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公开(公告)号:US08960123B2
公开(公告)日:2015-02-24
申请号:US14138542
申请日:2013-12-23
Applicant: Enki Technology, Inc.
Inventor: Brenor L. Brophy , Sina Maghsoodi , Patrick J. Neyman , Peter R. Gonsalves , Jeffrey G. Hirsch , Yu S. Yang
CPC classification number: B05D1/28 , B05C1/003 , B05C1/025 , B05C1/0817 , B05C1/083 , B05C1/0834 , B05C1/0847 , B05C1/0856 , B05C1/0878 , B05C1/0882 , B05C11/025 , B05C11/06 , B05C11/1042 , B05D3/002 , B05D3/007 , B05D3/08 , B05D3/142 , C03C17/00 , C23C18/1241 , C23C18/1254 , C23C18/1283 , Y10T428/249969 , Y10T428/265
Abstract: Disclosed are coating apparatus including flow coating and roll-coating that may be used for uniform sol-gel coating of substrates such as glass, solar panels, windows or part of an electronic display. Also disclosed are methods for substrate preparation, flow coating and roll coating. Lastly systems and methods for skin curing sol-gel coatings deposited onto the surface of glass substrates using a high temperature air-knife are disclosed.
Abstract translation: 公开了包括流动涂布和辊涂的涂布设备,其可以用于诸如玻璃,太阳能电池板,窗户或电子显示器的一部分的基底的均匀溶胶 - 凝胶涂覆。 还公开了用于底物制备,流涂和辊涂的方法。 最后,公开了使用高温气刀将沉积在玻璃基板表面上的溶胶 - 凝胶涂层进行皮肤固化的系统和方法。
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公开(公告)号:US20140227507A1
公开(公告)日:2014-08-14
申请号:US14138542
申请日:2013-12-23
Applicant: Enki Technology, Inc.
Inventor: Brenor L. Brophy , Sina Maghsoodi , Patrick J. Neyman , Peter R. Gonsalves , Jeffrey G. Hirsch , Yu S. Yang
CPC classification number: B05D1/28 , B05C1/003 , B05C1/025 , B05C1/0817 , B05C1/083 , B05C1/0834 , B05C1/0847 , B05C1/0856 , B05C1/0878 , B05C1/0882 , B05C11/025 , B05C11/06 , B05C11/1042 , B05D3/002 , B05D3/007 , B05D3/08 , B05D3/142 , C03C17/00 , C23C18/1241 , C23C18/1254 , C23C18/1283 , Y10T428/249969 , Y10T428/265
Abstract: Disclosed are coating apparatus including flow coating and roll-coating that may be used for uniform sol-gel coating of substrates such as glass, solar panels, windows or part of an electronic display. Also disclosed are methods for substrate preparation, flow coating and roll coating. Lastly systems and methods for skin curing sol-gel coatings deposited onto the surface of glass substrates using a high temperature air-knife are disclosed.
Abstract translation: 公开了包括流动涂布和辊涂的涂布设备,其可以用于诸如玻璃,太阳能电池板,窗户或电子显示器的一部分的基底的均匀溶胶 - 凝胶涂覆。 还公开了用于底物制备,流涂和辊涂的方法。 最后,公开了使用高温气刀将沉积在玻璃基板表面上的溶胶 - 凝胶涂层进行皮肤固化的系统和方法。
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公开(公告)号:US09688863B2
公开(公告)日:2017-06-27
申请号:US15182729
申请日:2016-06-15
Applicant: Enki Technology, Inc.
Inventor: Sina Maghsoodi , Brenor L. Brophy , Thomas E. Colson , Peter R. Gonsalves , Ze'ev R. Abrams
IPC: C09D173/00 , C09D5/00 , G02B1/11 , C03C17/30 , C09D183/08 , G02B1/111 , G02B1/12 , H01L31/0216 , H01L31/18 , H01L33/00 , H01L33/44 , C09D183/04 , C09D7/12 , G02B5/02 , C08K3/36 , G02B1/14
CPC classification number: C09D5/006 , C03C17/007 , C03C17/30 , C03C2217/20 , C03C2217/425 , C03C2217/45 , C03C2217/465 , C03C2217/47 , C03C2217/732 , C08K3/36 , C09D7/61 , C09D173/00 , C09D183/04 , C09D183/08 , G02B1/11 , G02B1/111 , G02B1/12 , G02B1/14 , G02B5/021 , G02B5/0215 , G02B5/0221 , H01L31/02168 , H01L31/18 , H01L33/005 , H01L33/44 , Y02E10/50 , Y02P20/582
Abstract: Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers, Si—OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.
