Process for making a metal-polymer composite having an irradiated and thermally adhered polymer coating
    61.
    发明申请
    Process for making a metal-polymer composite having an irradiated and thermally adhered polymer coating 审中-公开
    制备具有照射和热粘合聚合物涂层的金属 - 聚合物复合材料的方法

    公开(公告)号:US20030198765A1

    公开(公告)日:2003-10-23

    申请号:US10127283

    申请日:2002-04-22

    CPC classification number: B05D7/14 B05D3/0254 B05D3/067 B05D3/068 Y10T428/1352

    Abstract: A process for making a metal-polymer composites sheet suitable for shaping into container end panels having improved adhesion and water resistance. A polymer precurser coating is applied to a metal sheet. The polymer precurser coating is selected from the group consisting of epoxy acrylates, silicones, and polyester acrylates. The polymer precurser coating on the metal sheet is irradiated with ultraviolet or an electron beam energy to polymerize the coating and heated to adhere the polymer to the microsurface of the metal sheet.

    Abstract translation: 一种制备金属 - 聚合物复合材料片材的方法,其适合于具有改进的粘合性和耐水性的成型为容器端面板。 将聚合物前体涂层施加到金属板上。 聚合物前体涂层选自环氧丙烯酸酯,硅氧烷和聚酯丙烯酸酯。 用紫外线或电子束能量照射金属片上的聚合物前体涂层以聚合涂层并加热以将聚合物粘附到金属片的微表面。

    Coating process
    63.
    发明申请
    Coating process 有权
    涂层工艺

    公开(公告)号:US20030075268A1

    公开(公告)日:2003-04-24

    申请号:US10213184

    申请日:2002-08-06

    Abstract: A process for producing products in web form comprising at least two layers, in which a composition emerging from an applicator is applied as a layer to a substrate in web form which is guided on a transport means, said application taking place with application of electrostatic charges, and the substrate coated with the composition is electrostatically neutralized before departing the applicator.

    Abstract translation: 一种用于生产纤维网形式的产品的方法,其包括至少两层,其中将从施用器出来的组合物作为一层施加到以传送装置为导向的网状的基材上,所述施用在施加静电荷的情况下发生 ,并且在离开涂布器之前将涂有组合物的基材静电中和。

    Vacuum deposition of cationic polymer systems
    65.
    发明申请
    Vacuum deposition of cationic polymer systems 有权
    阳离子聚合物体系的真空沉积

    公开(公告)号:US20020156142A1

    公开(公告)日:2002-10-24

    申请号:US09783926

    申请日:2001-02-13

    CPC classification number: C23C14/12 B05D3/068 B05D3/144 B05D7/04

    Abstract: A thermally-stable cationic photoinitiator capable of flash vaporization under vacuum and temperature conditions of an available flash-evaporation chamber is selected. The photoinitiator is mixed with a cation-polymerizable monomer and/or oligomer of interest and the mixture is flash evaporated and condensed in conventional manner as a film on a cold substrate. The resulting vacuum-deposited, homogeneous layer is cured with a high-energy radiation source that causes the cationic photoinitiator to liberate acidic species that catalyze the crosslinking of the monomer/oligomer compounds in its deposited film form. As a result of the homogeneous, pinhole-free nature of the vacuum deposition process, the thin-film polymer product does not suffer from the disadvantages attendant to prior-art atmospheric processes for cationically-cured polymers. In addition, because of the versatility afforded by vacuum deposition, hybrid films of such polymers with inorganic materials are also easily manufactured in-line during the same process.

    Abstract translation: 选择能够在可用的闪蒸室的真空和温度条件下闪蒸的热稳定的阳离子光引发剂。 将光引发剂与感兴趣的阳离子可聚合单体和/或低聚物混合,并将混合物以常规方式闪蒸并冷凝,在薄膜上冷却。 所得到的真空沉积的均匀层用高能量辐射源固化,其使得阳离子光引发剂释放催化以其沉积膜形式的单体/低聚物化合物的交联的酸性物质。 由于真空沉积工艺的均匀的无针孔特性,薄膜聚合物产品不会遭受与现有技术的阳离子固化聚合物的常规方法相关的缺点。 另外,由于通过真空沉积提供的通用性,这种与无机材料的聚合物的混合膜也可以在同一工艺中在线容易地制造。

    Vaccum deposition of cationic polymer systems

    公开(公告)号:US06468595B1

    公开(公告)日:2002-10-22

    申请号:US09783926

    申请日:2001-02-13

    CPC classification number: C23C14/12 B05D3/068 B05D3/144 B05D7/04

    Abstract: A thermally-stable cationic photoinitiator capable of flash vaporization under vacuum and temperature conditions of an available flash-evaporation chamber is selected. The photoinitiator is mixed with a cation-polymerizable monomer and/or oligomer of interest and the mixture is flash evaporated and condensed in conventional manner as a film on a cold substrate. The resulting vacuum-deposited, homogeneous layer is cured with a high-energy radiation source that causes the cationic photoinitiator to liberate acidic species that catalyze the crosslinking of the monomer/oligomer compounds in its deposited film form. As a result of the homogeneous, pinhole-free nature of the vacuum deposition process, the thin-film polymer product does not suffer from the disadvantages attendant to prior-art atmospheric processes for cationically-cured polymers. In addition, because of the versatility afforded by vacuum deposition, hybrid films of such polymers with inorganic materials are also easily manufactured in-line during the same process.

