公开(公告)号：US09556088B2

公开(公告)日：2017-01-31

申请号：US13691181

申请日：2012-11-30

Applicant: Iowa State University Research Foundation, Inc.

Inventor： Igor Ivan Slowing ,  Kapil Kandel

IPC: C07C7/12 ,  C07C1/22 ,  B01J31/12 ,  C07C1/207 ,  C10G25/00 ,  C10G25/06 ,  C10G45/06 ,  C10G3/00 ,  B01J31/08 ,  B01J31/10 ,  B01J31/16 ,  B01J27/185 ,  B01J29/03 ,  B82Y30/00 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC classification number: C07C7/12 ,  B01J27/1853 ,  B01J29/0308 ,  B01J29/0325 ,  B01J29/0333 ,  B01J29/0341 ,  B01J31/08 ,  B01J31/10 ,  B01J31/1616 ,  B01J35/0013 ,  B01J35/0033 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0209 ,  B01J2231/641 ,  B82Y30/00 ,  C07C1/2078 ,  C07C1/22 ,  C07C2521/08 ,  C07C2523/755 ,  C10G3/44 ,  C10G3/45 ,  C10G3/48 ,  C10G3/50 ,  C10G25/003 ,  C10G25/06 ,  C10G45/06 ,  C10G2300/1011 ,  Y02E50/13 ,  Y02P20/52 ,  C07C9/22

Abstract: The present invention provides an adsorbent catalytic nanoparticle including a mesoporous silica nanoparticle having at least one adsorbent functional group bound thereto. The adsorbent catalytic nanoparticle also includes at least one catalytic material. In various embodiments, the present invention provides methods of using and making the adsorbent catalytic nanoparticles. In some examples, the adsorbent catalytic nanoparticles can be used to selectively remove fatty acids from feedstocks for biodiesel, and to hydrotreat the separated fatty acids.

Abstract translation: 本发明提供一种吸附剂催化纳米颗粒，其包括具有至少一个与其结合的吸附官能团的介孔二氧化硅纳米颗粒。 吸附剂催化纳米颗粒还包括至少一种催化材料。 在各种实施方案中，本发明提供了使用和制备吸附剂催化纳米颗粒的方法。 在一些实例中，吸附剂催化纳米颗粒可用于从用于生物柴油的原料中选择性除去脂肪酸，并加氢处理分离的脂肪酸。

公开(公告)号：US09539567B2

公开(公告)日：2017-01-10

申请号：US15059036

申请日：2016-03-02

Applicant: SASOL TECHNOLOGY (PROPRIETARY) LIMITED

Inventor： Jacobus Lucas Visagie ,  Tanja Allers ,  Frederik Marie Paul Rafael Van Laar ,  Frederik Borninkhof ,  Jana Heloise Taljaard ,  Rita Meyer

IPC: B01J21/08 ,  B01J37/02 ,  B01J21/12 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J23/12 ,  B01J23/20 ,  B01J23/22 ,  B01J23/30 ,  B01J23/34 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/89 ,  B01J31/02 ,  B01J35/00 ,  C10G2/00 ,  B01J21/06 ,  C07C1/04 ,  C07C29/157 ,  C07C41/01

CPC classification number: B01J37/0203 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/12 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J23/12 ,  B01J23/20 ,  B01J23/22 ,  B01J23/30 ,  B01J23/34 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8913 ,  B01J31/0274 ,  B01J35/002 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0209 ,  C07C1/0445 ,  C07C29/157 ,  C07C41/01 ,  C10G2/33 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333

Abstract: A method of preparing a modified catalyst support comprises contacting a catalyst support material with a modifying component precursor in an impregnating liquid medium. The impregnating liquid medium comprises a mixture of water and an organic liquid solvent for the modifying component precursor. The mixture contains less than 17% by volume water based on the total volume of the impregnating liquid medium. The modifying component precursor comprises a compound of a modifying component selected from the group consisting of Si, Zr, Co, Ti, Cu, Zn, Mn, Ba, Ni, Al, Fe, V, Hf, Th, Ce, Ta, W, La and mixtures of two or more thereof. A modifying component containing catalyst support material is thus obtained. Optionally, the modifying component containing catalyst support material is calcined at a temperature above 100° C. to obtain a modified catalyst support.

