公开(公告)号：US20170326536A1

公开(公告)日：2017-11-16

申请号：US15458437

申请日：2017-03-14

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Inventor： Abiola Azeez JIMOH ,  Abdul Malik Peedikakkal

IPC: B01J31/12 ,  C07F3/06 ,  C07F1/08 ,  C07C51/285 ,  C07C45/29 ,  C07C27/16 ,  B01J35/10 ,  C07F15/02

CPC classification number: B01J31/123 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1057 ,  B01J35/1061 ,  C07C27/16 ,  C07C29/48 ,  C07C45/28 ,  C07C45/294 ,  C07C51/285 ,  C07C2101/14 ,  C07C2601/14 ,  C07F1/08 ,  C07F3/06 ,  C07F15/025 ,  C07C35/08 ,  C07C49/403 ,  C07C47/54 ,  C07C63/06

Abstract: A metal organic framework comprising zinc (II) ions and second metal ions, such as iron (II) ions, cobalt (II) ions, and copper (II) ions as nodes or clusters and coordinated 1,3,5-benzenetricarboxylic acid struts or linkers between them forming a porous coordination network in the form of polyhedral crystals that are isostructural to HKUST-1. Transmetallation processes for producing the metal organic frameworks, as well as methods for applications of the metal organic frameworks as catalysts, specifically catalysts for the oxidation of cyclic hydrocarbons, such as toluene, cyclohexane, and methylcyclohexane.

公开(公告)号：US20170282166A1

公开(公告)日：2017-10-05

申请号：US15086832

申请日：2016-03-31

Applicant: FORD GLOBAL TECHNOLOGIES, LLC

Inventor： JASON AARON LUPESCU ,  GIOVANNI CAVATAIO

IPC: B01J29/70 ,  B01J29/08 ,  B01J29/068 ,  B01D53/94 ,  B01J29/80 ,  B01J20/18 ,  B01J20/28 ,  B01J29/65 ,  B01J35/10

CPC classification number: B01J29/7015 ,  B01D53/945 ,  B01D53/9486 ,  B01D2255/50 ,  B01D2255/9022 ,  B01D2255/9025 ,  B01D2255/904 ,  B01D2255/912 ,  B01D2255/9202 ,  B01J20/18 ,  B01J20/2808 ,  B01J29/068 ,  B01J29/084 ,  B01J29/106 ,  B01J29/126 ,  B01J29/146 ,  B01J29/166 ,  B01J29/44 ,  B01J29/46 ,  B01J29/65 ,  B01J29/67 ,  B01J29/68 ,  B01J29/69 ,  B01J29/723 ,  B01J29/7415 ,  B01J29/743 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/783 ,  B01J29/80 ,  B01J29/88 ,  B01J35/1057 ,  Y02T10/22

Abstract: Hydrocarbon (HC) traps are disclosed. The HC trap may include a first zeolite material having an average pore diameter of at least 5.0 angstroms and configured to trap hydrocarbons from an exhaust stream and to release at least a portion of the trapped hydrocarbons at a temperature of at least 225° C. The HC trap may also include a second zeolite material having an average pore diameter of less than 5.0 angstroms or larger than 7.0 angstroms. One or both of the zeolite materials may include metal ions, such as transition, Group 1A, or platinum group metals. The HC trap may include two or more discrete layers of zeolite materials or the two or more zeolite materials may be mixed. The multiple zeolite HC trap may form coke molecules having a relatively low combustion temperature, such as below 500° C.

