公开(公告)号：US20160096165A1

公开(公告)日：2016-04-07

申请号：US14436059

申请日：2014-06-05

Applicant: UNIWERSYTET JAGIELLONSKI

Inventor： Mieczyslawa Najbar ,  Jaroslaw Dutkiewicz ,  Tomasz Wilkosz ,  Elzbieta BIELANSKA ,  Aleksandra Weselucha-Birczynska ,  Jôzef Camra ,  Janusz Danko ,  Jakub Bartyzel

IPC: B01J23/889 ,  B01J37/08 ,  B01J37/06 ,  B01J37/18 ,  B01J35/04 ,  B01J37/12

CPC classification number: B01J23/8892 ,  B01D53/8628 ,  B01D53/865 ,  B01D2255/20738 ,  B01D2255/20753 ,  B01D2255/405 ,  B01D2258/0283 ,  B01J21/005 ,  B01J23/755 ,  B01J35/002 ,  B01J35/0053 ,  B01J35/04 ,  B01J35/1004 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/06 ,  B01J37/08 ,  B01J37/12 ,  B01J37/18 ,  C23C8/10 ,  C23C8/80

Abstract: A monolithic catalyst for simultaneous removal of NOx and carbon particles, especially from off-gases of carbon power plants contains the monolith is made from acid-proof austenitic steel. The catalyst is a two-phase one; moreover, it contains the phases NiFe2O4 and Fe2O3(Mh) with spinel structure, and these phases form microcrystallites, additionally containing Mn.The manner of production of the monolithic catalyst for simultaneous removal of NOx and carbon particles, especially from off-gases of carbon power plants depends on the monolith is subject to oxidation after which the resulting oxide layers are washed with the solution of nickel salts; later the monolith is baked in the oxidising atmosphere with the view to inserting nickel ions into the oxide layer; finally this obtained oxide layers are subject to reduction.

Abstract translation: 用于同时去除NOx和碳颗粒的整体式催化剂，特别是从碳发电厂的废气中排出的整体式催化剂包含由耐酸奥氏体钢制成的整料。 催化剂是两相的; 此外，它包含具有尖晶石结构的NiFe 2 O 4和Fe 2 O 3（Mh）相，并且这些相形成微晶，另外含有Mn。 用于同时去除NOx和碳颗粒，特别是碳发电厂废气的整体式催化剂的生产方式取决于整体是否经历氧化，之后用镍盐溶液洗涤所得到的氧化物层; 之后，在氧化气氛中烘烤整料，以便将镍离子插入到氧化物层中; 最终得到的氧化物层被还原。

公开(公告)号：US09254483B2

公开(公告)日：2016-02-09

申请号：US14035194

申请日：2013-09-24

Applicant: KOREA INSTITUTE OF ENERGY RESEARCH

Inventor： Hee Yeon Kim ,  Nam Jo Jeong ,  Seong Ok Han

IPC: B01J37/34 ,  B01J31/06 ,  B01J23/28 ,  B01J23/42 ,  B01J23/75 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  C01B3/40 ,  C01B31/08 ,  C10G2/00

CPC classification number: B01J37/341 ,  B01J23/28 ,  B01J23/42 ,  B01J23/75 ,  B01J23/755 ,  B01J31/06 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/34 ,  B01J37/343 ,  C01B3/40 ,  C01B32/324 ,  C01B2203/1052 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/70 ,  Y02P20/52

Abstract: The present disclosure relates to a catalyst having metal catalyst nanoparticles supported on natural cellulose fibers and a method of preparing the same, whereby natural cellulose fibers are subjected to specific pretreatment to increase a surface area and form defects on the surface thereof and metal catalyst nanoparticles are then supported on the cellulose catalyst support in a highly dispersed state, thereby providing improved catalysis while allowing production of the catalyst at low cost. The catalyst may be utilized for various catalytic reactions.

