公开(公告)号：DE3151041A1

公开(公告)日：1983-07-28

申请号：DE3151041

申请日：1981-12-23

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  GEHM ROBERT DIPL CHEM DR ,  FRANK WOLFRAM DIPL CHEM DR ,  MARX MATTHIAS DIPL CHEM DR

IPC: C08G18/18 ,  C08G18/14

Abstract: The invention describes a process for harmonizing the reaction rates for the formation of urethane and isocyanurate groups during the preparation of polyurethane-polyisocyanurate foams by reacting organic polyisocyanates with polyols in the presence of blowing agents and salts of amines having the formula as catalysts, wherein R stands for an hydrogen atom or a straight chained or branched alkyl radical with 1 to 19 carbon atoms, and n and m are equal or different whole numbers from 2 to 10.

公开(公告)号：DE2964667D1

公开(公告)日：1983-03-10

申请号：DE2964667

申请日：1979-05-28

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  SCHOEN ERNST DR ,  REICH ERHARDT DR ,  VOLKERT OTTO DR

IPC: C08G18/00 ,  C08G18/16 ,  C08G18/18 ,  C08G18/22 ,  C08G18/72 ,  C08G18/73 ,  C08G18/75 ,  C08G18/78 ,  C08G18/80 ,  C08G18/14

Abstract: To prepare light-stable polyurethane integral skin foams, especially soft integral foams, aliphatic and/or cycloaliphatic polyisocyanates, both categories preferably containing urethane groups and/or biuret groups, are reacted with polyols in the presence of blowing agents and of a synergistic catalyst combination comprising an alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and/or hexahydrotriazine derivative and an organic tin, zinc and/or iron(II) compound, in the presence or absence of assistants and adjuvants. The preferred catalyst combination is tri-(dimethylaminopropyl)-s-hexahydrotriazine and dibutyl-tin dilaurate.

公开(公告)号：DE3269728D1

公开(公告)日：1986-04-10

申请号：DE3269728

申请日：1982-12-06

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  GEHM ROBERT DR ,  FRANK WOLFRAM DR ,  MARX MATTHIAS DR

IPC: C08G18/18

Abstract: The invention describes a process for harmonizing the reaction rates for the formation of urethane and isocyanurate groups during the preparation of polyurethane-polyisocyanurate foams by reacting organic polyisocyanates with polyols in the presence of blowing agents and salts of amines having the formula as catalysts, wherein R stands for an hydrogen atom or a straight chained or branched alkyl radical with 1 to 19 carbon atoms, and n and m are equal or different whole numbers from 2 to 10.

公开(公告)号：DE3306373A1

公开(公告)日：1984-08-30

申请号：DE3306373

申请日：1983-02-24

Applicant: BASF AG

Inventor： BUELTJER UWE DR ,  HORACEK HEINRICH DR ,  DRUSCHKE WOLFGANG DR ,  FRANZMANN GERNOT DR ,  KLAHR ERHARD DR ,  FOERSTER HANS-JUERGEN DR

IPC: C08G18/10 ,  C08L75/04 ,  C08K5/09 ,  C08K5/29 ,  C08K5/42 ,  C09D3/72 ,  C09D5/34 ,  C09J3/16 ,  C09K3/10

Abstract: The subject of the invention is constituted by moisture-curing, storage-stable single-component polyurethane systems which contain A) a polyurethane prepolymer having an NCO content of 1 to 5 wt.%, B) a dialdimine of the formula in which R is an alkylene radical having 2 to 10 C atoms, an alkylene radical, having 4 to 10 C atoms, containing oxygen and/or an N-alkyl group as bridge member, a cycloalkylene radical having 6 to 15 C atoms or an arylene radical having 6 to 21 C atoms, and C) an aromatic and/or aliphatic carboxylic acid or toluene-sulphonic acid. The polyurethane systems are used as coating, covering, sealing, grouting, puttying and bonding compositions.

公开(公告)号：DE3216363A1

公开(公告)日：1983-11-03

申请号：DE3216363

申请日：1982-05-03

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  WITTMANN OTTO DIPL ING ,  MARX MATTHIAS DIPL CHEM DR ,  MAYER JOHANN DIPL CHEM DR

IPC: C08G18/10 ,  C08G18/54 ,  C08G18/76 ,  C08G18/80 ,  C08L97/02 ,  C09J175/04 ,  B29J5/00

Abstract: A process for bonding lignocellulose raw materials using an isocyanate group-containing urethane-modified diphenylmethane diisocyanate mixture having a viscosity of 120 to 1000 mPas at 25 DEG C. and an isocyanate content of 15 to 33.6 percent by weight which is obtained by reacting a diphenylmethane diisocyanate mixture containing 10 to 75 percent by weight of 2,4'-diphenylmethane diisocyanate with 0.05 to 0.5 hydroxyl equivalents of a polyol per equivalent isocyanate group.