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公开(公告)号:US09314811B1
公开(公告)日:2016-04-19
申请号:US14709031
申请日:2015-05-11
Applicant: Enki Technology, Inc.
Inventor: Brenor L. Brophy , Peter R. Gonsalves , Sina Maghsoodi , Thomas E. Colson , Yu S. Yang , Ze'ev R. Abrams
CPC classification number: B05C9/14 , B05C1/08 , B05C1/0817 , B05C1/083 , B05C1/0856 , B05C1/0865 , B05C5/007 , B05C5/0254 , B05C11/025 , B05C11/08 , B05C11/1005 , B05C11/1039 , C23C18/1254 , C23C18/22 , H01L31/18
Abstract: Disclosed is a coating apparatus including flow coating and roll-coating that may be used for uniform sol-gel coating of substrates such as glass, solar panels, windows or part of an electronic display. Also disclosed are methods for substrate preparation, flow coating and roll coating. Lastly, systems and methods for curing sol-gel coatings deposited onto the surface of glass substrates using high temperature air-knives, infrared emitters and direct heat applicators are disclosed.
Abstract translation: 公开了一种涂布设备,其包括流涂和辊涂,其可用于诸如玻璃,太阳能电池板,窗户或电子显示器的一部分的基底的均匀溶胶 - 凝胶涂覆。 还公开了用于底物制备,流涂和辊涂的方法。 最后,公开了使用高温空气刀,红外线发射器和直接加热器来固化沉积在玻璃基底表面上的溶胶 - 凝胶涂层的系统和方法。
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公开(公告)号:US20150099060A1
公开(公告)日:2015-04-09
申请号:US14563962
申请日:2014-12-08
Applicant: Enki Technology, Inc.
Inventor: Brenor L. Brophy , Peter R. Gonsalves , Yu S. Yang , Patrick J. Neyman
CPC classification number: B05D1/28 , B05C1/003 , B05C1/025 , B05C1/0817 , B05C1/083 , B05C1/0834 , B05C1/0847 , B05C1/0856 , B05C1/0878 , B05C1/0882 , B05C11/025 , B05C11/06 , B05C11/1042 , B05D3/002 , B05D3/007 , B05D3/08 , B05D3/142 , C03C17/00 , C23C18/1241 , C23C18/1254 , C23C18/1283 , Y10T428/249969 , Y10T428/265
Abstract: Disclosed herein is a method of coating and curing, including conveying a substantially flat substrate to be coated with a conveyor system through a combination roll coating and curing facility, wherein the combination roll coating and curing facility comprises at least one roll coating facility and at least one curing facility, roll coating the substantially flat substrate with a continuous sol gel coating material with the at least one roll coating facility, and curing the sol gel coating material on the substantially flat substrate with an air knife of the at least one curing facility, wherein the air knife is adapted to direct a heated stream of air to cure the continuous sol gel coating material while an interior of the substantially flat substrate remains at a temperature substantially lower than a temperature of air from the air knife.
Abstract translation: 本文公开了一种涂覆和固化的方法,包括通过组合辊涂和固化设备输送要涂覆有传送系统的基本平坦的基材,其中组合辊涂和固化设备包括至少一个辊涂设备,并且至少 一个固化设备,用具有至少一个辊涂设备的连续溶胶凝胶涂覆材料辊涂基本上平坦的基材,并且用至少一个固化设备的气刀将基本平坦的基材上的溶胶凝胶涂料固化, 其中所述气刀适于引导加热的空气流以固化连续溶胶凝胶涂层材料,同时基本上平坦的基底的内部保持在基本上低于来自气刀的空气的温度的温度。
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公开(公告)号:US20160289457A1
公开(公告)日:2016-10-06
申请号:US15182729
申请日:2016-06-15
Applicant: Enki Technology, Inc.
