METHOD FOR PRODUCING ALKYLARYL COMPOUNDS
    2.
    发明申请
    METHOD FOR PRODUCING ALKYLARYL COMPOUNDS 审中-公开
    用于生产烷CONNECTIONS

    公开(公告)号:WO2005061447A3

    公开(公告)日:2007-01-04

    申请号:PCT/EP2004014444

    申请日:2004-12-17

    Abstract: The production of alkylaryl compounds comprises the following stages: a) reaction of a C4/C5 olefin mixture on a metathesis catalyst to produce a C 4-8 olefin mixture containing 2-pentene and the optional isolation of the C 4-8 olefin mixture; b) isolation of between 5 and 100 % of the 2-pentene obtained in step a) and subsequent reaction on an isomerisation catalyst to form a mixture of 2-pentene and 1-pentene, which is returned to stage a); c) dimerisation of the C 4-8 olefin mixture obtained in stage b) after the isolation process, to form a mixture containing C 8-16 olefins, isolation of the C 8-16 olefins and optional isolation of a partial stream of the latter; d) reaction of the C 8-16 olefin mixtures obtained in stage c) or the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst, to form alkyl aromatic compounds, whereby prior to the reaction an additional 0 to 60 wt. % linear olefins, in relation to the C 8-16 olefin mixtures obtained in stage c), can be added; e) optional sulphonation of the alkyl aromatic compounds obtained in stage d) and neutralisation to form alkylaryl sulphonates, whereby prior to the sulphonation an additional 0 to 60 wt. % linear alkyl benzols, in relation to the alkyl aromatic compounds obtained in stage d), can be added, provided that there were no admixtures in stage d); f) optional mixing of the alkylaryl sulphonates obtained in stage e) with between 0 and 60 wt. %, linear alkylaryl sulphonates, in relation to the alkylaryl sulphonates obtained in stage e), provided that there were no admixtures in stages d) and e).

    Abstract translation: 烷基芳基化合物通过C4 / C5烯烃混合物的超过一个C含有2-戊烯 4-8 烯烃混合物的制备复分解催化剂的C 的)反应,和可选地移除该制剂 4-8 烯烃混合物,b)中的5%至100%的分离在步骤a)所得2-戊烯和异构化催化剂的2-戊烯与1-戊烯的混合物随后的反应,在阶段a) 再循环,C)C的分离之后,在步骤b中得到的二聚) 4-8 在二聚催化剂存在下烯烃混合物,得到含烯烃-C 8-16 混合物, 的C 8-16 烯烃,和任选除去一个部分流体,D)在步骤C中获得的化合物反应)C 8-16 烯烃混合物或所述部分与芳族料流的分离 在烷基化催化剂的存在下烃以形成烷基芳香族Ve的 rbindungen,其中烯烃,e)可以反应,0〜60重量%之前添加到直链烯烃,基于在步骤c得到的)C在磺化 8-16,任选地 获得步骤d)的烷基芳族化合物中和以得到烷基芳基磺酸盐,其中之前的磺化,0至60重量%,基于在步骤d)中获得的烷基,可被加入到直链烷基苯的芳族化合物中,如果在步骤d没有掺合)下进行 中,f)如果到60重量%)的0)在步骤e中得到的烷基芳基磺酸盐的适当的混合,基于在步骤e烷芳基磺酸盐所获得的),线性烷基芳基磺酸盐,如果在步骤没有外加剂d)和e被执行。

    6.
    发明专利
    未知

    公开(公告)号:AT385845T

    公开(公告)日:2008-03-15

    申请号:AT02740529

    申请日:2002-04-26

    Applicant: BASF AG

    Abstract: A reactor (1) having a vertical longitudinal axis and an inlet (2) for a liquid or liquid/solid feed stream in the upper region of the reactor and an inlet (3) for a gaseous stream in the lower region of the reactor (1), characterized by at least two chambers (4) arranged above one another in the longitudinal direction, where the chambers (4) are separated from one another by liquid-tight bottom plates, each chamber is connected via a liquid overflow (6) to the chamber (4) located immediately underneath and a liquid product stream is taken off via the liquid overflow (6) of the bottommost chamber (4), the gas space (7) above the liquid surface in each chamber (4) is connected to the chamber (4) located immediately above it by one or more guide tubes (8) which opens (each open) into a gas distributor (9) provided with openings for exit of gas below the liquid surface, and each chamber is provided with at least one guide plate (12) which is arranged vertically around each siphon like gas distributor (9) and whose upper end is below the liquid surface and whose lower end is above the liquid-tight bottom plate (5) of the chamber (4) and which divides each chamber (4) into one or more spaces into which gas flows (13) and one or more spaces into which gas does not flow (14), is used for gas/liquid or gas/liquid/solid reactions.

    10.
    发明专利
    未知

    公开(公告)号:BRPI0409375A

    公开(公告)日:2006-04-25

    申请号:BRPI0409375

    申请日:2004-04-14

    Applicant: BASF AG

    Abstract: Production of alkylaromatic compounds (I), by reacting 3-30C olefins (II) (or alcohols forming (II) under the reaction conditions) with aromatic hydrocarbons (III) in presence of an alkylation catalyst (IV), is carried out in a cascade of at least two reactors each containing (IV), where at least 80 % of (III) is supplied to the first reactor of the cascade and at least 40 % of (II) is supplied after the first reactor. An independent claim is included for the preparation of alkylarylsulfonates (A), by: (1) converting a 4C olefin mixture over a metathesis catalyst to give an olefin mixture containing 2-pentene and/or 2-hexene; (2) catalytically dimerizing the 2-pentene and/or 2-hexene (optionally after isolation) to give a mixture containing 10-12C olefins, optionally separating the 10-12C olefins and separating 5-30 wt. % (based on the 10-12C olefins) of low-boiling components of the 10-12C olefins; (3) reacting the obtained 10-12C olefin mixture with (III) in presence of (IV) to give alkylaromatic compounds (I'), optionally with addition of 0-60 wt. % (based on the 10-12C olefin mixture) of linear olefins before the reaction; (4) sulfonating (I') and neutralizing to give (A), optionally with addition of 0-60 wt. % (based on (I')) of linear alkylbenzenes (provided that no mixing has been carried out in the previous step); and (5) optionally mixing the obtained (A) with optionally with addition of 0-60 wt. % (based on (A)) of linear aralkylsulfonates (provided that no mixing has been carried out either of the previous two steps); The novel feature being that the reaction in the alkylation stage (3) is carried out as for the present procedure for preparing (I).

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