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    Method for selectively removing hydrogen from molecules
    63.
    发明授权
    Method for selectively removing hydrogen from molecules 有权
    从分子中选择性除去氢的方法

    公开(公告)号：US07998537B2

    公开(公告)日：2011-08-16

    申请号：US10374550

    申请日：2003-02-25

    Applicant: Raymond W. M. Kwok ,  Woon Ming Lau

    Inventor： Raymond W. M. Kwok ,  Woon Ming Lau

    IPC: C23C16/48 ,  C23C14/46 ,  B05D3/06 ,  C23C14/48

    CPC classification number: C23C14/5833 ,  B05D1/185 ,  B05D3/007 ,  B05D3/06 ,  B29C59/16 ,  B29C2035/0877 ,  C23C8/02 ,  C23C8/36 ,  C23C8/80 ,  C23C14/5873 ,  C23C16/452 ,  C23C16/56 ,  C23G5/00

    Abstract: Methods for removing hydrogen from molecules are disclosed. In one embodiment, hydrogen-containing molecules are deposited on a solid substrate and are bombarded with hydrogen projectile particles. The particles may have energies of 5-100 eV, or more preferably 10-50 eV. The hydrogen projectile particles remove hydrogen atoms from the deposited molecules while they are on the substrate, without removing other atoms from the molecules. Dangling bonds are created by the loss of hydrogen and can be used to cross-link the molecules. The resulting product can be a nanometer-thick dense film.

    Abstract translation: 公开了从分子中除去氢的方法。 在一个实施方案中，含氢分子沉积在固体基质上并用氢射弹颗粒轰击。 颗粒的能量可以为5-100eV，更优选10-50eV。 氢放射体颗粒在沉积的分子同时在基底上除去氢原子，而不从分子中除去其他原子。 悬挂键由氢的损失产生，可用于交联分子。 所得产物可以是纳米厚的致密膜。

    Metal nanoparticle having a self-assembled monolayer on its surface, and formation of conductive pattern using the same
    65.
    发明授权
    Metal nanoparticle having a self-assembled monolayer on its surface, and formation of conductive pattern using the same 有权
    在其表面上具有自组装单层的金属纳米颗粒，以及使用其形成导电图案

    公开(公告)号：US07923110B2

    公开(公告)日：2011-04-12

    申请号：US11653889

    申请日：2007-01-17

    Applicant: Jong Jin Park ,  Dong Woo Shin ,  Sung Woong Kim

    Inventor： Jong Jin Park ,  Dong Woo Shin ,  Sung Woong Kim

    IPC: B32B5/16

    CPC classification number: G03F7/0047 ,  B05D1/185 ,  C03C17/06 ,  H05K3/02 ,  H05K2201/0257 ,  H05K2203/0514 ,  Y10S977/777 ,  Y10S977/778 ,  Y10S977/779 ,  Y10T428/2991

    Abstract: A metal nanoparticle which is prepared by forming a self-assembled monolayer including a terminal reactive group on the surface thereof, and introducing a functional group capable of being removed by the action of an acid or an base into the terminal reactive group wherein the self-assembled monolayer is built up of a thiol, an isocyanide, an amine, a carboxylate or a phosphate compound having the terminal reactive group, or built up of a thiol, an isocyanide, an amine, a carboxylate or a phosphate compound having no terminal reactive group followed by introducing the terminal reactive group thereto; and a method for forming a conductive pattern using the same are provided. Since the metal nanoparticle of exemplary embodiments of the present invention can easily form a high conductive film or a high conductive pattern through photo-irradiation and photo-degradation and randomly regulate its conductivity when occasions demand, it can be advantageously applied to an antistatic washable sticky film, antistatic shoes, a conductive polyurethane printer roller, an electromagnetic interference shielding, and the like.