Abstract translation: 本发明涉及一种具有负载在天然纤维素纤维上的金属催化剂纳米颗粒的催化剂及其制备方法，其中天然纤维素纤维进行特定预处理以增加表面积并在其表面形成缺陷，并且金属催化剂纳米颗粒为 然后以高度分散的状态负载在纤维素催化剂载体上，从而提供改进的催化，同时以低成本制备催化剂。 催化剂可用于各种催化反应。

公开(公告)号：US09233366B2

公开(公告)日：2016-01-12

申请号：US14055268

申请日：2013-10-16

Applicant: Board of Trustees of The University of Alabama

Inventor： Martin G. Bakker ,  Franchessa Maddox Sayler ,  Kevin Shaughnessy

IPC: B01J21/18 ,  B01J23/16 ,  B01J23/20 ,  B01J23/24 ,  B01J23/32 ,  B01J23/38 ,  B01J23/48 ,  B01J35/10 ,  B01J37/08 ,  B01J37/16 ,  B01J37/18 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J23/72 ,  B01J23/755 ,  B01J35/00 ,  B01J37/02 ,  C07C209/36 ,  C07C2/86 ,  C07C253/30 ,  C07C67/343 ,  B82Y30/00

CPC classification number: B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/72 ,  B01J23/755 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/0053 ,  B01J35/006 ,  B01J35/08 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J35/109 ,  B01J35/1095 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/06 ,  B01J37/08 ,  B01J37/084 ,  B01J37/088 ,  B01J37/16 ,  B01J37/18 ,  B82Y30/00 ,  C04B38/0032 ,  C07C2/861 ,  C07C41/30 ,  C07C67/343 ,  C07C209/36 ,  C07C253/30 ,  C07C2521/18 ,  C07C2523/44 ,  C07C211/46 ,  C07C255/57 ,  C07C255/50 ,  C07C15/52 ,  C07C69/618 ,  C04B35/52 ,  C04B38/0054 ,  C04B38/0058 ,  C04B38/0064 ,  C04B38/045 ,  C04B38/0615

Abstract: Disclosed are hierarchically porous carbon materials with a plurality of discreet nanoparticles dispersed on their carbon phase. The materials possess a continuous network of pores that spans the porous material, permitting the flow of fluids into and through the material. The porous materials can be used as heterogeneous catalysts.

Abstract translation: 公开了具有分散在其碳相上的多个分散纳米颗粒的层状多孔碳材料。 这些材料具有跨越多孔材料的连续孔隙网络，允许流体流入材料和通过材料。 多孔材料可用作非均相催化剂。

公开(公告)号：US09233360B1

公开(公告)日：2016-01-12

申请号：US14482313

申请日：2014-09-10

Applicant: Kandaswamy Jothimurugesan ,  Mark Muraoka

Inventor： Kandaswamy Jothimurugesan ,  Mark Muraoka

IPC: B01J21/04 ,  B01J23/75 ,  B01J23/70 ,  B01J27/185 ,  B01J23/89 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  C10G2/00

CPC classification number: B01J27/1856 ,  B01J21/04 ,  B01J23/70 ,  B01J23/75 ,  B01J23/80 ,  B01J23/8946 ,  B01J23/8953 ,  B01J23/896 ,  B01J23/8966 ,  B01J23/898 ,  B01J23/8993 ,  B01J27/188 ,  B01J27/19 ,  B01J27/198 ,  B01J35/002 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/08 ,  B01J37/18 ,  C10G2/332 ,  C10G2/333

Abstract: A process has been developed for preparing a Fischer-Tropsch catalyst precursor and a Fischer-Tropsch catalyst made from the precursor. The process includes contacting a gamma alumina catalyst support material with a first solution containing a compound containing zinc and optionally containing P, Ti, V, Co, Ga, Ge, Mo, W and/or Pr to obtain a modified catalyst support material. The modified catalyst support material is calcined at a temperature of at least 500° C. The calcined modified catalyst support has a pore volume of at least 0.4 cc/g. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component to obtain a catalyst precursor. The catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer-Tropsch catalyst. The catalyst has enhanced hydrothermal stability as measured by losing no more than 20% of its pore volume when exposed to water vapor.

