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公开(公告)号：JPH09241658A
公开(公告)日：1997-09-16
申请号：JP8053896
申请日：1996-03-08
Applicant: MITSUI PETROCHEMICAL IND
Inventor： KISO YOSHIHISA , OYOSHI HAJIME , SHIMAMOTO KENJI , YAMANAKA TAKASHI , YANAGII SHIZUO
Abstract: PROBLEM TO BE SOLVED: To establish production of an oily material due to catalytic decomposition of a synthetic polymer (plastic). SOLUTION: A mineral consisting essentially of SiO2 -Al2 O3 and having =250m /g specific surface area, (70/30) to (45/55) ratio (wt/wt) of SiO2 /Al2 O3 and containing 3-15wt.% subsidiary component is used as a catalyst. The preferred example of the mineral is Secard OW (R). The catalyst in an amount of 10wt.% is added to 10g polyethylene resin and catalytic decomposition of the polyethylene resin is carried out. In the reaction, a time until distilled amount attains 5ml is 4min and a time until distilled amount attains 9ml is 7min and distilled liquid amount is 74.4wt.% and amount of gas generated is 20.6wt.% and residual amount is 5.0wt.%.
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公开(公告)号：JPH0977689A
公开(公告)日：1997-03-25
申请号：JP17948296
申请日：1996-07-09
Applicant: MITSUI PETROCHEMICAL IND
Inventor： SUZUKI YASUHIKO , KISO YOSHIHISA , FUKUOKA ONORI
Abstract: PROBLEM TO BE SOLVED: To obtain a hydrogenation product of an olefin in the presence of a catalyst high in hydrogenation activity in a high yield by reacting the olefin with hydrogen in the presence of the catalyst comprising a metallocene compound and an organic aluminum compound. SOLUTION: An olefin (preferably a cycloalkadiene) is reacted with hydrogen in the presence of (A) a metallocene compound and (B) an organic aluminum oxy compound (preferably methylaluminoxane) preferably at 20-100 deg.C for 1-30hr. The component A is preferably a zirconocene of the formula: MLx (M is zirconium; L groups are ligands, wherein at least one of the L groups is a ligand having a cyclopentadienyl skeleton, and the others are each a 1-12C hydrocarbon, an alkoxy, etc.; x is the valency of M). The component A and the component B are used in amounts of 0.001-0.1 mole and 0.01-1 mole, respectively, per mole of the olefin. The components A and B are used in an Al/M atomic ratio of 100-500.
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公开(公告)号：JP2574012B2
公开(公告)日：1997-01-22
申请号：JP25157788
申请日：1988-10-05
Applicant: MITSUI PETROCHEMICAL IND
Inventor： YOKOYAMA KEIICHI , TANIGUCHI KATSUO , KISO YOSHIHISA
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公开(公告)号：JPH07286005A
公开(公告)日：1995-10-31
申请号：JP12134894
申请日：1994-06-02
Applicant: MITSUI PETROCHEMICAL IND
Inventor： FUKUOKA ONORI , TASHIRO KOJI , KAWAI KOJI , SAITO JUNJI , IMUDA JUNICHI , FUJITA TERUNORI , NITAHARA MASATOSHI , UEDA TAKASHI , KISO YOSHIHISA , YOSHIDA MASAYASU
IPC: C08F4/642 , C08F4/60 , C08F4/6592 , C08F10/00
Abstract: PURPOSE:To provide a new transition metal compound, an olefin polymerization catalyst containing a catalyst component containing this compound and the polymerization process. CONSTITUTION:An olefin (co)polymerization catalyst is obtained by pretreating, by prepolymerization of an olefin, a solid catalyst component prepared by impregnating a fine particulate support with a transition metal compound (A) such as represented by the formula [wherein M is IVa, Va or VIa transition metal; R is a 2-6C hydrocarbon group; R is a 6-16C aryl group; X and X are each H, halogen, a 1-20C hydrocarbon group, a 1-20C halohydrocarbon group, an oxygenous group or a sulfur group; Y is a 1-20C bivalent hydrocarbon group; a 1-20C halohydrocarbon group; a bivalent siliciferous group, a germanous group, -O-, -CO-, -S-, -SO-, -NR -,-P(R ), AIR (wherein R is H, halogen or the like)], an organoaluminumoxy compound and at least one compound selected from compounds capable of forming an ionic pair by reaction with component A and an organoaluminumoxy compound.
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公开(公告)号：JPH07216011A
公开(公告)日：1995-08-15
申请号：JP1167694
申请日：1994-02-03
Applicant: MITSUI PETROCHEMICAL IND
Inventor： FUKUOKA ONORI , SAITO JUNJI , IMUDA JUNICHI , FUJITA TERUNORI , TASHIRO KOJI , KAWAI KOJI , YOSHIDA MASAYASU , UEDA TAKASHI , KISO YOSHIHISA
IPC: C08F4/642 , C08F4/60 , C08F4/6592 , C08F10/00
Abstract: PURPOSE:To obtain a catalyst, comprising a specific transition metal, having excellent polymerization activity for an olefin and capable of producing a polyolefin, having a high molecular weight and a high melting point and excellent in stereoregularity. CONSTITUTION:This transition metallic compound is expressed by the formula (M is a group IVa, Va or VIa transition metal of the Periodic Table; R is H, a halogen, a 1-20C halogenated hydrocarbon, a silicon-containing group, etc.; R is a 1-20C hydrocarbon which may be substituted with a halogen, etc.; Hal is fluorine or chlorine; X and X are each H, a halogen, a 1-20C hydrocarbon, etc.; Y is a 1-20C bivalent hydrocarbon, SO, etc.). Furthermore, the catalyst for polymerizing an olefin comprises the transition metallic compound and is prepared by supporting the transition metallic compound, an organoaluminumoxy compound and a compound, reactive with the metallic compound and forming an ion paxr on a particulate carrier. The method for polymerizing the olefin comprises a reaction in the presence of the catalyst.