    Abstract translation: 一种金属纳米颗粒，其通过在其表面上形成包括末端反应性基团的自组装单层并将能够通过酸或碱的作用除去的官能团引入末端反应性基团而制备， 组装的单层由硫醇，异氰化物，胺，羧酸酯或具有末端反应性基团的磷酸酯化合物构成，或由硫醇，异氰化物，胺，羧酸酯或不具有末端反应性的磷酸酯化合物 然后引入末端反应性基团; 并且提供了使用其形成导电图案的方法。 由于本发明的示例性实施方案的金属纳米颗粒可以通过光照射和光降解容易地形成高导电膜或高导电图案，并且当需要时随机调节其导电性，因此可以有利地应用于抗静电可洗粘性 薄膜，抗静电鞋，导电性聚氨酯打印辊，电磁干扰屏蔽等。

    METHODS UTILIZING SCANNING PROBE MICROSCOPE TIPS AND PRODUCTS THEREOF OR PRODUCED THEREBY
    67.
    发明申请
    METHODS UTILIZING SCANNING PROBE MICROSCOPE TIPS AND PRODUCTS THEREOF OR PRODUCED THEREBY 有权
    使用扫描探针显微镜的方法及其产品或其生产方法

    公开(公告)号：US20100330345A1

    公开(公告)日：2010-12-30

    申请号：US11933251

    申请日：2007-10-31

    Applicant: Chad A MIRKIN ,  Richard Piner ,  Seunghun Hong

    Inventor： Chad A MIRKIN ,  Richard Piner ,  Seunghun Hong

    IPC: G01Q60/24 ,  B05D5/00 ,  C23F1/04 ,  B05C1/00 ,  B05C13/00 ,  G01Q80/00 ,  B32B3/10 ,  C40B40/00

    CPC classification number: B82B3/00 ,  B05D1/007 ,  B05D1/185 ,  B05D1/26 ,  G01Q80/00 ,  G03F7/0002 ,  G03F7/165 ,  Y10S977/849 ,  Y10S977/853 ,  Y10S977/854 ,  Y10S977/855 ,  Y10S977/856 ,  Y10S977/857 ,  Y10S977/86 ,  Y10S977/88 ,  Y10S977/884 ,  Y10S977/885 ,  Y10S977/886 ,  Y10S977/895 ,  Y10T428/24802

    Abstract: The invention provides a lithographic method referred to as “dip pen” nanolithography (DPN). DPN utilizes a scanning probe microscope (SPM) tip (e.g., an atomic force microscope (AFM) tip) as a “pen,” a solid-state substrate (e.g., gold) as “paper,” and molecules with a chemical affinity for the solid-state substrate as “ink.” Capillary transport of molecules from the SPM tip to the solid substrate is used in DPN to directly write patterns consisting of a relatively small collection of molecules in submicrometer dimensions, making DPN useful in the fabrication of a variety of microscale and nanoscale devices. The invention also provides substrates patterned by DPN, including submicrometer combinatorial arrays, and kits, devices and software for performing DPN. The invention further provides a method of performing AFM imaging in air. The method comprises coating an AFM tip with a hydrophobic compound, the hydrophobic compound being selected so that AFM imaging performed using the coated AFM tip is improved compared to AFM imaging performed using an uncoated AFM tip. Finally, the invention provides AFM tips coated with the hydrophobic compounds.

    Abstract translation: 本发明提供了称为“浸笔”纳米光刻（DPN）的光刻方法。 DPN使用扫描探针显微镜（SPM）尖端（例如，原子力显微镜（AFM）尖端）作为“笔”，固态基底（例如，金）作为“纸”，并且具有化学亲和力的分子 固体底物作为“墨水”。DPN中使用分子从SPM尖端到固体基质的毛细管转运，以直接写入由亚微米尺寸的相对小的分子集合组成的图案，使得DPN可用于制造 各种微米级和纳米级器件。 本发明还提供由DPN图案化的衬底，包括亚微米组合阵列，以及用于执行DPN的试剂盒，装置和软件。 本发明还提供了一种在空气中进行AFM成像的方法。 该方法包括用疏水性化合物涂覆AFM尖端，选择疏水性化合物，使得与使用未涂覆的AFM尖端进行的AFM成像相比，使用涂覆的AFM尖端进行的AFM成像得到改善。 最后，本发明提供涂覆有疏水化合物的AFM尖端。

    METHOD FOR PRODUCING ORGANIC THIN FILM
    68.
    发明申请
    METHOD FOR PRODUCING ORGANIC THIN FILM 有权
    生产有机薄膜的方法

    公开(公告)号：US20100313789A1

    公开(公告)日：2010-12-16

    申请号：US12833791

    申请日：2010-07-09

    Applicant: Nobuo KIMURA ,  Yoshitaka Fujita ,  Norifumi Nakamoto ,  Tomoya Hidaka