Inventor: Sina Maghsoodi , Brenor L. Brophy , Thomas E. Colson , Peter R. Gonsalves , Ze'ev R. Abrams
IPC: C09D5/00 , G02B1/111 , C03C17/30 , C09D183/08 , C09D7/12
CPC classification number: C09D5/006 , C03C17/007 , C03C17/30 , C03C2217/20 , C03C2217/425 , C03C2217/45 , C03C2217/465 , C03C2217/47 , C03C2217/732 , C08K3/36 , C09D7/61 , C09D173/00 , C09D183/04 , C09D183/08 , G02B1/11 , G02B1/111 , G02B1/12 , G02B1/14 , G02B5/021 , G02B5/0215 , G02B5/0221 , H01L31/02168 , H01L31/18 , H01L33/005 , H01L33/44 , Y02E10/50 , Y02P20/582
Abstract: Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers, Si—OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.
Abstract translation: 本文公开了基于聚倍半硅氧烷的抗反射涂层(ARC)组合物,制备方法和沉积在基材上的方法。 在一个实施方案中,本公开的聚倍半硅氧烷是以有机烷氧基硅烷的酸催化水解的两步法制备的,然后加入基于Si-NMR产生具有> 40mol%硅烷醇的硅氧烷聚合物的四氢化烷氧基硅烷。 这些高硅烷醇硅氧烷聚合物是稳定的,并且在室温下在极性有机溶剂中具有长的保质期。 还公开了由具有和不具有添加剂的这些组合物制成的低折射率ARC,例如致孔剂,模板,热自由基引发剂,光自由基引发剂,交联剂,Si-OH缩合催化剂和纳米填料。 还公开了用于将涂层施加到平面基板上的方法和装置,包括基板预处理工艺,涂覆工艺和涂层固化工艺,包括使用热风刀的皮肤固化。 还公开了用于高度可调,耐用,高耐磨性的功能化抗反射涂层的涂料组合物和制剂。
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公开(公告)号:US09399720B2
公开(公告)日:2016-07-26
申请号:US14799507
申请日:2015-07-14
Applicant: Enki Technology, Inc.
Inventor: Sina Maghsoodi , Brenor L. Brophy , Thomas E. Colson , Peter R. Gonsalves , Ze'ev R. Abrams
IPC: C09D183/00 , C09D173/00 , C09D5/00 , G02B1/11 , C03C17/30 , C09D183/08 , G02B1/111 , G02B1/12 , H01L31/0216 , H01L31/18 , H01L33/00 , H01L33/44
CPC classification number: C09D5/006 , C03C17/007 , C03C17/30 , C03C2217/20 , C03C2217/425 , C03C2217/45 , C03C2217/465 , C03C2217/47 , C03C2217/732 , C08K3/36 , C09D7/61 , C09D173/00 , C09D183/04 , C09D183/08 , G02B1/11 , G02B1/111 , G02B1/12 , G02B1/14 , G02B5/021 , G02B5/0215 , G02B5/0221 , H01L31/02168 , H01L31/18 , H01L33/005 , H01L33/44 , Y02E10/50 , Y02P20/582
Abstract: Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers, Si—OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.
Abstract translation: 本文公开了基于聚倍半硅氧烷的抗反射涂层(ARC)组合物,制备方法和沉积在基材上的方法。 在一个实施方案中,本公开的聚倍半硅氧烷是以有机烷氧基硅烷的酸催化水解的两步法制备的,然后加入基于Si-NMR产生具有> 40mol%硅烷醇的硅氧烷聚合物的四氢化烷氧基硅烷。 这些高硅烷醇硅氧烷聚合物是稳定的,并且在室温下在极性有机溶剂中具有长的保质期。 还公开了由具有和不具有添加剂的这些组合物制成的低折射率ARC,例如致孔剂,模板,热自由基引发剂,光自由基引发剂,交联剂,Si-OH缩合催化剂和纳米填料。 还公开了用于将涂层施加到平面基板上的方法和装置,包括基板预处理工艺,涂覆工艺和涂层固化工艺,包括使用热风刀的皮肤固化。 还公开了用于高度可调,耐用,高耐磨性的功能化抗反射涂层的涂料组合物和制剂。
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公开(公告)号:US09376593B2
公开(公告)日:2016-06-28
申请号:US14856601
申请日:2015-09-17
Applicant: Enki Technology, Inc.
