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公开(公告)号：US12290799B2
公开(公告)日：2025-05-06
申请号：US17857503
申请日：2022-07-05
Inventor： Rajesh Kumar Parsapur , Robert P. Hodgkins , Omer Refa Koseoglu , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari
Abstract: A composition of matter is provided comprising hierarchically ordered crystalline microporous material having well-defined long-range mesoporous ordering of hexagonal symmetry. The composition possesses mesopores having walls of crystalline microporous material and a mass of mesostructure between mesopores of crystalline microporous material. Long-range ordering is defined by presence of secondary peaks in an X-ray diffraction (XRD) pattern and/or hexagonal symmetry observable by microscopy.
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公开(公告)号：US20240416333A1
公开(公告)日：2024-12-19
申请号：US18335719
申请日：2023-06-15
Inventor： Robert Peter Hodgkins , Omer Refa Koseoglu , Kuo-Wei Huang , Magnus Rueping , Manoja K. Samantaray , Rajesh Kumar Parsapur , Anissa Bendjeriou Sedjerari
Abstract: Modified zeolites may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm, wherein the plurality of mesopores are ordered with cubic symmetry. The modified zeolite may include a plurality of hafnium hydride moieties each bonded to at least two bridging oxygen atoms, wherein a hafnium atom of the hafnium hydride is bonded to the bridging oxygen atom, and wherein the bridging oxygen atom bridges the hafnium atom of the hafnium hydride moiety and a silicon atom of the microporous framework.
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公开(公告)号：US11834340B2
公开(公告)日：2023-12-05
申请号：US17230560
申请日：2021-04-14
Inventor： Robert Peter Hodgkins , Omer Refa Koseoglu , Kuo-Wei Huang , Jean-Marie Maurice Basset , Yu Han , Rajesh Parsapur , Anissa Bendjeriou Sedjerari , Sathiyamoorthy Murugesan
IPC: B01J29/40 , C01B39/40 , B01J29/04 , B01J29/48 , B01J29/46 , B01J29/42 , C01B39/06 , B01J29/44 , B01J35/10 , B01J35/02
CPC classification number: C01B39/40 , B01J29/04 , B01J29/041 , B01J29/042 , B01J29/043 , B01J29/045 , B01J29/046 , B01J29/047 , B01J29/048 , B01J29/405 , B01J29/42 , B01J29/44 , B01J29/46 , B01J29/48 , B01J35/023 , B01J35/109 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1057 , B01J35/1061 , C01B39/06 , C01B39/065 , B01J2229/183 , C01P2002/01 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C01P2006/16
Abstract: Embodiments of the present disclosure relate to zeolites and method for making such zeolites. According to embodiments disclosed herein, a zeolite may have a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm and a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm. The microporous framework may include an MFI framework type. The microporous framework may include silicon atoms, aluminum atoms, oxygen atoms, and transition metal atoms. The transition metal atoms may be dispersed throughout the entire microporous framework.
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公开(公告)号：US11753307B2
公开(公告)日：2023-09-12
申请号：US17230532
申请日：2021-04-14
Inventor： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Sathiyamoorthy Murugesan , Manouj K. Gangwar
CPC classification number: C01B39/40 , B01J29/405 , B01J35/023 , B01J35/1061 , B01J35/1066 , B01J37/0203 , B01J37/16 , C01B39/026 , C01P2002/72 , C01P2002/82 , C01P2002/86 , C01P2004/03 , C01P2004/04 , C01P2004/62 , C01P2004/64 , C01P2006/16
Abstract: Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to a nitrogen atom of a secondary amine functional group comprising a nitrogen atom and a hydrogen atom. The organometallic moieties may comprise a hafnium atom that is bonded to the nitrogen atom of the secondary amine functional group. The nitrogen atom of the secondary amine function group may bridge the hafnium atom of the organometallic moiety and a silicon atom of the microporous framework.
