Abstract:
The reaction product of (i) an oligomer formed from one monomer or two or more different monomers, the or each monomer being an ethylenically unsaturated compound and said oligomer or each of said monomers being optionally partially or fully esterified, with (ii) a polyalkenyl derivative of an ethylenically unsaturated carboxylic reagent (iii), and (iv) a polyamine containing at least two --NH.sub.2 and/or --NH groups, wherein at least one of the ethylenically unsaturated compounds of the oligomer has a functional group which can react with an amine; and the use of the reaction product for its dispercency and low haze properties in lubricant compositions, fuel compositions and additive concentrates.
Abstract:
A method of inhibiting or retarding formation of hydrates from water and a lower alkane, such as methane or ethane, involves adding additives which comprise (i) a corrosion inhibitor and (ii) a salt which is of formula [R.sup.1 (R.sup.2)XR.sup.3 ].sup.+ Y.sup.-, wherein each of R.sup.1, R.sup.2 and R.sup.3 is bonded directly to X, each of R.sup.1 and R.sup.2, which may be the same or different is an alkyl group of at least 4 carbons, X is S, NR.sup.4 or PR.sup.4, wherein each of R.sup.3 and R.sup.4 which may be the same or different represents hydrogen or an organic group, with the proviso that at least one of R.sup.3 and R.sup.4 is an organic group of at least 4 carbons, and Y is an anion, the additives being added in an amount effective to inhibit or retard hydrate formation, to a medium susceptible to hydrate formation.
Abstract:
An antifoam additive for hydrocarbon oils and in particular fuel oils comprises the combination of an antifoam agent and an ashless dispersant.
Abstract:
A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.
Abstract:
The present invention relates to an organopolysiloxane compound having at least one group having the formula ##STR1## and at least one group having its formula selected from --R.sup.3 --C.sub.6 H.sub.5 or --R.sub.3 --O--C.sub.6 H.sub.5 per molecule wherein R.sup.3 is a divalent hydrocarbon group having from 1 to 20 carbon atoms, R.sup.4 is hydrogen, an alkyl group, an aryl group, or an acyl group, d has a value of 0 to 150, e has a value of 0 to 150, with the proviso that the value of d+e is at least one. The organopolysiloxane compounds of this invention reduce the amount of foam in the hydrocarbon fuel, especially in diesel fuels and jet fuels. The organopolysiloxane compound acts as a foam control agent which displays consistent compatibility and miscibility with additives which are frequently present in hydrocarbon fuels.
Abstract translation:本发明涉及具有至少一个具有式“IMAGE”的基团的有机聚硅氧烷化合物和至少一种其分子式为选自每个分子的-R 3 -C 6 H 5或-R 3 -O-C 6 H 5的基团,其中R 3是具有 1至20个碳原子,R 4是氢,烷基,芳基或酰基,d的值为0至150,e的值为0至150,条件是d + e至少是一个。 本发明的有机聚硅氧烷化合物减少烃燃料中的泡沫,特别是在柴油和喷气燃料中。 有机聚硅氧烷化合物起到泡沫控制剂的作用,其与烃燃料中经常存在的添加剂具有一致的相容性和混溶性。
Abstract:
A fuel mixture containing an ionic complex of an amine salt of a phosphoric acid is effective in reducing the smoke emitted during operation of a two-cycle internal combustion engine. A preferred phosphoric acid derivative is dioctyldithiophosphate. A preferred primary amine component is dihydrogenated tallow amine.
Abstract:
The present invention is a class of organosilicone terpolymers which may be used to abate the foaming of diesel fuel at silicon levels below 1.2 ppm. Said silicone terpolymers are modified alkyl phenol derivatives and polyethers grafted on a polysiloxane copolymer. Said polysiloxane terpolymer has a structure of MD.sub.x D*.sub.y D**.sub.2 M, where M is O.sub.0.5 Si(CH.sub.3).sub.3, D is a OSi(CH.sub.3).sub.2, D* is OSi(CH.sub.3)R, R is a polyether, D** is OSi(CH.sub.3)R', R' is a phenol derivative x+y+z is 35-350, x/(y+z) is 3 to 6 and y/z is 0.25 to about 9.0.
Abstract:
The specification discloses a method of controlling foaming of liquid hydrocarbon fuels (e.g. diesel fuel and jet fuel) by inclusion therein of certain siloxane polyoxyalkylene copolymer as antifoam agents. The copolymers have an average molecular formula such that oxyalkylene groups of the copolymer provide from about 25% to about 65% by weight of the copolymer. Preferred copolymers are according to the general formulaMe.sub.3 SiO(Me.sub.2 SiO).sub.x (MeR'SiO).sub.y SiMe.sub.3in which each Me represents a methyl group, each R' represents a group according to the general formulaQ(OA).sub.n OZin which Q represents a divalent group attached to the silicon atom, each A represents an ethylene group, n has a value from 10 to 15, Z represents a hydrogen atom or a group OCR" in which R" represents a monovalent group and the ratio x:y lies in the range 1:1 to 11:1, more preferably in the range 3:1 to 7:1.
Abstract:
Emulsions of fluorosilicone fluids in mineral oil are disclosed. These emulsions are stabilized by a polydimethylsiloxane- polybutadiene copolymer or a polydimethylsiloxane-hydrogenated polybutadiene copolymer. The emulsions are an effective foam suppressant for organic liquids, especially crude petroleum.
Abstract:
An oxygenated hydrocarbon based fuel for use in internal combustion engines is composed by volume of alcohol (40-80%), ketone (0-30%) ether (15-40%), a dimethyl siloxane (0.01-1.0%) a surfactant (0.25-1.0%) and a fuel-soluble corrosion inhibitor (0.02-0.1%). The resulting fuel has excellent storage life and performance characteristics superior to gasoline.