公开(公告)号：DE59003682D1

公开(公告)日：1994-01-13

申请号：DE59003682

申请日：1990-09-12

Applicant: BASF AG

Inventor： POTTHOFF-KARL BIRGIT DR ,  NUBER ADOLF DR ,  HINZ WILLY DR ,  SANNER AXEL DR

IPC: C08F6/10 ,  C08F2/04 ,  C08F2/10 ,  C08F6/00 ,  C08F26/10 ,  C08F218/02 ,  C08F218/04 ,  C08F226/10

Abstract: Preparation of copolymers which are clear in water from A) 45 to 90% by weight of N-vinylpyrrolidone, B) 10 to 55% by weight of a vinyl ester and C) 0 to 10% by weight of further copolymerisable monomers by free radical polymerisation in an organic solvent in the presence of a free radical initiator and separation of the organic solvent and other volatile components by distillation, by carrying out the polymerisation until the N-vinylpyrrolidone content of the reaction mixture corresponds to 5 to 1% by weight of the amount of N-vinylpyrrolidone used, substantially separating off the organic solvent and other volatile components by distillation, adding water to the mixture, leaving the aqueous solution for 1 to 10 hours at 50 to 100 DEG C with further addition of free radical initiators and then virtually completely removing volatile organic components by steam distillation.

公开(公告)号：DE4020766A1

公开(公告)日：1992-01-02

申请号：DE4020766

申请日：1990-06-29

Applicant: BASF AG

Inventor： LANG REINHARD DR ,  BECK ERICH DR ,  KEIL EDMUND ,  NUBER ADOLF DR ,  PETERSEN HARRO DR ,  RENZ HANS DR ,  SCHMIDT HORST DR ,  WEISS WOLFRAM DR

IPC: C08F299/02 ,  C08F290/00 ,  C08F290/14 ,  C08G12/40 ,  C08G12/42 ,  C08G14/12 ,  C09D161/00 ,  C09D161/34

公开(公告)号：DE4415624A1

公开(公告)日：1995-11-09

申请号：DE4415624

申请日：1994-05-04

Applicant: BASF AG

Inventor： REICH WOLFGANG DR ,  JAEGER ULRICH DR ,  BECK ERICH DR ,  KEIL EDMUND ,  ERHARDT ULRICH DR ,  NUBER ADOLF DR

IPC: C08F299/02 ,  C08F290/00 ,  C08G59/17 ,  C08G59/56 ,  C08G63/58 ,  C08G63/91 ,  C08L63/00 ,  C07C69/54 ,  C07C67/26 ,  C07C67/08 ,  C07C229/06 ,  C07C227/08 ,  C08L63/10 ,  C09D163/10

Abstract: The prodn. of radiation-curable acrylates (I) comprises (1) reacting hydroxy cpds. (II) with (meth)acrylic acid and (2) reacting the prods. with epoxide(s) (III); cpds. with one or more prim. or sec. amino gps. (IV) are added in or before stage (2), which is then continued until the acid no. of the mixt. has decreased by at least 3 mg KOH/g from its value at the time of addn. of (IV). Also claimed are acrylates (I) obtd. by this process.

公开(公告)号：DE3785017D1

公开(公告)日：1993-04-29

申请号：DE3785017

申请日：1987-12-05

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  DENZINGER WALTER ,  SANNER AXEL DR

IPC: C08F2/10 ,  C08F2/38 ,  C08F4/28 ,  C08F4/34 ,  C08F26/10

Abstract: Hydrazine-free N-vinyl-2-pyrrolidone polymers (PVP), which form clear solns. in water and organic solvents and contain min. 50 (wt.)% polymerised N-vinyl-2-pyrrolidone (VP) are prepd. by treating the aq. monomer soln. with 0.1-3 wt.% (w.r.t. the monomer) of di-tert.-butyl peroxide (DTBP), opt. diluted up to 100 fold in soln. or emulsion; stirring the mixt. for 1-15 h at 100-160 deg.C; and adjusting the mol.wt. to a Fikentscher K value of 10-100 as required by adding 0-100% regulator w.r.t. the monomer. Pref., the mol.wt. regulator is i-PrOH.

公开(公告)号：DE3773084D1

公开(公告)日：1991-10-24

申请号：DE3773084

申请日：1987-08-12

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  SANNER AXEL DR ,  STRAUB FERDINAND DR ,  VOGEL FRIEDRICH DR

IPC: A61K8/00 ,  A61K8/31 ,  A61K8/34 ,  A61K8/35 ,  A61K8/36 ,  A61K8/41 ,  A61K8/81 ,  A61Q5/06 ,  C08F8/44 ,  C08F26/10 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F220/12 ,  C08F220/18 ,  C08F226/10 ,  A61K7/11

Abstract: New terpolymer (I), is prepd. by the radical polymerisation of, by wt., : 30-50 % vinyl pyrrolidone, 40-70 % tert. Bu acrylate or -methacrylate and 5-5% acrylic- or methacrylic acid and its -COOH gps are neutralised, opt partly or completely, e.g. to 5-100%, by an organic amine and has K-value 10-60. Hair-spray compsn. contains, by wt.: 0.5-15% (I), 10-95% solvent, e.g. acetone, EtOH, propanol, isopropanol, butanol and/or 1-methoxy-propanol and 5-90% propellant, e.g. propane, n-butane, isobutane, 2,2-dimethyl-propane, isopentane and/or dimethyl ether. The compsn. opt contains also 0.1-10 % water of 1% CH2Cl2 or C2H3Cl3.