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公开(公告)号：US20230085197A1
公开(公告)日：2023-03-16
申请号：US17412732
申请日：2021-08-26
Inventor： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Sathiyamoorthy Murugesan , Manoj Kumar Gangwar
Abstract: A functionalized fibrous hierarchical zeolite includes a framework comprising aluminum atoms, silicon atoms, and oxygen atoms, the framework further comprising a plurality of micropores and a plurality of mesopores. The functionalized fibrous hierarchical zeolite is functionalized with at least one terminal amine bonded to a silicon atom. Terminal organometallic functionalities are bonded to a nitrogen atom of the at least one terminal amine, the terminal organometallic functionalities comprising a platinum atom.
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Patent Agency Ranking
公开(公告)号：US11591230B2
公开(公告)日：2023-02-28
申请号：US17231191
申请日：2021-04-15
Inventor： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Manoj K. Gangwar , Sathiyamoorthy Murugesan
Abstract: Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework includes at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties include a hafnium atom. The hafnium atom is bonded to a bridging oxygen atom, and bridging oxygen atom bridges the hafnium atom of the organometallic moiety and a silicon atom of the microporous framework.
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公开(公告)号：US20220340433A1
公开(公告)日：2022-10-27
申请号：US17230500
申请日：2021-04-14
Inventor： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Manoj K. Gangwar , Sathiyamoorthy Murugesan
Abstract: Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework comprising a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties may include a titanium atom. The titanium atom may be bonded to a bridging oxygen atom, and the bridging oxygen atom may bridge the titanium atom of the organometallic moiety and a silicon atom of the microporous framework.
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公开(公告)号：US11097243B2
公开(公告)日：2021-08-24
申请号：US16670243
申请日：2019-10-31
Inventor： Kuo-Wei Huang , Zhiping Lai
IPC: B01J16/00 , B01J8/02 , B01J8/00 , B01J23/46 , C07C67/40 , B01J31/18 , C07C67/00 , B01J15/00 , B01J19/24
Abstract: Embodiments include a system that may include a reactor including a reaction zone and a gas release zone separated by a selectively permeable membrane, wherein the selectively permeable membrane permits hydrogen to pass through the membrane and substantially blocks a substrate and its dehydrogenative coupling product from passing through the membrane. Embodiments further include a method of producing a dehydrogenative coupling product, wherein the method may include exposing a substrate to a catalyst in a reaction zone of a reactor; coupling the substrate to form the dehydrogenative coupling product and hydrogen; and separating the hydrogen from the dehydrogenative coupling product using a selectively permeable membrane and passing the hydrogen to a gas release zone of the reactor.
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公开(公告)号：US10399072B2
公开(公告)日：2019-09-03
申请号：US15510119
申请日：2015-09-09
Inventor： Kuo-Wei Huang , Qianyi Zhao
IPC: B01J31/18 , C07F9/58 , B01J31/12 , C07C29/14 , C07C29/15 , C07D317/36 , C07F15/04 , C07C231/10 , C07C29/09 , B01J31/02 , B01J37/04
Abstract: The invention describes phospho-amino pincer-type ligands, metal complexes thereof, and catalytic methods comprising such metal complexes for conversion of carbon dioxide to methanol, conversion of aldehydes into alcohols, conversion of aldehydes in the presence of a trifluoromethylation agent into trifluorinated secondary alcohols, cycloaddition of carbon dioxide to an epoxide to provide cyclic carbonates or preparation of an amide from the combination of an alcohol and an amine.
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公开(公告)号：US20250121364A1
公开(公告)日：2025-04-17
申请号：US18485844
申请日：2023-10-12
Inventor： Rajesh Kumar Parsapur , Robert Peter Hodgkins , Omer Refa Koseoglu , Kuo-Wei Huang , Magnus Rueping , Anissa Bendjeriou Sedjerari
Abstract: According to one or more embodiments, a zeolite beta material may be made by a method that may include adding a parent zeolite beta in a basic solution to form a basic zeolite beta suspension, adding water to the basic zeolite beta suspension to form a dilute basic zeolite beta suspension, hydrothermally treating the dilute basic zeolite beta suspension to form a hydrothermally treated mixture, and separating from the hydrothermally treated mixture a solid zeolite beta material consisting essentially of polymorph-A and polymorph-B. The molar ratio of polymorph-A to polymorph-B of the solid zeolite beta material may be greater than molar ratio of polymorph-A to polymorph-B of the parent zeolite beta.
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