公开(公告)号：WO2010083978A3

公开(公告)日：2011-01-06

申请号：PCT/EP2010000280

申请日：2010-01-19

Applicant: BASF SE ,  TELES JOAQUIM HENRIQUE ,  RESCH PETER ,  RUPPEL WILHELM ,  WEGERLE ULRIKE ,  GERLINGER WOLFGANG ,  ROESSLER-FEIGEL BEATRICE ,  MEIER ANTON ,  MUELLER CHRISTIAN

Inventor： TELES JOAQUIM HENRIQUE ,  RESCH PETER ,  RUPPEL WILHELM ,  WEGERLE ULRIKE ,  GERLINGER WOLFGANG ,  ROESSLER-FEIGEL BEATRICE ,  MEIER ANTON ,  MUELLER CHRISTIAN

IPC: B01J19/24 ,  B01J19/00

CPC classification number: B01J19/2425 ,  B01J4/001 ,  B01J19/006 ,  B01J2219/00085 ,  B01J2219/00166 ,  F28D7/16 ,  F28F9/0265 ,  F28F9/0275 ,  F28F9/0278 ,  Y02P20/582

Abstract: The invention relates to a tube bundle reactor having a flat feed dome. Alternatively, the discharge dome can also be designed flat. The flat design reduces the reaction heat developing in the hood in reaction types that take place not only in the tube bundle (non-catalyzed reactions and reactions with homogenously distributed catalyst). Undesired reactions that already take place in the dome due to accumulated heat are thus heavily suppressed, whereby greater selectivity in temperature-sensitive reactions is achieved. Additionally, the temperature distribution within the domes can be precisely controlled. The tube bundle reactor comprises a tube bundle that has a feed end connected to a feed dome of the tube bundle reactor, wherein the feed dome is designed in a flat shape having a cross-sectional surface at the feed end and an inner volume, and the ratio of the inner volume to the cross-sectional surface is less than 0.35 m. The invention is furthermore implemented by a method for operating a tube bundle reactor, comprising: introducing a reactant mixture into a tube bundle and converting at least a portion of the reactant mixture into a product inside the tube bundle. The introduction step comprises: feeding the reactant mixture into an inner space of a feed dome of the tube bundle reactor and forwarding the reactant mixture into a feed end of the tube bundle in the form of a fluid flow. The fluid flow has a cross-sectional surface upon entering the feed end and the inner space of the feed dome through which the fluid flows has an inner volume; wherein the ratio of the inner volume to the cross-sectional surface is less than 0.35 m.

Abstract translation: 本发明涉及一种具有平面供应罩管束反应器。 可替换地，放电罩可以制成平的。 扁平设计降低导致反应类型，发生不仅在Rohbündel（未催化的反应和反应以均匀地分布催化剂）罩反应热。 其特征在于，由此更高的选择性与对温度敏感的反应实现的是那些已经在罩发生不希望的反应，由于积热，强烈抑制。 此外，该罩内的温度分布可以被精确地控制。 包括具有进料端，其连接到所述管束反应器的供给罩管束管束反应器中，与在进料端的内部容积的横截面面积和扁平形状的供给罩构造，并且内部容积的横截面面积的比例为小于0， 35米。 引入在管束中的反应物混合物，并且至少在管束内的反应混合物的一部分反应，以一个产品：此外，本发明是通过一种用于操作管束反应器的方法，包括的手段来实现。 放电，其包括：供给所述反应物混合物进入管束反应器的供给罩的内和反应物混合物通入在流体流的形式管束的一个进给端。 流体流动的横截面面积，因为它进入的进料端和通过其流体流流，具有内部容积的供给机罩的内部; 其中内部体积与横截面面积的比例为小于0.35微米。

公开(公告)号：WO2013117536A3

公开(公告)日：2014-01-09

申请号：PCT/EP2013052223

申请日：2013-02-05

Applicant: BASF SE

Inventor： PARVULESCU ANDREI-NICOLAE ,  MUELLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  SEELIG BIANCA ,  KAMPE PHILIP ,  WEBER MARKUS ,  BAYER ROBERT ,  SEIDEL KARSTEN ,  RESCH PETER

IPC: B01J29/89 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C01B37/00 ,  C07D301/12

CPC classification number: B01J29/7088 ,  B01J29/7476 ,  B01J29/89 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/42 ,  C01B37/005 ,  C01B39/026 ,  C01B39/06 ,  C01B39/085 ,  C01B39/12 ,  C07D301/12 ,  Y02P20/52

Abstract: The present invention relates to a micropowder, wherein the particles of the micropowder have a Dv10 value of at least 2 micrometer and the micropowder comprises mesopores which have an average pore diameter in the range of from 2 to 50 nm and comprise, based on the weight of the micropowder, at least 95 weight-% of a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc.