Abstract translation: 已经开发了制备费 - 托催化剂前体和由前体制备的费 - 托催化剂的方法。 该方法包括使γ氧化铝催化剂载体材料与含有锌化合物和任选地含有P，Ti，V，Co，Ga，Ge，Mo，W和/或Pr的第一溶液接触，以获得改性的催化剂载体材料。 改性的催化剂载体材料在至少500℃的温度下煅烧。煅烧的改性催化剂载体的孔体积至少为0.4cc / g。 改性的催化剂载体在酸溶液中比相当的未改性的催化剂载体更难溶解。 将改性的催化剂载体与包含活性钴催化剂组分的前体化合物的第二溶液接触以获得催化剂前体。 催化剂前体被还原以活化催化剂前体以获得费 - 托催化剂。 催化剂具有增强的水热稳定性，当暴露于水蒸气时，其通过损失其不超过其孔体积的20％来测量。

公开(公告)号：US20150352525A1

公开(公告)日：2015-12-10

申请号：US14592808

申请日：2015-01-08

Applicant: Indian Oil Corporation Limited

Inventor： Kumaresan Loganathan ,  Mohan Prabhu Kuvettu ,  Arumugam Velayutham Karthikeyani ,  Biswanath Sarkar ,  Balaiah Swamy ,  Alex Pulikottil ,  Pankaj Kumar Kasliwal ,  Jayaraj Christopher ,  Brijesh Kumar ,  Santanam Rajagopal

IPC: B01J23/44 ,  B01J23/42 ,  B01J37/02 ,  B01J37/00 ,  B01J35/08 ,  B01J21/04 ,  B01J35/10 ,  B01J37/06 ,  B01J35/00 ,  C10G11/00 ,  B01J37/04

CPC classification number: B01J23/44 ,  B01J21/04 ,  B01J23/42 ,  B01J35/00 ,  B01J35/0006 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/038 ,  B01J37/04 ,  B01J37/06 ,  C10G11/00 ,  C10G11/02 ,  C10G11/18 ,  C10G2300/405 ,  Y02P30/446

Abstract: The invention relates to a CO oxidation promoter additive and a method of its preparation. The CO oxidation promoter additive is having improved apparent bulk density and attrition properties for use in hydrocarbon conversion during fluid catalytic cracking. The CO oxidation promoter additive has a better CO to CO2 conversion.

Abstract translation: 本发明涉及一种CO氧化促进剂添加剂及其制备方法。 CO氧化促进剂添加剂在流化催化裂化过程中具有改进的表观堆积密度和用于烃转化的磨耗特性。 CO氧化促进剂添加剂具有更好的CO至CO 2转化率。

公开(公告)号：US09206363B2

公开(公告)日：2015-12-08

申请号：US13597598

申请日：2012-08-29

Applicant: Hyung Suk Woo ,  Jane Chi-ya Cheng ,  Teh C. Ho ,  Stephen Harold Brown ,  Richard Charles Dougherty ,  David Thomas Ferrughelli ,  Federico Barrai

Inventor： Hyung Suk Woo ,  Jane Chi-ya Cheng ,  Teh C. Ho ,  Stephen Harold Brown ,  Richard Charles Dougherty ,  David Thomas Ferrughelli ,  Federico Barrai

IPC: C10G47/00 ,  C10G53/02 ,  C10G53/04 ,  C10G65/12 ,  C10G47/02 ,  C10G45/04 ,  C10G49/02 ,  C10G49/22 ,  C10G67/04 ,  B01J37/20 ,  B01J23/74 ,  B01J35/02 ,  B01J37/02 ,  B01J23/883 ,  B01J23/888 ,  B01J35/10

CPC classification number: C10G45/00 ,  B01J23/74 ,  B01J23/883 ,  B01J23/8885 ,  B01J35/023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/20 ,  C10G45/02 ,  C10G45/04 ,  C10G45/32 ,  C10G45/44 ,  C10G45/58 ,  C10G47/00 ,  C10G47/02 ,  C10G49/02 ,  C10G49/22 ,  C10G67/0454 ,  C10G67/049 ,  C10G2300/1037 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/206 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2300/44 ,  C10L1/04

Abstract: Heavy oil feeds are hydroprocessed in the presence of a solvent under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.

