115.
    发明专利
    未知

    公开(公告)号:DE19809418A1

    公开(公告)日:1999-09-09

    申请号:DE19809418

    申请日:1998-03-05

    Applicant: BASF AG

    Abstract: The invention relates to a method for the catalytic hydrogenation of a carbonyl compound or of a mixture comprised of two or more carbonyl compounds in the presence of a catalyst. Said catalyst comprises an inorganic supporting material containing TiO2, and, as an active component, copper or a mixture of copper with at least one of the metals selected from the group zinc, aluminum, cerium, a precious metal and a metal of subgroup VIII. The invention is characterized in that the copper surface amounts to a maximum of 10 m /g.

    Process for preparing polytetrahydrofuran and derivatives thereof

    公开(公告)号:AU4556497A

    公开(公告)日:1998-05-05

    申请号:AU4556497

    申请日:1997-09-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/05204 Sec. 371 Date Apr. 1, 1999 Sec. 102(e) Date Apr. 1, 1999 PCT Filed Sep. 23, 1997 PCT Pub. No. WO98/15589 PCT Pub. Date Apr. 16, 1998Polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butyne-1,4-diol, diesters of these polymers with C2-C20-monocarboxylic acids or monoesters of these polymers with C1-C10-monocarboxylic acids are prepared by polymerization of tetrahydrofuran in the presence of one of the telogens water, 1,4-butanediol, 2-butyne-1,4-diol, polytetrahydrofuran having a molecular weight of from 200 to 700 Dalton, a C1-C10-monocarboxylic acid or an anhydride of a C2-C20-monocarboxylic acid or a mixture of these telogens over a heterogeneous supported catalyst which comprises a catalytically active amount of an oxygen-containing molybdenum and/or tungsten compound on an oxidic support material and which has been calcined at from 5OO DEG C. to 1OOO DEG C. after application of the precursor compounds of the oxygen-containing molybdenum and/or tungsten compounds onto the support material precursor, wherein the catalyst is activated by treatment with a reducing agent before it is used as a polymerization catalyst.

    METHOD OF PRODUCING POLYTETRAHYDROFURANE

    公开(公告)号:SK38397A3

    公开(公告)日:1997-11-05

    申请号:SK38397

    申请日:1995-09-21

    Applicant: BASF AG

    Abstract: A method is disclosed of producing polytetrahydrofurane or polytetrahydrofurane monoesters of C1 - C10 monocarboxylic acids by polymerisation of tetrahydrofurane on a heterogenous catalyst in the presence of one of the following telogens: water, 1,4-butane diol, polytetrahydrofurane with a molecular weight of 200 - 700 Da, a C1 - C10 monocarboxylic acid, or mixtures of these telogens. The catalyst used is a carrier catalyst which contains a catalytically active quantity of an oxygen-containing tungsten or molybdenum compound or mixtures of such compounds on an oxide carrier material and has undergone calcination at temperatures of 500 - 1000 C after the precursors of the oxygen-containing molybdenum and/or tungsten compounds have been deposited on the carrier material precursor.

    METHOD OF OBTAINING POLYTETRAHYDROFURANE

    公开(公告)号:PL319300A1

    公开(公告)日:1997-08-04

    申请号:PL31930095

    申请日:1995-09-21

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03651 Sec. 371 Date Mar. 10, 1997 Sec. 102(e) Date Mar. 10, 1997 PCT Filed Sep. 21, 1995 PCT Pub. No. WO96/09335 PCT Pub. Date Mar. 28, 1996A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C1-C10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C1-C10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500 DEG to 1000 DEG C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.

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