公开(公告)号：DE3931681A1

公开(公告)日：1991-04-04

申请号：DE3931681

申请日：1989-09-22

Applicant: BASF AG

Inventor： POTTHOFF-KARL BIRGIT DR ,  NUBER ADOLF DR ,  HINZ WILLY DR ,  SANNER AXEL DR

IPC: C08F6/10 ,  C08F2/04 ,  C08F2/10 ,  C08F6/00 ,  C08F26/10 ,  C08F218/02 ,  C08F218/04 ,  C08F226/10

Abstract: Preparation of copolymers which are clear in water from A) 45 to 90% by weight of N-vinylpyrrolidone, B) 10 to 55% by weight of a vinyl ester and C) 0 to 10% by weight of further copolymerisable monomers by free radical polymerisation in an organic solvent in the presence of a free radical initiator and separation of the organic solvent and other volatile components by distillation, by carrying out the polymerisation until the N-vinylpyrrolidone content of the reaction mixture corresponds to 5 to 1% by weight of the amount of N-vinylpyrrolidone used, substantially separating off the organic solvent and other volatile components by distillation, adding water to the mixture, leaving the aqueous solution for 1 to 10 hours at 50 to 100 DEG C with further addition of free radical initiators and then virtually completely removing volatile organic components by steam distillation.

公开(公告)号：DE3627970A1

公开(公告)日：1988-02-25

申请号：DE3627970

申请日：1986-08-18

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  SANNER AXEL DR ,  STRAUB FERDINAND DR ,  VOGEL FRIEDRICH DR

IPC: A61K8/00 ,  A61K8/31 ,  A61K8/34 ,  A61K8/35 ,  A61K8/36 ,  A61K8/41 ,  A61K8/81 ,  A61Q5/06 ,  C08F8/44 ,  C08F26/10 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F220/12 ,  C08F220/18 ,  C08F226/10 ,  A61K7/06

Abstract: A terpolymer of vinylpyrolidone, tert-butyl (meth)acrylate and acrylic or methacrylic acid, its use in hair treatment agents, and hair cosmetics compositions which contain these agents.

公开(公告)号：ES2113138T3

公开(公告)日：1998-04-16

申请号：ES95108201

申请日：1995-05-30

Applicant: BASF AG

Inventor： REICH WOLFGANG DR ,  BECK ERICH DR ,  KEIL EDMUND ,  ERHARDT ULRICH DR ,  NUBER ADOLF DR

IPC: C07C67/08 ,  C07C67/26 ,  C07C67/60 ,  C07C69/54 ,  C08F20/26 ,  C08F2/46 ,  C08F2/48 ,  C08F290/00 ,  C08F299/02 ,  C08G59/17 ,  C08G63/47

Abstract: The prodn. of radiation-curable acrylates comprises (1) reaction of hydroxy cpds. with (meth)acrylic acid followed by (2) reaction with peroxide cpds. in presence of quat. ammonium or phosphonium cpds. of formula (I) or (II) as catalysts: X = counter-ion; R -R = 1-18C alkyl (opt. substd. with 1 or 2 Ph gps.) or 6-12C aryl (opt. substd. with 1 or 2 1-6C alkyl gps.). Also claimed are curable acrylates (A) obtd. by this process, and radiation-curable prepns. (B) contg. (A) and an isocyanate cpd. with at least 2 NCO gps. for subsequent crosslinking, pref. in amts. of 0.05-30 wt.%.

公开(公告)号：ES2057670T3

公开(公告)日：1994-10-16

申请号：ES91110025

申请日：1991-06-19

Applicant: BASF AG

Inventor： LANG REINHARD DR ,  BECK ERICH DR ,  KEIL EDMUND ,  NUBER ADOLF DR ,  PETERSEN HARRO DR ,  RENZ HANS DR ,  SCHMIDT HORST DR ,  WEISS WOLFRAM DR

IPC: C08F299/02 ,  C08F290/00 ,  C08F290/14 ,  C08G12/40 ,  C08G12/42 ,  C08G14/12 ,  C09D161/00 ,  C09D161/34

公开(公告)号：AT110758T

公开(公告)日：1994-09-15

申请号：AT91110025

申请日：1991-06-19

Applicant: BASF AG

Inventor： LANG REINHARD DR ,  BECK ERICH DR ,  KEIL EDMUND ,  NUBER ADOLF DR ,  PETERSEN HARRO DR ,  RENZ HANS DR ,  SCHMIDT HORST DR ,  WEISS WOLFRAM DR

IPC: C08F299/02 ,  C08F290/00 ,  C08F290/14 ,  C08G12/40 ,  C08G12/42 ,  C08G14/12 ,  C09D161/00 ,  C09D161/34