Abstract translation: 本发明涉及一种微粉，其中微粉的颗粒具有至少2微米的Dv10值，并且该微粉包括平均孔径在2至50nm范围内的介孔，并且基于重量 的微粉末，至少95重量％的含有钛和锌的结构型MWW的微孔无铝沸石材料。

公开(公告)号：WO2010023211A2

公开(公告)日：2010-03-04

申请号：PCT/EP2009060956

申请日：2009-08-26

Applicant: BASF SE ,  TELES JOAQUIM HENRIQUE ,  RUPPEL WILHELM ,  WEGERLE ULRIKE ,  MEIER ANTON ,  GENGER THOMAS ,  SCHELPER MICHAEL ,  RESCH PETER

Inventor： TELES JOAQUIM HENRIQUE ,  RUPPEL WILHELM ,  WEGERLE ULRIKE ,  MEIER ANTON ,  GENGER THOMAS ,  SCHELPER MICHAEL ,  RESCH PETER

IPC: C07C45/33 ,  C07C49/11

CPC classification number: C07C45/28 ,  C07C45/82 ,  C07C2601/08 ,  Y02P20/582 ,  C07C49/403 ,  C07C49/395 ,  C07C49/413

Abstract: The present invention relates to a process for preparing at least one monocyclic ketone having 4 to 20 carbon atoms by reacting a mixture G1 comprising at least one monocyclic olefin having 4 to 20 carbon atoms with a mixture G2 comprising at least dinitrogen monoxide, this reaction being carried out adiabatically.

Abstract translation: 本发明涉及一种方法，用于由混合物G1包括4至20个碳原子的至少一种单环烯烃与含有至少一氧化二氮的混合物G2使具有碳原子数4〜20的至少一个单环酮的制备方法，所述反应在绝热下进行。

公开(公告)号：BRPI1010906A2

公开(公告)日：2016-10-25

申请号：BRPI1010906

申请日：2010-05-05

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： BARTOSCH CHRISTIAN ,  SCHINDLER GOETZ-PETER ,  GÖBBEL HANS-GEORGE ,  TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  WEIDENBACH MEINOLF ,  BASSLER PETER ,  RESCH PETER ,  KAMPE PHILIP ,  JACUBINAS RICHARD ,  CHIN SOO YIN ,  GRASSLER THOMAS ,  MÜLLER ULRICH

IPC: C07D301/12

公开(公告)号：ZA201406532B

公开(公告)日：2016-06-29

申请号：ZA201406532

申请日：2014-09-05

Applicant: BASF SE

Inventor： RESCH PETER ,  SEIDEL KARSTEN ,  BAYER ROBERT ,  WEBER MARKUS ,  KAMPE PHILIP ,  SEELIG BIANCA ,  MÜLLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  PARVULESCU ANDREI-NICOLAE

Abstract: The present invention relates to a molding, comprising a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc (ZnTiMWW), said molding preferably comprising a micropowder comprising, based on the weight of the micropowder, at least 95 weight-% of a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc (ZnTiMWW), the molding preferably further comprising at least one binder, preferably a silica binder.

公开(公告)号：NO20082792A

公开(公告)日：2008-08-29

申请号：NO20082792

申请日：2008-06-20

Applicant: BASF SE

Inventor： BECKER MICHAEL ,  SALDEN ALEX ,  STACK BIANCA ,  HENKELMANN JOCHEM ,  SPRINGMANN STEFFEN ,  LAAR FREDRIK VAN ,  RUPPEL WILHELM ,  RESCH PETER ,  BENDER MICHAEL

IPC: C07C5/10 ,  C07C7/148 ,  C07C13/18

CPC classification number: C07C13/18 ,  C07C5/10 ,  C07C7/1485 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/46 ,  C10G65/08 ,  C10G67/02 ,  C10G2300/1096 ,  C10G2300/202 ,  Y02P20/125

