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公开(公告)号:DE59709864D1
公开(公告)日:2003-05-22
申请号:DE59709864
申请日:1997-05-26
Applicant: BASF AG
Inventor: BOECKH DIETER , STEIN STEFAN , FUNHOFF ANGELIKA , LUX ALFRED , JAEGER HANS-ULRICH
IPC: C08F226/06 , C11D3/00 , C11D3/37
Abstract: The use of water-soluble copolymers which comprise(a) 5-20 mol % of N-vinylimidazole or 4-vinylpyridine N-oxide units,(b) 95-50 mol % of N-vinylpyrrolidone, N-vinyloxazolidone, methyl-N-vinylimidazole units or mixtures thereof and(c) 0-30 mol % of other monoethylenically unsaturated monomer units,and have an average molecular weight Mw of more than 50,000 as color transfer inhibitors in detergents.
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公开(公告)号:DE59705913D1
公开(公告)日:2002-01-31
申请号:DE59705913
申请日:1997-10-28
Applicant: BASF AG
Inventor: BOECKH DIETER , JAEGER HANS-ULRICH , LUX ALFRED , STEIN STEFAN , DETERING JUERGEN , SCHADE CHRISTIAN
IPC: C08F226/06 , C11D3/00 , C11D3/37 , D06P1/52 , D06P5/08
Abstract: PCT No. PCT/EP97/05939 Sec. 371 Date May 5, 1999 Sec. 102(e) Date May 5, 1999 PCT Filed Oct. 28, 1997 PCT Pub. No. WO98/21301 PCT Pub. Date May 22, 1998The use of polymers which comprise at least 5 mol % of quaternized 1-vinylimidazole units of the formula where R is C1-C25-alkyl, C5-C10-cycloalkyl or benzyl R1,R2,R3 are identical or different and are H, CH3 and C2H5, and X(-) is an anion, as color-fixing and color transfer-inhibiting additive to laundry aftertreatment aids and to detergents.
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公开(公告)号:AU6604601A
公开(公告)日:2001-12-17
申请号:AU6604601
申请日:2001-06-05
Applicant: BASF AG
Inventor: BOECKH DIETER , NORENBERG RALF , HILDEBRANDT SOREN , MOHR BERNHARD , SCHOPKE HOLGER , LEYRER REINHOLD J , HUFF JURGEN
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公开(公告)号:DE10027636A1
公开(公告)日:2001-12-13
申请号:DE10027636
申请日:2000-06-06
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , DETERING JUERGEN , BERTLEFF WERNER , SCHOEPKE HOLGER , LEYRER REINHOLD , HUFF JUERGEN
IPC: C11D1/38 , C11D1/86 , C11D3/00 , C11D3/02 , C11D3/37 , C11D11/00 , D06M15/263 , D06M23/08 , C09D5/02 , C09D7/02 , C09D133/26 , C08G69/48 , B01F17/00 , C09K3/18
Abstract: The use of particulate, hydrophobic polymers with a particle size of 10 nm to 100 microns, cationically modified by surface-coating with multivalent metal ions and/or cationic surfactants, as additives in rinsing, care, washing and cleaning materials. Independent claims are also included for: (i) a treatment for laundry, textile surfaces, leather, wood and hard surfaces, containing: (a) 0.05-40 wt.% of modified polymer as above (I); (b) 0.01-20 wt.% of water-soluble salts of calcium, magnesium, aluminum and/or zinc and/or 0.01-30 wt.% of cationic surfactant; (c) 0-80 wt.% of additive(s) such as acids, bases, inorganic builders, organic co-builders, other surfactants, polymeric color-transfer inhibitors, polymeric greying inhibitors, soil release polymers, enzymes, complex-formers, corrosion inhibitors, wax, silicone oils, light stabilizers, dyes, solvents, hydrotropic additives, thickeners and/or alkanolamines; and (d) water to make up 100 wt.%; (ii) laundry after-treatment and care material containing: (a) 0.1-30 wt.% of (I) (containing ethylenically-unsaturated monomer unit(s)), dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0.1-30 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or a cationic surfactant; (d) 0-10 wt.% of additives such as perfume, silicone oil, light stabilizers, dyes, complex-formers, greying inhibitors, soil-release polyesters, color-transfer inhibitors, non-aqueous solvents, hydrotropic additives, thickeners and/or alkanolamines; and (e) water to make up 100 wt.% of; (iii) a laundry after-treatment and care material containing: (a) 0.5-25 wt.% of hydrophobic polymer particles (size as above) containing 5-45 wt.% of unsaturated monomer units with carboxylic acid groups, dispersed in water with an anionic emulsifier and/or anionic protective colloid; (b) 0.05-10 wt.% of acid; (c) 0.1-30 wt.% of metal salt and/or surfactant as above; (d) 0-10 wt.% of additives (as in ii); and (e) water (to 100 wt.%); (iv) a liquid cleaning and care formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.01-40 wt.% of non-ionic or anionic surfactant; (c) 0.01-30 wt.% of metal salt and/or surfactant as above; (d) 0-10 wt.% of complex-former(s); (e) 0-20 wt.