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    Gasoline additives and gasoline containing soluble platinum group metal compounds and use in internal combustion engines
    38.
    发明授权
    Gasoline additives and gasoline containing soluble platinum group metal compounds and use in internal combustion engines 失效
    含有可溶性铂族金属化合物的汽油添加剂和汽油，用于内燃机

    公开(公告)号：US4891050A

    公开(公告)日：1990-01-02

    申请号：US897869

    申请日：1986-08-19

    Applicant: Wayne E. Bowers ,  Barry N. Sprague

    Inventor： Wayne E. Bowers ,  Barry N. Sprague

    IPC: C07F15/00 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/22 ,  C10L1/30 ,  C10L3/00 ,  C10L10/02

    CPC classification number: C10L1/14 ,  C07F15/0086 ,  C10L1/1814 ,  C10L1/301 ,  C10L1/305 ,  C10L10/02 ,  C10L3/003 ,  C10L1/1608 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/1855 ,  C10L1/1857 ,  C10L1/231

    Abstract: The invention provides gasoline additive compositions comprising solutions of at least one fuel-soluble platinum group metal compound in a solvent miscible in the gasoline, the platinum group metal complex being present in an amount sufficient to supply from 0.01 to 1.0 parts per million of the platinum group metal when added to a predetermined amount of gasoline.Preferred solvents are oxygenated hydrocarbons such as ethanol, tetrahydrofuran, and methyl tertiary butyl ether, and will preferably be employed in amounts of less than 5% of the weight of the gasoline to provide oxygen and the metal at a weight ratio of from 1,000:1 to 100,000:1. Especially preferred compounds are those of the formula:X M.sup.II R.sub.2wherein X is a cyclooctadienyl ligand; M is a platinum group metal; and R is benzyl, phenyl or nitrobenzyl.The additive compositions and fuel treated therewith improve operating efficiency of internal combustion engines in terms of increased power output per unit of fuel burned and reduce the emissions of particulates and noxious gases such as carbon monoxide and nitrogen monoxide. The additives provide beneficial results upon immediate use and over long periods of continuous use.

    Abstract translation: 本发明提供了汽油添加剂组合物，其包含至少一种可溶于燃料的铂族金属化合物在可与汽油混合的溶剂中的溶液，铂族金属络合物的存在量足以提供0.01至1.0ppm的铂 当添加到预定量的汽油时，将金属组合。 优选的溶剂是含氧烃如乙醇，四氢呋喃和甲基叔丁基醚，并且优选以低于汽油重量的5％的量使用以提供氧和重量比为1,000:1的金属 至100,000：1。 特别优选的化合物是下式的化合物：X MII R2其中X是环辛二烯基配体; M是铂族金属; R为苄基，苯基或硝基苄基。 添加剂组合物和经过处理的燃料可以提高内燃机的运行效率，从而提高每单位燃料燃料的功率输出，并减少颗粒物和有毒气体如一氧化碳和一氧化氮的排放。 这些添加剂在立即使用和长时间连续使用时提供有益的结果。

    Cetane number
    39.
    发明授权
    Cetane number 失效
    十六烷值

    公开(公告)号：US4738686A

    公开(公告)日：1988-04-19

    申请号：US944770

    申请日：1986-12-22

    Applicant: Diane M. Dillon ,  Peter J. Jessup

    Inventor： Diane M. Dillon ,  Peter J. Jessup

    IPC: C10L1/18

    CPC classification number: C10L1/1855

    Abstract: Hydrocarbon fuels with an improved cetane number are obtained by blending a liquid fuel with a cyclic ether compound. Cyclic ethers are compounds which have a ring structure of carbon and a minor number of oxygen atoms, including beta-lactones and adducts of the beta-lactones with aldehydes or ketones.

    Abstract translation: 具有改善的十六烷值的烃燃料通过混合液体燃料与环醚化合物而获得。 环醚是具有碳和少量氧原子的环结构的化合物，包括β-内酯和β-内酯与醛或酮的加合物。

    Preparation of improved motor fuels containing furan antiknocks
    40.
    发明授权
    Preparation of improved motor fuels containing furan antiknocks 失效
    制备含有呋喃抗爆剂的改进的机动燃料

    公开(公告)号：US3909216A

    公开(公告)日：1975-09-30

    申请号：US27186072

    申请日：1972-07-14

    Applicant: SUN VENTURES INC

    Inventor： STEARNS RICHARD S ,  THOMPSON ROBERT M

    IPC: C07C409/04 ,  C07D307/06 ,  C10L1/02 ,  C10L1/14

    CPC classification number: C10L1/1855 ,  C07C407/00 ,  C07C409/04 ,  C07D307/06 ,  C10L1/023

    Abstract: The octane rating of gasoline alkylate may be improved by separating therefrom 2,4- and 2,5-dimethylhexanes (''''DMH'''') and subjecting said DMH to the following combination of steps: (1) oxidizing the DMH to form the corresponding hydroperoxides; (2) reacting of the hydroperoxides with propylene to yield the corresponding diols plus propylene oxide; and (3) dehydrating of the diols to produce 2,2,5,5-tetramethyltetrahydrofuran (''''TMTHF''''), which product is then added to the gasoline alkylate, thereby improving its octane rating. In addition, valuable propylene oxide is recovered as a by-product.

    Abstract translation: 汽油烷基化物的辛烷值可以通过与2,4-和2,5-二甲基己烷（“DMH”）分离并使所述DMH进行以下步骤组合来改善：（1）氧化DMH以形成相应的氢过氧化物; （2）氢过氧化物与丙烯的反应，得到相应的二醇和环氧丙烷; 和（3）二醇脱水以产生2,2,5,5-四甲基四氢呋喃（“TMTHF”），然后将该产物加入到烷基化汽油中，从而提高其辛烷值。 此外，作为副产物回收有价值的环氧丙烷。

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