Abstract translation: 在提供各种益处的条件下，在溶剂存在下将重油进料加氢处理。 溶剂可以是加氢处理的添加溶剂或一部分液体流出物。 该方法允许重油进料的较低压力处理用于延长的处理时间或延长的催化剂寿命来减少或减轻加氢处理催化剂上焦炭形成的量。

公开(公告)号：US20150337221A1

公开(公告)日：2015-11-26

申请号：US14816531

申请日：2015-08-03

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich GABRIELOV ,  Ed GANJA ,  Theofiel MEURIS ,  Maxim Vasilievich OVCHINNIKOV

IPC: C10G45/08

CPC classification number: C10G45/08 ,  B01J21/04 ,  B01J23/75 ,  B01J23/755 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J31/02 ,  B01J31/0201 ,  B01J31/0235 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1066 ,  B01J37/0203 ,  B01J37/0207 ,  C10G45/06 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/1088 ,  C10G2300/301

Abstract: A composition having a substantial or material absence of or no phosphorous and comprising a support material, a metal compound and either a hydrocarbon oil or a polar additive or a combination of both a hydrocarbon oil and polar additive. The polar additive has particularly defined properties including having a dipole moment of at least 0.45. The composition is useful in the hydroprocessing of hydrocarbon feedstocks, and it is especially useful in the hydrotreating of vacuum gas oils and petroleum resid feedstocks.

Abstract translation: 具有实质上或物质上不存在或不含磷的组合物，并且包含载体材料，金属化合物和烃油或极性添加剂或烃油和极性添加剂的组合。 极性添加剂具有特别限定的性质，包括偶极矩至少为0.45。 该组合物可用于烃类原料的加氢处理，特别适用于真空瓦斯油和石油渣油原料的加氢处理。

公开(公告)号：US09192929B2

公开(公告)日：2015-11-24

申请号：US13776521

申请日：2013-02-25

Applicant: Velocys, Inc

Inventor： Anna Lee Tonkovich ,  Gary Roberts ,  Sean P. Fitzgerald ,  Paul W. Neagle ,  Dongming Qui ,  Matthew B. Schmidt ,  Steven T. Perry ,  David J. Hesse ,  Robert J. Luzenski ,  G. Bradley Chadwell ,  Ying Peng ,  James A. Matthias ,  Nathan P. Gano ,  Richard Q. Long ,  Wm. Allen Rogers ,  Ravi Arora ,  Wayne W. Simmons ,  Barry L. Yang ,  David J. Kuhlmann ,  Yong Wang ,  Thomas D. Yuschak ,  Thomas Forte ,  John Arthur Monahan ,  Robert Jetter

IPC: B01J19/00 ,  C01B3/38 ,  B01J37/18 ,  B01J37/02 ,  B01J21/00 ,  B01J23/46 ,  B01J23/58 ,  B01J23/63 ,  B01J8/00 ,  B01J8/02 ,  B01J35/00 ,  B01J35/02 ,  C01B3/00 ,  C01B3/02 ,  C01B3/32 ,  C01B3/34 ,  B01J21/04 ,  B01J21/10

CPC classification number: B01J37/18 ,  B01J21/005 ,  B01J21/04 ,  B01J21/10 ,  B01J23/464 ,  B01J23/58 ,  B01J23/63 ,  B01J37/0207 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0226 ,  B01J37/0228 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0822 ,  C01B2203/1241 ,  C01B2203/1604 ,  C01B2203/1609 ,  C01B2203/1695 ,  Y02P20/128 ,  Y02P20/52

Abstract: Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results, and/or results that can not be achieved with any prior art devices.