公开(公告)号：DE3125402A1

公开(公告)日：1983-01-13

申请号：DE3125402

申请日：1981-06-27

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  BUETHE INGOLF DIPL CHEM DR ,  MARX MATTHIAS DIPL CHEM DR

IPC: C08G18/08 ,  C08G18/40 ,  C08J9/00 ,  C08L75/02 ,  C08G18/14 ,  C08L3/06 ,  C08L67/02 ,  C08L71/02

Abstract: The invention relates to polyurea-polyol dispersions with a long shelf life which contain a) from 2 to 35 % by weight, based on the entire dispersion, of a polyurea prepared from modified aliphatic and/or cycloaliphatic polyisocyanates and aliphatic amines and/or optionally substituted monoaminobenzenes or modified aromatic polyisocyanates and aliphatic amines and, b) from 98 to 65 % by weight, based on the entire dispersion, of a bifunctional to hexafunctional polyol having a hydroxyl number of from 20 to 600. The dispersions are prepared by in-situ reaction of the modified polyisocyanates with aliphatic amines and/or monoaminobenzenes in polyols, have, at a polyurea content of 10 % by weight, a viscosity at 25 DEG C of from 1000 to 2500 mPa.s and a clear point of from 100 to 300 DEG C and are particularly suitable for the production of polyurethane foams.

公开(公告)号：DE3021293A1

公开(公告)日：1981-12-24

申请号：DE3021293

申请日：1980-06-06

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  MARX MATTHIAS DIPL CHEM DR ,  BUETHE INGOLF DIPL CHEM DR ,  JARRE WOLFGANG DIPL CHEM DR ,  SCHOEN ERNST DIPL CHEM DR

IPC: C08G18/28 ,  C08G18/14 ,  C08G18/65

Abstract: The process involves the reaction of organic polyisocyanates, polyols, optionally substituted aliphatic and/or cycloaliphatic monoamines in an amount of from 0.1 to 10 parts by weight per 100 parts by weight of polyol, and/or optionally substituted aromatic monoamines in an amount of from 0.1 to 4 parts by weight per 100 parts by weight of polyol, and, if desired, chain extenders or crosslinking agents, in the presence of blowing agents, catalysts, assistants and, if desired, additives.

公开(公告)号：DE3245678A1

公开(公告)日：1984-06-14

申请号：DE3245678

申请日：1982-12-10

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  HUMMERICH RAINER DR ,  OHLINGER RAINER DR ,  WENNER GOTTHILF DR ,  FUESSL RUEDIGER

IPC: C07C265/12 ,  C08G18/10 ,  C08G18/69 ,  C08G18/76 ,  C09J107/00 ,  C09J175/00 ,  C07C119/048 ,  C09J3/12 ,  C09J3/16

Abstract: The invention relates to polyisocyanate mixtures of isomers and homologues of the diphenylmethane series having an NCO content of 30 to 33 % by weight, an average number functionality of 2.8 to 3.5 and a content of 0 to 12 % by weight of methylene-diphenyl isocyanates, 46 to 98 % by weight of dimethylene-triphenylene triisocyanates, 1 to 13 % by weight of trimethylene-tetraphenylene tetraisocyanates and 1 to 29 % by weight of higher ring polymethylene-polyphenylene polyisocyanates, where the said percentages add up to 100 % by weight, and the use of these polyisocyanate mixtures as an adhesive additive.

公开(公告)号：DE2862168D1

公开(公告)日：1983-03-03

申请号：DE2862168

申请日：1978-12-16

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  GEHM ROBERT DR ,  VOLKERT OTTO DR ,  CHAKRABARTI SARBANANDA ,  PAULS MATHIAS ,  WEYLAND PETER DR

IPC: C08G18/46 ,  C08G18/50 ,  C08J9/14

公开(公告)号：AT21919T

公开(公告)日：1986-09-15

申请号：AT83104000

申请日：1983-04-23

Applicant: BASF AG

Inventor： HORACEK HEINRICH DR ,  WITTMANN OTTO ,  MARX MATTHIAS DR ,  MAYER JOHANN DR

IPC: C08G18/10 ,  C08G18/54 ,  C08G18/76 ,  C08G18/80 ,  C08L97/02 ,  C09J175/04