公开(公告)号：US09718049B2

公开(公告)日：2017-08-01

申请号：US14587608

申请日：2014-12-31

Applicant: Alexander Katz ,  Isao Ogino ,  Stacey Ian Zones

Inventor： Alexander Katz ,  Isao Ogino ,  Stacey Ian Zones

IPC: C01B39/02 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48 ,  B01J29/70 ,  B01J29/65 ,  B01J29/04 ,  B01J37/00 ,  B01J37/34 ,  B01J29/86 ,  B01J35/00 ,  B01J35/10

CPC classification number: B01J29/7038 ,  B01J29/041 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7088 ,  B01J29/86 ,  B01J35/002 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/0072 ,  B01J37/343 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/38 ,  C01B39/026 ,  C01B39/38 ,  C01B39/40 ,  C01B39/46 ,  C01B39/48

Abstract: The present invention is directed to the synthesis of novel delaminated layered zeolite precursor materials prepared by fluoride/chloride anion-promoted exfoliation. The method comprises, for example, using a combination of fluoride and chloride anions at a mild pH in aqueous solution to affect delamination of a layered zeolite precursor. The method can also comprise using a combination of fluoride and chloride anions in a non-aqueous solution comprising an organic solvent. The method may be used in conjunction with either acidification or sonication, or both. The resulting delaminated zeolite precursors are then isolated. Precursors that are then isolated lack amorphous silica content. The UCB-1 product is an example of such a novel oxide material and is obtained in yields in excess of 90% without the need for sonication.

公开(公告)号：US20170165655A1

公开(公告)日：2017-06-15

申请号：US15296301

申请日：2016-10-18

Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH

Inventor： Anil Kumar SINHA ,  Mohit ANAND ,  Saleem Akthar FAROOQUI ,  Rakesh KUMAR ,  Rakesh Kumar JOSHI ,  Rohit KUMAR ,  Tasleem KHAN ,  Parvez ALAM ,  Gopalan Sibi MALAYIL

IPC: B01J29/78 ,  B01J37/04 ,  B01J37/00 ,  C10G3/00 ,  B01J37/18 ,  B01J37/08 ,  B01J37/02 ,  B01J37/20 ,  B01J29/74 ,  B01J37/06

CPC classification number: C10G3/50 ,  B01J29/044 ,  B01J29/045 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/74 ,  B01J29/78 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/026 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/036 ,  B01J37/08 ,  B01J37/18 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/62 ,  C10G3/49 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  Y02P30/20

Abstract: A novel pt/pd sodalite caged catalyst combination with sulfided base metal catalyst for improved catalytic hydroprocessing of renewable feedstock. Particularly, the invention relates to a process for preparation of the said catalyst. More particularly, the invention relates to a process for the preparation of hydrocarbon fuel from the feed stock using a said catalyst. Further, the invention discloses a novel catalyst and a process for the preparation of the Pt/Pd encapsulated in sodalite cage with silica-alumina ZSM-5 synthesized around it supported with nickel, molybdenum, cobalt, tungsten or one or more thereof. The invention also provides process to convert vegetable oils, free fatty acids, and microbial lipids, bio-crude and conventional non-renewable crude based feed stocks such as diesel, naphtha, kerosene, gas oil, residue, etc., into gasoline, aviation, diesel, fuel and other hydrocarbons fuel with reduced coke formation and hydrogen generation due to formation of napthenes and aromatics using the novel catalyst.

公开(公告)号：US09610575B2

公开(公告)日：2017-04-04

申请号：US13880034

申请日：2012-08-16

Applicant: Shigeru Fujino

Inventor： Shigeru Fujino

IPC: C03B19/06 ,  B01J31/26 ,  B01J35/10 ,  B01J23/06 ,  B01J23/40 ,  B01J23/48 ,  B01J23/72 ,  B01J37/08 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J31/26 ,  B01J23/06 ,  B01J23/40 ,  B01J23/48 ,  B01J23/72 ,  B01J35/10 ,  B01J35/1052 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/08 ,  C03B19/066

Abstract: Some embodiments in the present disclosure generally relate to catalytic silica-polyvinyl alcohol composites, silica structures therefrom, and/or microreactors therefrom. Some embodiments in the present disclosure generally relate to porous substrates that can have at least one pore with a catalyst associated with the inside of the pore.