% of pH regulator, thickener, solvent, hydrotropic agent, polycarboxylic acid, silicone, brightener, perfume and/or dye; and (f) 0-90 wt.% of water; (v) a liquid acid cleaning formulation containing: (a) 0.1-30 wt.% of (I) (as in ii above); (b) 0.05-20 wt.% of acid; and (c) other components as in (iv); (vi) a liquid acid cleaning formulation containing: (a) 0.5-25 wt.% of (I) (as in (iii) above), dispersed as described; (b) 0.1-40 wt.% of non-ionic or anionic surfactant; (c) 0.1-30 wt.% of metal salt and/or surfactant as above; (d) 0.1-20 wt.% of acid, and other components as in (iv); (vii) a solid detergent formulation containing: (a) 0.05-20 wt.% of (I); (b) 0.1-40 wt.% of non-ionic, cationic and/or anionic surfactant(s); (c) 0-50 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; and (e) 0-60 wt.% of other ingredients such as regulators, enzymes, perfumes, complex-formers, corrosion inhibitors, bleaching agents, activators and/or catalysts, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, solubilizers and/or break-up agents; (viii) a liquid detergent formulation containing: (a) 0.05-20 wt.% of (I); (b) 0.1-40 wt.% of surfactant(s) as in (vii); (c) 0-20 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; (e) 0-10 wt.% of additives such as soda, enzymes, perfume, complex formers, corrosion inhibitors, bleaching agents, activators and/or catalysts, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, non-aqueous solvents, hydrotropic agents, thickeners and/or alkanolamines; and (f) 0-90 wt.% of water.
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公开(公告)号:DE10027634A1
公开(公告)日:2001-12-13
申请号:DE10027634
申请日:2000-06-06
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER REINHOLD , HUFF JUERGEN
IPC: D06L1/12 , C08J3/205 , C11D3/37 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356 , C09D5/02 , C09D7/02 , C09D133/26 , C08G69/48 , B01F17/00 , C09K3/18
Abstract: The use of particulate, hydrophobic polymers with a particle size of 10 nm to 100 micro m, cationically modified by coating with cationic polymers, as additives in washing or care materials for textiles and as additives in detergents. Independent claims are also included for: (i) a treatment for laundry and textile surfaces, containing: (a) 0.05-40 wt.% of the modified polymer (I); (b) 0.01-10 wt.% of a cationic polymer; and (c) 0-80 wt.% of additive(s) such as acids, bases, inorganic builders, organic co-builders, surfactants, polymeric color-transfer inhibitors, polymeric greying inhibitors, soil release polymers, enzymes, complex-formers, corrosion inhibitors, wax, silicone oils, light stabilizers, dyes, solvents, hydrotropic additives, thickeners and/or alkanolamines; (ii) a laundry after-treatment and care material containing: (a) 0.1-30 wt.% of (I) (containing ethylenically unsaturated monomer unit(s)), dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0.1-10 wt.% of a cationic polymer; (d) 0-30 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or a cationic surfactant; and (e) 0-10 wt.% of additives such as perfume, silicone oil, light stabilizers, dyes, complex-formers, greying inhibitors, soil-release polyesters, color-transfer inhibitors, non-aqueous solvents, hydrotropic additives, thickeners and/or alkanolamines; (iii) a solid detergent formulation containing: (a) 0.05-20 wt.% of (I) (optionally also modified with multivalent metal ions and/or cationic surfactants); (b) 0.1-40 wt.% of non-ionic, cationic and/or anionic surfactant(s); (c) 0-50 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; and (e) 0-60 wt.% of other ingredients such as regulators, enzymes, perfumes, complex-formers, corrosion inhibitors, bleaching agents and/or activators, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, solubilizers and/or break-up agents; (iv) a liquid detergent formulation containing: (a) , (b) , (c) , (d) , (e) (f) (a) 0.05-20 wt.% of (I) (optionally further modified as in Independent Claim (iii)); (b) 0.1-40 wt.% of surfactant(s) as in Independent Claim (iii); (c) 0-20 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; (e) 0-10 wt.% of additives such as soda, enzymes, perfume, complex formers, corrosion inhibitors, bleaching agents, activators and/or catalysts, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, non-aqueous solvents, hydrotropic agents, thickeners and/or alkanolamines; and (f) 0-90 wt.% of water.