Abstract translation: 制备改性催化剂载体的方法包括使催化剂载体材料与浸渍液体介质中的改性组分前体接触。 浸渍液体介质包含水和用于改性组分前体的有机液体溶剂的混合物。 基于浸渍液体介质的总体积，混合物含有少于17体积％的水。 改性成分前体包括选自Si，Zr，Co，Ti，Cu，Zn，Mn，Ba，Ni，Al，Fe，V，Hf，Th，Ce，Ta，W中的一种改性成分的化合物 ，La及其两种或更多种的混合物。 由此得到含有催化剂载体材料的改性成分。 任选地，含有催化剂载体材料的改性组分在高于100℃的温度下煅烧以获得改性的催化剂载体。

公开(公告)号：US20170001174A1

公开(公告)日：2017-01-05

申请号：US15101876

申请日：2014-12-03

Applicant: Heesung Catalysts Corporation

Inventor： Hyun-sik Han ,  Young-San Yoo ,  Ho-Dong Kim

IPC: B01J23/62 ,  B01J21/04 ,  B01J37/16 ,  B01J37/08 ,  B01J37/02 ,  C07C5/333 ,  B01J35/10

CPC classification number: B01J23/626 ,  B01J21/04 ,  B01J23/14 ,  B01J23/42 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/08 ,  B01J37/16 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2523/62 ,  C10G45/62

Abstract: Disclosed are a catalyst for dehydrogenating a paraffinic hydrocarbon and a method of preparing the same, wherein the catalyst is configured such that a sponge-type alumina support having 3D meso/macro pores is directly impregnated with an active metal, thus decreasing the diffusion resistance of a material, realizing structural stability, and maximizing the distribution of the active metal in the support, thereby significantly increasing olefin conversion and selectivity.In this catalyst, the sponge-type alumina support is directly impregnated with the active metal to thus form an active metal layer inside the support having 3D meso/macro pores that are interconnected to each other.

Abstract translation: 在该催化剂中，海绵型氧化铝载体直接用活性金属浸渍，从而在支撑体内部形成活性金属层，其具有彼此互连的3D中孔/宏观孔。

公开(公告)号：US09527061B2

公开(公告)日：2016-12-27

申请号：US14114477

申请日：2011-04-28

Applicant: Albertus Jacobus Sandee ,  Robert Johan Andreas Maria Terorde

Inventor： Albertus Jacobus Sandee ,  Robert Johan Andreas Maria Terorde

IPC: B01J23/00 ,  B01J23/89 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B01J35/00 ,  B01J37/02 ,  B01J37/18 ,  C10G49/04 ,  C10G49/08 ,  C10G2/00 ,  B01J23/06 ,  B01J23/28 ,  B01J23/34 ,  B01J23/46 ,  B01J23/745

CPC classification number: B01J23/8986 ,  B01J23/06 ,  B01J23/28 ,  B01J23/34 ,  B01J23/462 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8913 ,  B01J23/892 ,  B01J35/0013 ,  B01J35/006 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0219 ,  B01J37/18 ,  C10G2/332 ,  C10G2/334 ,  C10G49/04 ,  C10G49/08

Abstract: A process for preparing a catalyst precursor includes forming a slurry of particles of an insoluble metal compound, where the metal of the insoluble metal compound is an active catalyst component, with particles and/or one or more bodies of a pre-shaped catalyst support in a carrier liquid. The particles of the insoluble metal compound are thus contacted with the particles and/or the one or more bodies of the pre-shaped catalyst support. A treated catalyst support is thereby produced. Carrier liquid is removed from the slurry to obtain a dried treated catalyst support, which either directly constitutes the catalyst precursor, or is optionally calcined to obtain the catalyst precursor.

Abstract translation: 制备催化剂前体的方法包括：将不溶性金属化合物的金属作为活性催化剂组分的不溶性金属化合物的颗粒与颗粒和/或预成型催化剂载体的一个或多个体形成淤浆 载液。 因此，不溶性金属化合物的颗粒与颗粒和/或预成形催化剂载体的一个或多个体接触。 由此产生经处理的催化剂载体。 将载体液体从浆料中除去，得到干燥处理的催化剂载体，其直接构成催化剂前体，或任选地煅烧以获得催化剂前体。

公开(公告)号：US20160326105A1

公开(公告)日：2016-11-10

申请号：US14781171

申请日：2014-03-28

Applicant: ARKEMA FRANCE

Inventor： Georges FREMY ,  Patrice BARRE ,  Karine SANCHOU ,  Alexia CORDOVA ,  Carole LAMONIER ,  Pascal BLANCHARD

IPC: C07C319/02 ,  B01J23/28 ,  B01J27/18 ,  B01J35/00 ,  C07C319/06 ,  B01J27/057 ,  B01J23/755 ,  B01J23/745 ,  B01J37/02 ,  B01J27/051 ,  B01J35/10