    Method for the application of a decorative layer on a substrate
    68.
    发明授权
    Method for the application of a decorative layer on a substrate 有权
    在基材上施加装饰层的方法

    公开(公告)号:US06406585B1

    公开(公告)日:2002-06-18

    申请号:US09231876

    申请日:1999-02-16

    Inventor: Wilhelm Taubert

    CPC classification number: B44C5/0415 B05D3/061 B05D3/068 B44C5/043 B44C5/0469

    Abstract: In a system for the application of a decorative layer made of a beam-curable coating mass, in particular out of lacquer, glue, adhesive or a mixture of some or all thereof (lacquer and glue, lacquer and adhesive, glue and adhesive, or lacquer, glue and adhesive), on a carrier-plate and/or a web-formed substrate, where the decorative-layer will be treated so long with high-energy radiation particularly UV-radiation, x-ray-radiation, laser-radiation and/or electron radiation, under the maintenance of a certain temperature at normal pressure, so that it will be crosslinked and/or polymerized until the decorative-layer has reached a desired hardness, it is provided, that the decorative layer, which has to be cured, as a shield against the influence of oxygen on one side, it will be covered by the from the substrate formed carrier-plate and on the other side, it will be covered by a foil, for example by a carrier foil, that the radiation of the decorative layer with high-energy, take place in an inert gas-free atmosphere and that a pressure in the heights of atmospheric pressure will be tuned and that during the effective time of the high-energy radiation, this pressure will be maintained.

    Abstract translation: 在用于施加由可光束固化的涂料质量组成的装饰层的系统中,特别是漆,胶,粘合剂或其一部分或全部(漆和胶,漆和粘合剂,胶和粘合剂或 漆,胶和粘合剂),在载体板和/或网状基底上,其中装饰层将被高能量辐射特别是UV辐射,x射线辐射,激光辐射 和/或电子辐射,在常压下保持一定温度下,使其交联和/或聚合,直到装饰层达到所需的硬度为止,装饰层必须 作为抵抗氧气在一侧的影响的屏蔽物,其将被来自基板形成的载体板覆盖,并且在另一侧上将被箔例如载体箔覆盖, 装饰层的辐射高能量,发生 在惰性气体环境中,大气压力的高压将被调整,而在高能辐射的有效时间内,将保持这种压力。

    Method for multi layer enameling and coating compounds for said method
    70.
    发明授权
    Method for multi layer enameling and coating compounds for said method 失效
    用于所述方法的多层搪瓷和涂层化合物的方法

    公开(公告)号:US06333077B1

    公开(公告)日:2001-12-25

    申请号:US09380084

    申请日:1999-11-22

    CPC classification number: B05D7/536 B05D3/065 B05D3/068 C09D201/02

    Abstract: A process for lacquer coating substrates with a colored and/or effect base lacquer and a clear lacquer topcoat, in which a colored and/or effect base lacquer layer of a base lacquer coating composition is applied onto a substrate and is provided in a wet-on-wet process with a clear lacquer coating. Before being jointly stoved or jointly cured with the base lacquer layer, the uncured clear lacquer layer is exposed to high-energy radiation. In the clear lacquer coating composition, the resin solids content contains 50 to 98 wt. % of a system A) thermally curable by addition and/or condensation reactions, which system contains substantially no free-radically polymerisable double bonds and substantially no groups capable of reacting in another way with free-radically polymerisable double bonds of a system B). The resin solids content further contains 2 to 50 wt. % of a system B) which is curable under the action of high-energy radiation by free-radical polymerisation of olefinic double bonds, wherein the weight percentages adds up to 100 wt. % and the C═C equivalent weight of the total resin solids content of A) and B) is between 300 and 10000. Clear lacquer coating compositions made by the process are also described.

    Abstract translation: 一种用彩色和/或效果底漆和透明漆面漆进行涂漆的方法,其中将基漆漆组合物的着色和/或效果基漆层涂覆在基材上, 湿润工艺,清漆漆。 在与基漆层共同烘烤或共同固化之前,未固化的透明漆层暴露于高能辐射。 在透明漆涂料组合物中,树脂固含量为50〜98wt。 通过加成和/或缩合反应可热固化的体系A%),该体系基本上不含可自由基聚合的双键,并且基本上不含能够以另一种方式与体系B)的可自由基聚合的双键反应的基团。 树脂固体含量进一步含有2〜50wt。 系统B的%),其通过烯属双键的自由基聚合在高能辐射的作用下可固化,其中重量百分比加到100重量% %,A)和B)的总树脂固体含量的C = C当量为300至10000.还描述了通过该方法制备的透明漆涂料组合物。

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