Inventor: Sina Maghsoodi , Brenor L. Brophy , Ze'ev R. Abrams , Peter R. Gonsalves
IPC: B32B17/06 , C03C17/30 , C09D183/04 , C03C17/34 , C09D5/00 , C09D7/12 , C03C17/00 , C09D5/16 , C09D183/08 , C08G77/24 , C08K3/36
CPC classification number: C09D183/04 , C03C17/007 , C03C17/3405 , C03C17/42 , C03C2203/27 , C03C2217/425 , C03C2217/73 , C03C2217/732 , C03C2217/76 , C03C2217/78 , C03C2218/113 , C03C2218/34 , C08G77/24 , C08K3/36 , C09D5/006 , C09D5/1662 , C09D7/61 , C09D7/63 , C09D183/08 , Y10T428/265 , Y10T428/31612
Abstract: Disclosed herein are coating materials and methods for applying a top-layer coating that is durable, abrasion resistant, highly transparent, hydrophobic, low-friction, moisture-sealing, anti-soiling, and self-cleaning to an existing conventional high temperature anti-reflective coating. The top coat imparts superior durability performance and new properties to the under-laying conventional high temperature anti-reflective coating without reducing the anti-reflectiveness of the coating. Methods and data for optimizing the relative thickness of the under-layer high temperature anti-reflective coating and the top-layer thickness for optimizing optical performance are also disclosed.
Abstract translation: 本文公开了用于将耐用,耐磨,高度透明,疏水,低摩擦,湿气密封,防污染和自清洁的顶层涂层施加到现有常规高温抗蚀剂的涂料和方法, 反光涂层。 顶层涂层赋予了低成本的常规高温抗反射涂层优异的耐久性能和新特性,而不会降低涂层的抗反射性。 还公开了用于优化底层高温抗反射涂层的相对厚度和优化光学性能的顶层厚度的方法和数据。
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公开(公告)号:US09376589B2
公开(公告)日:2016-06-28
申请号:US14799479
申请日:2015-07-14
Applicant: Enki Technology, Inc.
Inventor: Sina Maghsoodi , Brenor L. Brophy , Thomas E. Colson , Peter R. Gonsalves , Ze'ev R. Abrams
IPC: C09D173/00 , C09D5/00 , G02B1/11
CPC classification number: C09D5/006 , C03C17/007 , C03C17/30 , C03C2217/20 , C03C2217/425 , C03C2217/45 , C03C2217/465 , C03C2217/47 , C03C2217/732 , C08K3/36 , C09D7/61 , C09D173/00 , C09D183/04 , C09D183/08 , G02B1/11 , G02B1/111 , G02B1/12 , G02B1/14 , G02B5/021 , G02B5/0215 , G02B5/0221 , H01L31/02168 , H01L31/18 , H01L33/005 , H01L33/44 , Y02E10/50 , Y02P20/582
Abstract: Disclosed herein are single layer transparent coatings with an anti-reflective property, a hydrophobic property, and that are highly abrasion resistant. The single layer transparent coatings contain a plurality of oblate voids. At least 1% of the oblate voids are open to a surface of the single layer transparent coatings.
Abstract translation: 本文公开了具有抗反射性,疏水性,并且具有高耐磨性的单层透明涂层。 单层透明涂层含有多个扁圆形的空隙。 至少1%的扁圆形空隙对单层透明涂层的表面开放。
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公开(公告)号:US20160032147A1
公开(公告)日:2016-02-04
申请号:US14799507
申请日:2015-07-14
Applicant: Enki Technology, Inc.
Inventor: Sina Maghsoodi , Brenor L. Brophy , Thomas E. Colson , Peter R. Gonsalves , Ze'ev R. Abrams
IPC: C09D183/08 , G02B1/12 , C03C17/30 , H01L33/00 , H01L31/0216 , H01L31/18 , G02B1/111 , H01L33/44
CPC classification number: C09D5/006 , C03C17/007 , C03C17/30 , C03C2217/20 , C03C2217/425 , C03C2217/45 , C03C2217/465 , C03C2217/47 , C03C2217/732 , C08K3/36 , C09D7/61 , C09D173/00 , C09D183/04 , C09D183/08 , G02B1/11 , G02B1/111 , G02B1/12 , G02B1/14 , G02B5/021 , G02B5/0215 , G02B5/0221 , H01L31/02168 , H01L31/18 , H01L33/005 , H01L33/44 , Y02E10/50 , Y02P20/582
Abstract: Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol % silanol based on Si-NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers, Si—OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.
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