NOx storage component comprising one or more of alumina, silica, titania, ceria, or manganese; and a second oxidation component comprising a second refractory metal oxide, a zeolite, and Pt. The oxidation catalyst composite is sulfur tolerant, adsorbs NOx and thermally releases the stored NOx at temperature less than 350° C.

公开(公告)号：US20200232366A1

公开(公告)日：2020-07-23

申请号：US16838751

申请日：2020-04-02

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: F01N3/20 ,  B01J37/02 ,  B01J23/63 ,  B01J23/52 ,  B01J23/46 ,  F01N3/28 ,  F01N3/10 ,  F01N3/08 ,  B01J37/08 ,  B01J35/04 ,  B01J33/00 ,  B01J23/44 ,  B01J23/42 ,  B01J35/10 ,  B01D53/94 ,  B01J23/10 ,  B01J35/00

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US10335776B2

公开(公告)日：2019-07-02

申请号：US14107704

申请日：2013-12-16

Applicant: BASF Corporation

Inventor： Shiang Sung ,  Stanley A. Roth ,  Claudia Zabel ,  Susanne Stiebels ,  Andreas Sundermann ,  Olga Gerlach

IPC: B01D53/94 ,  B01J29/076 ,  B01J37/02 ,  B01J35/00 ,  B01J23/40 ,  B01J23/656

Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat layer comprising a Pt component and a Pd component, and a second washcoat layer including a refractory metal oxide support containing manganese, a zeolite, and a platinum component is described.

公开(公告)号：US09044734B2

公开(公告)日：2015-06-02

申请号：US13624524

申请日：2012-09-21

Applicant: BASF SE ,  BASF Corporation

Inventor： Gerd Grubert ,  Torsten Neubauer ,  Alfred Punke ,  Marcus Hilgendorff ,  Torsten Müller-Stach ,  Olga Gerlach ,  Xinyi Wei ,  Jeffrey Hoke ,  Shiang Sung ,  Stanley Roth

IPC: B01J23/63 ,  B01D53/94 ,  B01J29/04 ,  B01J37/02 ,  B01J29/70 ,  B01J35/04 ,  B01J35/02 ,  B01J37/00

CPC classification number: B01J29/04 ,  B01D53/944 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/9025 ,  B01D2258/012 ,  B01J23/63 ,  B01J29/7007 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0244 ,  B01J37/0246 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/48 ,  B01J2523/49 ,  B01J2523/31 ,  B01J2523/824 ,  B01J2523/828

Abstract: The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.

Abstract translation: 本发明涉及层状柴油氧化催化剂（DOC），其包括：a）载体基材; b）一种柴油氧化催化材料，其包含：b1）位于所述载体基底上的第一层，所述第一层包含浸渍在载体材料上的钯，所述载体材料包含基于载体材料总重量至少45重量％的二氧化铈 ，并且任选地包含铂; b2）位于所述第一层上的第二层，所述第二层包含钯和铂，各自浸渍在包含金属氧化物的载体材料上; 其中第一层的铂与钯的重量比低于第二层的铂与钯的重量比。

公开(公告)号：US20140271427A1

公开(公告)日：2014-09-18

申请号：US14203862

申请日：2014-03-11

Applicant: BASF Corporation

Inventor： Jeffrey B. Hoke ,  Olga Gerlach ,  Andreas Sundermann

IPC: B01J23/63 ,  B01D53/94

CPC classification number: B01J23/63 ,  B01D53/9413 ,  B01D53/9427 ,  B01D53/9459 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/102 ,  B01D2255/2065 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2523/00 ,  Y02T10/24 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/22 ,  B01J2523/25 ,  B01J2523/41

Abstract: A catalyst material for the oxidation of NO comprising a catalyst carrier including a ceria-alumina support having platinum and optionally palladium dispersed on the support is described. When palladium is present, the ratio of platinum to palladium by weight is at least 1:1. The amount of ceria in the support is in the range of 1% to 12% by weight. The catalyst material is useful for methods and systems of abating pollutants from automotive exhaust gas from lean burn engines.

Abstract translation: 描述了用于氧化NO的催化剂材料，其包含催化剂载体，其包含具有铂的二氧化铈 - 氧化铝载体和任选的钯分散在载体上。 当钯存在时，铂与钯的重量比至少为1:1。 载体中二氧化铈的量在1重量％至12重量％的范围内。 催化剂材料可用于减轻来自稀燃燃烧发动机的汽车尾气污染物的方法和系统。