公开(公告)号：SG10201803792UA

公开(公告)日：2018-06-28

申请号：SG10201803792U

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： PARVULESCU ANDREI-NICOLAE ,  MÜLLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  SEELIG BIANCA ,  KAMPE PHILIP ,  WEBER MARKUS ,  RESCH PETER ,  BARTOSCH CHRISTIAN ,  RIEDEL DOMINIC ,  URBANCZYK DANIEL ,  SCHRÖDER ALEXANDER ,  WEGERLE ULRIKE

Abstract: Regeneration of a Titanium Containing Zeolite The present invention relates to a process for the regeneration of a catalyst comprising a #" titanium-containing zeolite, said catalyst having been used in a process for the preparation of an olefin oxide and having phosphate deposited thereon, said process for the regeneration comprising the steps: (a) separating the reaction mixture from the catalyst, (b) washing the catalyst obtained from (a) with liquid aqueous system; (c) optionally drying the catalyst obtained from (b) in a gas stream comprising an inert gas at a temperature of less than °C; (d) $%" calcining the catalyst obtained from (c) in a gas stream comprising oxygen at a temperature of at least 300 °C. " " &'(")*+,-./0"1+2*304"

公开(公告)号：ES2637839T3

公开(公告)日：2017-10-17

申请号：ES13716733

申请日：2013-02-05

Applicant: BASF SE

Inventor： PARVULESCU ANDREI-NICOLAE ,  MÜLLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  SEELIG BIANCA ,  KAMPE PHILIP ,  WEBER MARKUS ,  BAYER ROBERT ,  SEIDEL KARSTEN ,  RESCH PETER

IPC: B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J39/02 ,  C01B37/00 ,  C01B39/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C07D301/12

Abstract: Un micropolvo, cuyas partículas tienen un valor de Dv10 de al menos 2 micrómetros, comprendiendo dicho micropolvo mesoporos que tienen un diámetro medio de poro (4V/A) en el intervalo de 2 a 50 nm determinado por porosimetría de Hg según DIN 66133, y que comprende, con base en el peso del micropolvo, por lo menos 95% en peso de un material zeolítico microporoso libre de aluminio de tipo MWW de estructura que contiene titanio y zinc (ZnTiMWW), donde el valor de Dv10 representa el tamaño medio de partícula donde el 10% en volumen de las partículas del micropolvo tienen un tamaño más pequeño.

公开(公告)号：SG10201606438RA

公开(公告)日：2016-09-29

申请号：SG10201606438R

申请日：2013-02-05

Applicant: BASF SE

Inventor： PARVULESCU ANDREI-NICOLAE ,  MÜLLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  SEELIG BIANCA ,  KAMPE PHILIP ,  WEBER MARKUS ,  BAYER ROBERT ,  SEIDEL KARSTEN ,  RESCH PETER

Abstract: The present invention relates to a molding, comprising a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc (ZnTiMWW), said molding preferably comprising a micropowder comprising, based on the weight of the micropowder, at least 95 weight-% of a microporous aluminum-free zeolitic material of structure type MWW containing titanium and zinc (ZnTiMWW), the molding preferably further comprising at least one binder, preferably a silica binder.

公开(公告)号：SG11201600536WA

公开(公告)日：2016-02-26

申请号：SG11201600536W

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： PARVULESCU ANDREI-NICOLAE ,  MÜLLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  SEELIG BIANCA ,  KAMPE PHILIP ,  WEBER MARKUS ,  RESCH PETER ,  BARTOSCH CHRISTIAN ,  RIEDEL DOMINIC ,  URBANCZYK DANIEL ,  SCHRÖDER ALEXANDER ,  WEGERLE ULRIKE

IPC: B01J29/90 ,  B01J29/70 ,  B01J29/89 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02 ,  B01J37/06 ,  B01J37/10 ,  B01J38/48 ,  C07D301/12 ,  C07D303/04

Abstract: The present invention relates to a process for the regeneration of a catalyst comprising a titanium-containing zeolite, said catalyst having been used in a process for the preparation of an olefin oxide and having phosphate deposited thereon, said process for the regeneration comprising the steps: (a) separating the reaction mixture from the catalyst, (b) washing the catalyst obtained from (a) with liquid aqueous system; (c) optionally drying the catalyst obtained from (b) in a gas stream comprising an inert gas at a temperature of less than 300° C.; (d) calcining the catalyst obtained from (c) in a gas stream comprising oxygen at a temperature of at least 300° C.