公开(公告)号：US09579637B2

公开(公告)日：2017-02-28

申请号：US13924462

申请日：2013-06-21

Applicant: Dalian Institute of Chemical Physics, Chinese Academy of Sciences

Inventor： Lei Xu ,  Peng Tian ,  Zhongmin Liu ,  Lixin Yang ,  Shuanghe Meng ,  Changqing He ,  Cuiyu Yuan ,  Yue Qi

IPC: B01J29/06 ,  B01J27/182 ,  B01J29/85 ,  B01J29/04 ,  C01B39/04 ,  C01B39/10 ,  C01B39/54 ,  B01J37/00 ,  C01B37/08 ,  C07C1/20 ,  C10G3/00 ,  B01J35/10

CPC classification number: B01J29/85 ,  B01J29/041 ,  B01J35/10 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0018 ,  C01B37/08 ,  C01B39/04 ,  C01B39/10 ,  C01B39/54 ,  C07C1/20 ,  C10G3/49 ,  C10G2400/20 ,  Y02P30/20 ,  C07C11/02

Abstract: The present invention relates to a SAPO-34 molecular sieve having both micropores and mesopores and synthesis method thereof. The mesopore diameter in the molecular sieve is in a range of 2-10 nm and the mesopore volume thereof is 0.03-0.3 cm3/g. Triethylamine is used as a template agent and the pore size modifiers are added to the synthesis gel at the same time in the synthesis process, thereby the prepared molecular sieve crystals have mesopore distribution besides micropores. The SAPO-34 molecular sieve synthesized in the present invention can be used as catalysts for conversion of oxygen-containing compounds to lower olefins.

Abstract translation: 本发明涉及具有微孔和介孔的SAPO-34分子筛及其合成方法。 分子筛中的中孔直径在2-10nm的范围内，中孔体积为0.03-0.3cm 3 / g。 使用三乙胺作为模板剂，并且在合成过程中同时将孔径调节剂加入到合成凝胶中，由此制备的分子筛晶体除微孔外还具有中孔分布。 本发明中合成的SAPO-34分子筛可用作将含氧化合物转化为低级烯烃的催化剂。

公开(公告)号：US20160310929A1

公开(公告)日：2016-10-27

申请号：US15137338

申请日：2016-04-25

Applicant: Georgia Tech Research Corporation

Inventor： Michael Charles Mangarella ,  Krista S. Walton

IPC: B01J20/20 ,  B01J21/18 ,  B01J35/10 ,  B01J37/02 ,  B01J20/30 ,  B01J37/18 ,  B01J20/06 ,  B01J20/02 ,  B01J20/28 ,  B01J20/32 ,  B01J23/745 ,  B01J37/24

CPC classification number: B01J20/20 ,  B01J20/02 ,  B01J20/06 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28071 ,  B01J20/3085 ,  B01J20/3204 ,  B01J20/3236 ,  B01J21/18 ,  B01J21/185 ,  B01J23/28 ,  B01J23/74 ,  B01J23/745 ,  B01J27/128 ,  B01J27/132 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/18 ,  B01J37/24

Abstract: Carbide-derived carbons are provided that have high dynamic loading capacity for high vapor pressure gasses such as H2S, SO2, or NH3. The carbide-derived carbons can have a plurality of metal chloride or metallic nanoparticles entrapped therein. Carbide-derived carbons are provided by extracting a metal from a metal carbide by chlorination of the metal carbide to produce a porous carbon framework having residual metal chloride nanoparticles incorporated therein, and annealing the porous carbon framework with H2 to remove residual chloride by reducing the metal chloride nanoparticles to produce the metallic nanoparticles entrapped within the porous carbon framework. The metals can include Fe, Co, Mo, or a combination thereof. The carbide-derived carbons are provided with an ammonia dynamic loading capacity of 6.9 mmol g−1 to 10 mmol g−1 at a relative humidity of 0% RH to 75% RH.