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公开(公告)号:AT204901T
公开(公告)日:2001-09-15
申请号:AT97952779
申请日:1997-11-18
Applicant: BASF AG
Inventor: BOECKH DIETER , SCHUERMANN GREGOR , MUNDINGER KLAUS , SCHOENHERR MICHAEL
IPC: C11D17/06 , C11D1/02 , C11D1/66 , C11D1/83 , C11D3/12 , C11D3/28 , C11D3/30 , C11D3/37 , C11D3/39 , C11D3/395
Abstract: Textile detergent formulation, containing(A) from 0.1 to 10 wt % of quaternized glycine nitriles,(B) from 0.5 to 40 wt % of bleaches in the form of peroxo compounds and/or peracids,(C) from 0.5 to 50 wt % of non-ionic and/or anionic surfactants and(D) from 5 to 85 wt % of compounds that are capable of sequestering calcium and/or magnesium ions.This formulation is suitable for domestic and commercial laundering of textiles in a dosage of more than 2 g per liter of washing liquor, particularly when using a goods-to-liquor ratio of from 1:10 to 1:2.
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公开(公告)号:DE59509188D1
公开(公告)日:2001-05-17
申请号:DE59509188
申请日:1995-06-27
Applicant: BASF AG
Inventor: WARZELHAN VOLKER , BRUCHMANN BERND , BOECKH DIETER , SEELIGER URSULA , YAMAMOTO MOTONORI , BAUER PETER
IPC: C08J9/00 , A01G9/10 , C05F17/00 , C08G18/42 , C08G18/46 , C08G63/60 , C08G63/668 , C08G63/672 , C08G63/685 , C08G63/688 , C08G63/91 , C08L1/00 , C08L67/02 , C08L75/06 , C08L101/16 , C09J167/02 , C09J175/06 , C09K15/32
Abstract: Biodegradable polyether esters P1 obtainable by reacting a mixture essentially comprising(a1) a mixture essentially comprising20-95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol % of a compound containing sulfonate groups,where the total of the individual mole percentages is 100 mol %, and(a2) a mixture of dihydroxy compounds essentially comprising(a21) from 15 to 99.8 mol % of a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols,(a22) from 85 to 0.2 mol % of a dihydroxy compound containing ether functionalities of the formula Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, or mixtures thereof,where the molar ratio of (a1) to (a2) is chosen in the range from 0.4:1 to 1.5:1, with the proviso that the polyether ester P1 has a molecular weight (Mn) in the range from 5000 to 80,000 g/mol, a viscosity number in the range from 30 to 450 g/ml (measured in o-dichlorobenzene/phenol (50/50 ratio by weight) at a concentration of 0.5% by weight of polyether ester P1 at 25° C.) and a melting point in the range from 50 to 200° C., and with the further proviso that from 0.01 to 5 mol %, based on the molar quantity of component (a1) employed, of a compound D with at least three groups capable of ester formation are employed to prepare the polyether ester P1,and further biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives, biodegradable moldings, films and blends with starch obtainable from the polymers and molding compositions according to the invention.