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Patent Agency Ranking
公开(公告)号：JPH07196734A
公开(公告)日：1995-08-01
申请号：JP29478594
申请日：1994-11-29
Applicant: MITSUI PETROCHEMICAL IND
Inventor： UEDA TAKASHI , MIZUNO AKIRA , KAWASAKI MASAAKI , FUKUOKA ONORI , KISO YOSHIHISA
Abstract: PURPOSE:To obtain the subject polymers excellent in rigidity, heat resistance, transparency, impact resistance, heat sealability, etc., by polymerizing propylene in the presence of a catalyst for olefin polymerization composed of a specific transition metal compound and organoaluminum oxy compound(s), etc. CONSTITUTION:These polymers are obtained by polymerizing propylene in the presence of a catalyst for olefin polymerization composed of (A) a transition metal compound of the formula [M is a group IVa, Va or VIa transition metal; R is a 2-6C hydrocarbon; R is a 6-16C (substituted)aryl; X and X are each H, a halogen, a 1-20C (halo)hydrocarbon, an oxygen-contg. group or a sulfur- contg. group; Y is a 1-20C divalent (halo)hydrocarbon, a silicon dioxide-contg. group, O, S, etc.] and (B) at least one kind of compound selected from (1) organoaluminum oxy compounds and (2) compounds each capable of forming an ion pair by reaction with the component A.
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公开(公告)号：JPH07149832A
公开(公告)日：1995-06-13
申请号：JP24318294
申请日：1994-10-06
Applicant: MITSUI PETROCHEMICAL IND
Inventor： UEDA TAKASHI , MIZUNO AKIRA , KAWASAKI MASAAKI , IMUDA JUNICHI , KISO YOSHIHISA , HASHIMOTO MIKIO
IPC: C08F210/06 , C08F4/60 , C08F4/642 , C08F4/6592 , C08F8/00
Abstract: PURPOSE:To obtain the copolymer excellent in transparency, rigidity, surface hardness, heat, blocking, bleedout and impact resistances and heat-sealability. CONSTITUTION:This propylene-based copolymer contains (a) 95-99.5mol% propylene unit and 0.5-5mol% ethylene unit and has (b) >=90.0% triad tacticity determined by C-NMR in a propylene unit chain part composed of head-tail bonds, (c) >=0.5% ratio of positional irregular units, determined by the C-NMR and based on the 2,1-insert of propylene monomer in the whole propylene inserts and
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公开(公告)号：JPH07138326A
公开(公告)日：1995-05-30
申请号：JP14641394
申请日：1994-06-28
Applicant: MITSUI PETROCHEMICAL IND
Inventor： MIZUNO AKIRA , KAWASAKI MASAAKI , UEDA TAKASHI , IMUDA JUNICHI , KISO YOSHIHISA , HASHIMOTO MIKIO
IPC: C08F210/16 , C08F4/60 , C08F4/642 , C08F4/6592
Abstract: PURPOSE:To obtain a propylene elastomer excellent in heat resistance, shock absorption, transparency, heat-sealability, and blocking resistance. CONSTITUTION:A propylene elastomer is selected which comprises 50-95mol% propylene units and 5-50mol% ethylene units and in which the triad tacticity (determined by C NMR) of chains comprising propylene units bonded head-to- tail is 90.0% or higher; the ratio (determined by C NMR) of position-irregular units due to 2,1-insertion of propylene to the whole propylene insertion is 0.5% or higher; the ratio of position-irregular units due to 1,3-insertion of propylene is 0.05% or lower; and the intrinsic viscosity (at 135 deg.C in decalin) is 0.1-12dl/g.
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公开(公告)号：JPH06312574A
公开(公告)日：1994-11-08
申请号：JP10331993
申请日：1993-04-28
Applicant: MITSUI PETROCHEMICAL IND
Inventor： FUJITA TERUNORI , NITAHARA MASATOSHI , KAWAI KOJI , KISO YOSHIHISA
Abstract: PURPOSE:To obtain a color developing recording material which has high whiteness of a skin, and high preservation stability such as moisture vapor resistance, light resistance, etc., of a color developer by incorporating quinone compound, amine compound represented by specific general formulae and acidic substance. CONSTITUTION:A color developing recording material such as heat-sensitive, pressure recording sheet, etc., useful for a record reader using a visible light and/or near infrared ray comprises three elements of quinone compound represented by a first general formula, amine compound represented by a second general formula, and acidic substance. In the first formula, A, B are hydrocarbon group, R -CO, R -O-CO-, R R N-CO-, and C, D are hydrogen, hydrocarbon group, halogen, R -CO-, R -COO-, R -O-CO-, etc. In the second formula, I, J are hydrogen or hydrocarbon group, K, L are hydrogen, hydrocarbon group, halogen, R -CO-, R -COO-, R -OCO-, etc.
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公开(公告)号：JPH06279477A
公开(公告)日：1994-10-04
申请号：JP6562493
申请日：1993-03-24
Applicant: MITSUI PETROCHEMICAL IND
Inventor： KISO YOSHIHISA , NITAHARA MASATOSHI , KAWAI KOJI
Abstract: PURPOSE:To efficiently produce a bulky cyclopentadienyl group-containing silicon or germanium compound in good yield in a short time. CONSTITUTION:The characteristic of this method for producing a cyclopentadienyl group-containing silicon or germanium compound is reacting (i) a lithium, a sodium or a potassium salt of a cyclopentadiene derivative with (ii) a halogenated silicon compound or a halogenated germanium compound in the presence of a diamine compound.
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