Abstract translation: 提供碳化物衍生的碳，其对于高蒸汽压气体如H 2 S，SO 2或NH 3具有高动态负载能力。 碳化物衍生的碳可以含有多个金属氯化物或金属纳米粒子。 通过将金属碳化物进行氯化从金属碳化物中提取金属以制备其中含有残余金属氯化物纳米颗粒的多孔碳骨架，并用H 2还原多孔碳骨架以通过还原金属来除去残留的氯化物来提供硬质合金衍生的碳 氯化物纳米颗粒，以产生包埋在多孔碳框架内的金属纳米颗粒。 金属可以包括Fe，Co，Mo或它们的组合。 在0％RH至75％RH的相对湿度下，碳化物衍生的碳具有6.9mmol g-1至10mmol g-1的氨动态负载能力。

公开(公告)号：US09376636B2

公开(公告)日：2016-06-28

申请号：US13995800

申请日：2011-12-15

Applicant: Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

Inventor： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC: C10G45/04 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  C10G45/10 ,  B01J29/03 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  C10G45/06 ,  B01J27/195 ,  B01J27/198

CPC classification number: C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

Abstract: A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.

Abstract translation: 至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属 式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数 从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是 整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。

公开(公告)号：US20160122258A1

公开(公告)日：2016-05-05

申请号：US14919591

申请日：2015-10-21

Applicant: Chevron U.S.A. Inc.

Inventor： Bi-Zeng Zhan ,  Stacey Ian Zones ,  Christopher M. Lew

IPC: C07C2/12 ,  C07C2/24

CPC classification number: C07C2/12 ,  B01J29/70 ,  B01J29/74 ,  B01J29/86 ,  B01J29/90 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/343 ,  B01J38/10 ,  B01J2229/186 ,  B01J2229/22 ,  B01J2229/34 ,  B01J2229/37 ,  B01J2229/42 ,  C07C2529/70 ,  C07C2529/74 ,  C10G50/00

Abstract: Provided is an improved process for olefin oligomerization allowing one to realize superior selectivity. The process comprises contacting a hydrocarbon feed comprised of straight and branched chain olefins under oligomerization conditions with a catalyst comprising delaminated SSZ-70. The delaminated SSZ-70 offers a zeolite layer with a single unit cell of thickness in one dimension, allowing for elimination of mass transfer in comparison with regular SSZ-70. The result is superior selectivity.

Abstract translation: 提供了一种改进的烯烃低聚方法，可以实现优异的选择性。 该方法包括在低聚条件下将由直链和支链烯烃组成的烃进料与包含脱层SSZ-70的催化剂接触。 分层SSZ-70在一个维度上提供了具有单个单元电池厚度的沸石层，与常规SSZ-70相比，可以消除传质。 结果是优异的选择性。

公开(公告)号：US09328035B1

公开(公告)日：2016-05-03

申请号：US14139629

申请日：2013-12-23

Applicant: John N. Kuhn ,  Babu Joseph

Inventor： John N. Kuhn ,  Babu Joseph

IPC: C07C1/04 ,  C10G2/00

CPC classification number: C07C1/043 ,  B01J23/83 ,  B01J35/1057 ,  B01J2523/00 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/062 ,  C01B2203/10 ,  C01B2203/1011 ,  C01B2203/82 ,  C10G2/33 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/847

Abstract: In one embodiment, liquid hydrocarbon fuels are produced in a single reactor using a hybrid catalyst system including a reforming catalyst, a Fischer-Tropsch synthesis (FTS) catalyst, and a porous material that spatially separates the reforming catalyst from the FTS catalyst.

Abstract translation: 在一个实施方案中，使用包括重整催化剂，费 - 托合成（FTS）催化剂和在空间上将重整催化剂与FTS催化剂分离的多孔材料的混合催化剂体系在单个反应器中制备液体烃燃料。