CPC classification number: C07C319/02 ,  B01J23/28 ,  B01J23/745 ,  B01J23/755 ,  B01J27/051 ,  B01J27/0576 ,  B01J27/1806 ,  B01J35/0006 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/0207 ,  C07C319/06 ,  C07C321/04

Abstract: The invention relates to a catalyst comprising an active component based on molybdenum and on potassium and a support based on hydroxyapatite, and also to a process for preparing said catalyst and a process for producing methyl mercaptan in a catalytic process by reaction of carbon monoxide, sulphur and/or hydrogen sulphide and hydrogen, comprising the use of said catalyst.

Abstract translation: 本发明涉及包含基于钼和钾的活性组分和基于羟基磷灰石的载体的催化剂，以及一种制备所述催化剂的方法以及通过一氧化碳，硫的反应在催化方法中生产甲基硫醇的方法 和/或硫化氢和氢气，包括使用所述催化剂。

公开(公告)号：US09486787B1

公开(公告)日：2016-11-08

申请号：US14857468

申请日：2015-09-17

Applicant: UNIVERSITY OF WYOMING

Inventor： Dongmei Li ,  Shuai Tan

IPC: B01J23/10 ,  B01J23/63 ,  B01J27/053 ,  B01J23/44 ,  B01J35/06 ,  B01J35/00 ,  B01J37/04 ,  B01J37/14 ,  B01J37/02

CPC classification number: B01J27/053 ,  B01D67/0088 ,  B01D2325/10 ,  B01J23/44 ,  B01J35/0013 ,  B01J35/065 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0213 ,  B01J37/0244 ,  B01J37/14 ,  B01J37/349 ,  C01B3/16 ,  C01B3/505

Abstract: Embodiments disclosed herein generally relate to methods and apparatus for simultaneous generation and separation processes. The apparatus provides a membrane module including a substrate, a catalytic layer and a membrane layer. The catalytic layer includes nano-sized sulfur-tolerant catalysts and/or particles. As a result, the apparatus can operate in sulfur-free and sulfur-laden (sour gas) environments for water gas shift (WGS) reactions while maintaining high reaction conversion. Methods for forming catalytic films are also disclosed herein. In one embodiment, methods of forming lanthanide containing oxysulfate nanocatalysts are provided.

Abstract translation: 本文公开的实施方案通常涉及同时生成和分离过程的方法和装置。 该装置提供了包括基底，催化层和膜层的膜组件。 催化层包括纳米尺寸的耐硫催化剂和/或颗粒。 因此，该设备可以在无硫和含硫（酸性气体）环境中进行水煤气变换（WGS）反应，同时保持高反应转化率。 本文还公开了形成催化膜的方法。 在一个实施方案中，提供了形成含有硫酸氢盐纳米催化剂的镧系元素的方法。

公开(公告)号：US20160318011A1

公开(公告)日：2016-11-03

申请号：US15211726

申请日：2016-07-15

Applicant: Abdurahman Hosseinifar ,  Maryam Fakhraie Farouji

Inventor： Abdurahman Hosseinifar ,  Maryam Fakhraie Farouji

IPC: B01J37/06 ,  B01J35/04 ,  B01J37/16 ,  B01J23/44 ,  B01J37/02

CPC classification number: B01J37/06 ,  B01J23/38 ,  B01J23/44 ,  B01J35/04 ,  B01J37/0207 ,  B01J37/0225 ,  B01J37/0236 ,  B01J37/16

Abstract: Provided is a method for synthesizing a ceramic-based catalyst including the steps of: purifying a ceramic foam by immersing the ceramic foam in hot water to form a clean substrate; activating the clean substrate by immersing the clean substrate in an etching solution to form an activated substrate; forming a first metal layer onto the activated substrate to form a metal-loaded substrate; and substituting the first metal layer with a noble metal layer by immersing the metal-loaded substrate in an acidic solution including a noble metal precursor to yield the ceramic-based noble metal catalyst.