    Inventor： Nobuo KIMURA ,  Yoshitaka Fujita ,  Norifumi Nakamoto ,  Tomoya Hidaka

    IPC: B05D1/02 ,  B05D1/18 ,  B05D1/28 ,  B05D5/00 ,  B05D3/12 ,  C09D7/00

    CPC classification number: C09D5/00 ,  B05D1/185 ,  C03C17/30 ,  Y10T428/261 ,  Y10T428/31504

    Abstract: A method for producing an organic thin film, which enables rapid film formation, and enables a dense organic thin film with minimal impurities to be formed stably, and in a plurality of consecutive repetitions. Also, a method for producing an organic thin film in which an organic thin film is formed on the surface of a substrate, including bringing the substrate into contact with an organic solvent solution containing a metal-based surfactant having at least one hydrolysable group, and a catalyst capable of interacting with the metal-based surfactant, wherein the water contact within the organic solvent solution is either set or maintained within a predetermined range.

    Abstract translation: 一种制造有机薄膜的方法，其能够快速成膜，并且能够稳定地形成具有最小杂质的致密有机薄膜，并且能够连续重复多次。 另外，制造有机薄膜的方法，其中有机薄膜形成在基片的表面上，包括使基片与含有至少一个可水解基团的金属基表面活性剂的有机溶剂溶液接触，以及 能够与金属基表面活性剂相互作用的催化剂，其中有机溶剂溶液内的水接触被设定或保持在预定范围内。

    MOLECULES SUITABLE FOR BINDING TO A METAL LAYER FOR COVALENTLY IMMOBILIZING BIOMOLECULES
    70.
    发明申请
    MOLECULES SUITABLE FOR BINDING TO A METAL LAYER FOR COVALENTLY IMMOBILIZING BIOMOLECULES 有权
    用于结合金属层用于共价固定生物分子的分子

    公开(公告)号：US20100284860A1

    公开(公告)日：2010-11-11

    申请号：US12841800

    申请日：2010-07-22

    Applicant: Filip Frederix ,  Kristien Bonroy ,  Karolien Jans

    Inventor： Filip Frederix ,  Kristien Bonroy ,  Karolien Jans

    IPC: G01N33/00 ,  C07F1/08 ,  C07F3/10 ,  C07F7/24 ,  C07F15/02 ,  C07F11/00 ,  C07F13/00 ,  C07F5/06 ,  C07F1/10 ,  C07F1/12 ,  C07F3/08 ,  H05K13/00

    CPC classification number: G01N33/54353 ,  B05D1/185 ,  B82Y5/00 ,  B82Y30/00 ,  B82Y40/00 ,  C08G65/329 ,  C08G65/334 ,  G01N33/54373 ,  G01N2610/00 ,  Y10T29/49002 ,  Y10T428/24

    Abstract: An article is provided for immobilizing functional organic biomolecules (e.g. proteins, DNA, and the like) through a covalent bond to a thiolate or disulfide monolayer to a metal surface wherein an extra activation step of the surface layer or an activation step of the functional biomolecules or bioreceptors could be avoided. The monolayer can contain, but is not limited to, two moieties. One has a group that resists nonspecific adsorption and another has a group that directly (without activation) reacts with functional groups on the biomolecules. In addition, poly(ethylene oxide) groups are incorporated in the monolayer surfaces to resist the nonspecific adsorption and to enhance the specific affinity interactions. A sensor device including these monolayers is also provided to perform reproducible, sensitive, specific and stable bioanalysis.

    Abstract translation: 提供了一种用于将功能性有机生物分子（例如蛋白质，DNA等）通过共价键固定到硫醇盐或二硫化物单层到金属表面的物品，其中表面层的额外活化步骤或功能性生物分子的活化步骤 或生物受体可以避免。 单层可以包含但不限于两个部分。 一个具有抵抗非特异性吸附的基团，另一个具有直接（不活化）与生物分子上的官能团反应的基团。 此外，聚（环氧乙烷）基团并入单层表面以抵抗非特异性吸附并增强特异性亲和力相互作用。 还提供了包括这些单层的传感器装置，以执行可重复，灵敏，特异和稳定的生物分析。

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