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公开(公告)号:BR9713457A
公开(公告)日:2000-03-28
申请号:BR9713457
申请日:1997-11-18
Applicant: BASF AG
Inventor: BOECKH DIETER , SCHUERMANN GREGOR , MUNDINGER KLAUS , SCHOENHERR MICHAEL
IPC: C11D17/06 , C11D1/02 , C11D1/66 , C11D1/83 , C11D3/12 , C11D3/28 , C11D3/30 , C11D3/37 , C11D3/39 , C11D3/395 , C11D3/00
Abstract: Textile detergent formulation, containing(A) from 0.1 to 10 wt % of quaternized glycine nitriles,(B) from 0.5 to 40 wt % of bleaches in the form of peroxo compounds and/or peracids,(C) from 0.5 to 50 wt % of non-ionic and/or anionic surfactants and(D) from 5 to 85 wt % of compounds that are capable of sequestering calcium and/or magnesium ions.This formulation is suitable for domestic and commercial laundering of textiles in a dosage of more than 2 g per liter of washing liquor, particularly when using a goods-to-liquor ratio of from 1:10 to 1:2.
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公开(公告)号:DE59503856D1
公开(公告)日:1998-11-12
申请号:DE59503856
申请日:1995-01-28
Applicant: BASF AG
Inventor: BOECKH DIETER , JAEGER HANS-ULRICH , SCHORNICK GUNNAR
IPC: C08G63/66 , C08G63/668 , C08G63/672 , C11D3/37
Abstract: PCT No. PCT/EP95/00300 Sec. 371 Date Aug. 5, 1996 Sec. 102(e) Date Aug. 5, 1996 PCT Filed Jan. 28, 1995 PCT Pub. No. WO95/21880 PCT Pub. Date Aug. 17, 1995Amphiphilic polyesters containing (a) ester units derived from polyalkylene glycols having a molecular weight of from 500 to 7500 and aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and (b) ester units derived from aromatic dicarboxylic acids and polyhydric alcohols and having molecular weights of from 1500 to 25,000, processes for preparing the amphiphilic polyesters by polycondensation, preparing first (a) aliphatic polyesters of polyalkylene glycols having a molecular weight of from 500 to 7500 with aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and then, within the aliphatic polyester thus obtained, (b) aromatic polyesters from aromatic dicarboxylic acids and polyhydric alcohols, reversing the order of the polycondensation, or condensing oligomeric aromatic polyesters (b) with oligomeric aliphatic polyesters (a), and use of the amphiphilic polyesters as additive in laundry detergents, other laundry detergent additives and laundry aftertreatments.
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公开(公告)号:AT171962T
公开(公告)日:1998-10-15
申请号:AT95906354
申请日:1995-01-28
Applicant: BASF AG
Inventor: BOECKH DIETER , JAEGER HANS-ULRICH , SCHORNICK GUNNAR
IPC: C08G63/66 , C08G63/668 , C08G63/672 , C11D3/37
Abstract: PCT No. PCT/EP95/00300 Sec. 371 Date Aug. 5, 1996 Sec. 102(e) Date Aug. 5, 1996 PCT Filed Jan. 28, 1995 PCT Pub. No. WO95/21880 PCT Pub. Date Aug. 17, 1995Amphiphilic polyesters containing (a) ester units derived from polyalkylene glycols having a molecular weight of from 500 to 7500 and aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and (b) ester units derived from aromatic dicarboxylic acids and polyhydric alcohols and having molecular weights of from 1500 to 25,000, processes for preparing the amphiphilic polyesters by polycondensation, preparing first (a) aliphatic polyesters of polyalkylene glycols having a molecular weight of from 500 to 7500 with aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and then, within the aliphatic polyester thus obtained, (b) aromatic polyesters from aromatic dicarboxylic acids and polyhydric alcohols, reversing the order of the polycondensation, or condensing oligomeric aromatic polyesters (b) with oligomeric aliphatic polyesters (a), and use of the amphiphilic polyesters as additive in laundry detergents, other laundry detergent additives and laundry aftertreatments.
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