Abstract translation: 提供一种合成陶瓷类催化剂的方法，包括以下步骤：通过将陶瓷泡沫体浸入热水中来净化陶瓷泡沫体以形成清洁的基材; 通过将清洁衬底浸入蚀刻溶液中以形成活化的衬底来激活干净的衬底; 在活化的基底上形成第一金属层以形成负载金属的衬底; 并且通过将含金属负载的基板浸渍在包含贵金属前体的酸性溶液中以形成陶瓷基贵金属催化剂，用贵金属层代替第一金属层。

公开(公告)号：US20160318008A1

公开(公告)日：2016-11-03

申请号：US15175214

申请日：2016-06-07

Applicant: Chevron Phillips Chemical Company LP

Inventor： Gyanesh P. Khare

IPC: B01J29/62 ,  B01J29/90 ,  B01J38/10 ,  B01J37/08 ,  B01J37/02 ,  B01J38/12 ,  C10G35/095 ,  B01J35/10

CPC classification number: B01J29/62 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/63 ,  B01J29/90 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/24 ,  B01J37/30 ,  B01J38/10 ,  B01J38/12 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G35/095

Abstract: Regenerable aromatization catalysts having high surface area and pore volume, as well as methods for producing these catalysts, are disclosed.

Abstract translation: 公开了具有高表面积和孔体积的可再生芳构化催化剂以及制备这些催化剂的方法。

公开(公告)号：US09475003B2

公开(公告)日：2016-10-25

申请号：US14727191

申请日：2015-06-01

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Takuto Hirose ,  Kiyoshi Yamazaki ,  Yuichi Sobue ,  Yusuke Shinmyo

IPC: B01D53/94 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J35/02 ,  F01N3/10

CPC classification number: B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/9022 ,  B01D2255/9202 ,  B01D2258/012 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0207 ,  B01J37/0219 ,  B01J37/0242 ,  B01J37/0248 ,  B01J37/08 ,  B01J37/088 ,  F01N3/103 ,  Y02A50/2341

Abstract: An exhaust gas purification catalyst includes an alumina support, a silica layer, and active metal particles. The silica layer is formed on a surface of the alumina support. The active metal particles are formed of platinum and palladium, the platinum and the palladium being supported on the silica layer. A ratio of fine particles having a particle size of 2.0 nm or less to all the active metal particles is 50% or higher in terms of the number of particles, the fine particles being included in the active metal particles. A ratio of fine alloy particles having a palladium content ratio of 10 at % to 90 at % to all the fine particles is 50% or higher in terms of the number of particles, the fine alloy particles being included in the fine particles.

Abstract translation: 废气净化催化剂包括氧化铝载体，二氧化硅层和活性金属颗粒。 二氧化硅层形成在氧化铝载体的表面上。 活性金属颗粒由铂和钯形成，铂和钯负载在二氧化硅层上。 粒子数为2.0nm以下的微粒与所有活性金属粒子的比率，相对于粒子数为50％以上，微粒包含在活性金属粒子中。 钯含量比例为10原子％〜90原子％的细微粒子的合金粒子的数量相对于微粒数为50％以上，微细合金粒子包含在微细粒子中。

公开(公告)号：US20160296922A1

公开(公告)日：2016-10-13

申请号：US14683435

申请日：2015-04-10

Applicant: Yihua Zhang ,  Theodorus Ludovicus Michael Maesen ,  Andrew Rainis ,  Bao Quoc Le

Inventor： Yihua Zhang ,  Theodorus Ludovicus Michael Maesen ,  Andrew Rainis ,  Bao Quoc Le

IPC: B01J29/16 ,  C10G47/20 ,  B01J37/04 ,  B01J37/08 ,  B01J35/10 ,  B01J37/02

CPC classification number: B01J29/166 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1023 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0207 ,  B01J2229/20 ,  C10G47/20

Abstract: A hydrocracking catalyst is provided comprising: a) greater than 10 wt % of a zeolite USY having: i. a total OD acidity of 0.350 to 0.650 mmol/g; ii. an ASDI between 0.05 and 0.15; iii. a BET surface area greater than 600 m2/g; iv. a SAR greater than 10; v. less than 45 vol % of pores greater than 2 nm; b) a support; and c) at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. A process for hydrocracking using a hydrocracking catalyst to produce middle distillates is provided. A method for making a hydrocracking catalyst is also provided.

Abstract translation: 提供加氢裂化催化剂，其包含：a）大于10重量％的具有以下成分的沸石USY： 总OD酸度为0.350〜0.650mmol / g; ii。 0.05和0.15之间的ASDI; iii。 BET表面积大于600m2 / g; iv。 大于10的SAR; v。小于45体积％的孔大于2nm; b）支持; 和c）选自元素周期表第6族和第8至10族元素中的至少一种金属。 提供了使用加氢裂化催化剂生产中间馏分的加氢裂化方法。 还提供了制备加氢裂化催化剂的方法。