Abstract translation: 描述了集成燃烧反应器（ICR）和制造ICR的方法，其中燃烧室（或通道）与用于吸热反应的反应室直接热接触。 还描述了特定的反应器设计。 介绍了综合燃烧反应器中进行反应的过程，并提出了结果。 这些过程中的一些特征在于意想不到的和优异的结果，和/或不能用任何现有技术装置实现的结果。

公开(公告)号：US09192921B1

公开(公告)日：2015-11-24

申请号：US14691797

申请日：2015-04-21

Applicant: Kandaswamy Jothimurugesan ,  Howard Steven Lacheen

Inventor： Kandaswamy Jothimurugesan ,  Howard Steven Lacheen

IPC: B01J27/198 ,  B01J37/02 ,  B01J37/08 ,  B01J37/16 ,  C10G2/00

CPC classification number: B01J27/198 ,  B01J23/83 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/16 ,  C10G2/33 ,  C10G2/332

Abstract: A process is disclosed for preparing a Fischer-Tropsch catalyst precursor and a catalyst made from the precursor. The process includes contacting an alumina catalyst support material with a first solution containing a vanadium compound and a phosphorus compound, to obtain a modified catalyst support material. The modified catalyst support material is calcined at a temperature of at least 500° C. The calcined modified catalyst support has a pore volume of at least 0.4 cc/g. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component and glutaric acid to obtain a catalyst precursor. The catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer-Tropsch catalyst. The catalyst has enhanced hydrothermal stability and good activity.

Abstract translation: 公开了制备费 - 托催化剂前体和由前体制备的催化剂的方法。 该方法包括使氧化铝催化剂载体材料与含有钒化合物和磷化合物的第一溶液接触，以获得改性的催化剂载体材料。 改性的催化剂载体材料在至少500℃的温度下煅烧。煅烧的改性催化剂载体的孔体积至少为0.4cc / g。 改性的催化剂载体在酸溶液中比相当的未改性的催化剂载体更难溶解。 改性的催化剂载体与包含活性钴催化剂组分的前体化合物和戊二酸的第二溶液接触以获得催化剂前体。 催化剂前体被还原以活化催化剂前体以获得费 - 托催化剂。 该催化剂具有增强的水热稳定性和良好的活性。

公开(公告)号：US20150306582A1

公开(公告)日：2015-10-29

申请号：US14260456

申请日：2014-04-24

Applicant: Yihua Zhang ,  Theodorus Ludovicus Michael Maeson

Inventor： Yihua Zhang ,  Theodorus Ludovicus Michael Maeson

IPC: B01J29/08 ,  B01J23/888 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J35/00 ,  C10G47/20 ,  B01J21/12

CPC classification number: B01J29/084 ,  B01J21/04 ,  B01J21/12 ,  B01J23/888 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1052 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/04 ,  B01J2229/42 ,  C10G47/18 ,  C10G47/20

Abstract: The present invention is directed to an improved hydrocracking catalyst containing a amorphous silica-alumina (ASA) base and alumina support. The ASA base is characterized as having a high nanopore volume and low particle density. The alumina support is characterized as having a high total nanopore volume. Hydrocracking catalysts employing the combination high nanopore volume ASA base and alumina support exhibit improved hydrogen efficiency, and greater product yield and quality, as compared to hydrocracking catalysts containing conventional ASA base and alumina components.

Abstract translation: 本发明涉及一种改进的含有无定形二氧化硅 - 氧化铝（ASA）基体和氧化铝载体的加氢裂化催化剂。 ASA碱的特征在于具有高的纳孔孔体积和低的颗粒密度。 氧化铝载体的特征在于具有高的总纳米孔体积。 与含有常规ASA碱和氧化铝组分的加氢裂化催化剂相比，使用高纳米孔体积ASA基和氧化铝载体的加氢裂化催化剂显示出改进的氢效率和更高的产物收率和质量。