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公开(公告)号:JPS63150246A
公开(公告)日:1988-06-22
申请号:JP29542487
申请日:1987-11-25
Applicant: BASF AG
Inventor: FISCHER ROLF , HOELDERICH WOLFGANG , SAUERWALD MANFRED
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公开(公告)号:JPS63165365A
公开(公告)日:1988-07-08
申请号:JP31639487
申请日:1987-12-16
Applicant: BASF AG
Inventor: MERGER FRANZ , PRIESTER CLAUS-ULRICH , FISCHER ROLF , SAUERWALD MANFRED
IPC: C07D201/08
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公开(公告)号:ES2191950T3
公开(公告)日:2003-09-16
申请号:ES98936425
申请日:1998-07-15
Applicant: BASF AG
Inventor: BREITSCHEIDEL BORIS , WALTER MARC , KRATZ DETLEF , SCHULZ GERHARD , SAUERWALD MANFRED
Abstract: A carbonyl compound or a mixture of two or more carbonyl compounds is catalytically hydrogenated in the presence of a Raney copper catalyst in the form of nuggets.
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公开(公告)号:HU202181B
公开(公告)日:1991-02-28
申请号:HU206589
申请日:1989-05-02
Applicant: BASF AG
Inventor: DECKER MARTIN , FRANZISCHKA WOLFGANG , IRNICH RUDOLF , SAUERWALD MANFRED
Abstract: Acid chlorides are prepared by reaction of carboxylic acids or anhydrides thereof with phosgene in the presence of a carboxamide of the formula I in which R denotes a radical of the formulae R denotes an alkyl radical having 2 to 9 carbon atoms, R denotes an alkyl radical having 1 to 9 carbon atoms, R and R denote hydrogen atoms or alkyl radicals having 1 to 9 carbon atoms, the two radicals R and R can also represent a hydrocarbon radical which completes the molecule portion to give a heterocycle, it being possible for the alkyl and hydrocarbon radicals mentioned additionally to contain substituents which are inert under the reaction conditions.
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公开(公告)号:HU198470B
公开(公告)日:1989-10-30
申请号:HU281685
申请日:1985-07-24
Applicant: BASF AG
Inventor: SAUERWALD MANFRED , DOCKNER TONI , ROHR WOLFGANG , REISSENWEBER GERNOT
IPC: A01N43/18 , C07D335/02
Abstract: 5,6-Dihydro-2H-thiopyran-3-carboxaldehydes of the formula where R denotes hydrogen or methyl, are prepared by a method in which acrolein or crotonaldehyde is reacted with hydrogen sulfide in a mineral oil whose boiling point is higher than those of the starting materials and of the end product, and the 5,6-dihydro-2H-thiopyran-3-carboxaldehyde is obtained by distillation. These aldehydes are important intermediates for the preparation of some crop protection agents.
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公开(公告)号:ES2192039T3
公开(公告)日:2003-09-16
申请号:ES99911740
申请日:1999-03-05
Applicant: BASF AG
Inventor: HESSE MICHAEL , KRATZ DETLEF , SCHULZ GERHARD , WALTER MARC , SAUERWALD MANFRED
IPC: B01J23/72 , C07B61/00 , C07C29/141 , C07C31/20 , C07C31/22
Abstract: A process for the catalytic hydrogenation of a carbonyl compound or of a mixture of two or more carbonyl compounds in the presence of a catalyst which comprises an inorganic support containing TiO2, and as active component copper or a mixture of copper and at least one of the metals selected from the group of zinc, aluminum, cerium, a noble metal and a group VIII metal, wherein the copper surface area does not exceed 10 m2/g.
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公开(公告)号:DE59904157D1
公开(公告)日:2003-03-06
申请号:DE59904157
申请日:1999-03-05
Applicant: BASF AG
Inventor: HESSE MICHAEL , KRATZ DETLEF , SCHULZ GERHARD , WALTER MARC , SAUERWALD MANFRED
IPC: B01J23/72 , C07B61/00 , C07C29/141 , C07C31/20 , C07C31/22
Abstract: A process for the catalytic hydrogenation of a carbonyl compound or of a mixture of two or more carbonyl compounds in the presence of a catalyst which comprises an inorganic support containing TiO2, and as active component copper or a mixture of copper and at least one of the metals selected from the group of zinc, aluminum, cerium, a noble metal and a group VIII metal, wherein the copper surface area does not exceed 10 m2/g.
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公开(公告)号:DE19809418A1
公开(公告)日:1999-09-09
申请号:DE19809418
申请日:1998-03-05
Applicant: BASF AG
Inventor: HESSE MICHAEL , KRATZ DETLEF , SCHULZ GERHARD , WALTER MARC , SAUERWALD MANFRED
IPC: B01J23/72 , C07B61/00 , C07C29/141 , C07C31/20 , C07C31/22 , C07B41/02 , C07C29/136 , C07C31/02
Abstract: The invention relates to a method for the catalytic hydrogenation of a carbonyl compound or of a mixture comprised of two or more carbonyl compounds in the presence of a catalyst. Said catalyst comprises an inorganic supporting material containing TiO2, and, as an active component, copper or a mixture of copper with at least one of the metals selected from the group zinc, aluminum, cerium, a precious metal and a metal of subgroup VIII. The invention is characterized in that the copper surface amounts to a maximum of 10 m /g.
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公开(公告)号:DE3782811D1
公开(公告)日:1993-01-07
申请号:DE3782811
申请日:1987-12-09
Applicant: BASF AG
Inventor: DOCKNER TONI DR , SAUERWALD MANFRED , FISCHER ROLF DR , HUTMACHER HANS-MARTIN DR , PRIESTER CLAUS-ULRICH DR , VAGT UWE DR
IPC: C07D201/08 , C07D201/16
Abstract: Caprolactam (I) is prepd. by heating 6-aminocaproic acid, its esters, amides or mixts. of these (II) in the presence of an inert hydrocarbon reaction medium (III) having b.pt. higher than that of (I), the process comprising heating the (III) at 150-350 deg.C, adding the (II) at a rate at which it is decomposed, and removing (I) from the reaction medium as it is formed.
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公开(公告)号:DE3772335D1
公开(公告)日:1991-09-26
申请号:DE3772335
申请日:1987-11-23
Applicant: BASF AG
Inventor: FISCHER ROLF , HOELDERICH WOLFGANG , SAUERWALD MANFRED
IPC: B01J27/16 , B01J23/02 , B01J27/00 , B01J27/18 , B01J29/00 , B01J29/08 , B01J29/70 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533
Abstract: Prodn. of 3-pentenoate esters of formula (I) is effected by (a) reacting a 2-pentenoate ester of formula (I) with an amine, alcohol or mercaptan of formula (III) at 200-300 deg. C, opt. in the presence of a basic catalyst, (b) contacting the prod. (IV) with an acid catalyst in the liq. or gas phase at 150-450 deg. C to form a mixt. of (I) and (II), and (c) sepg. (I) from the mixt.. In the formulae Y = XR2 or NR3R4; X = O or S; R1 and R2 = 1-12C alkyl, 5-8C cycloalkyl, 7-10c aralkyl or 6-10C aryl; R3 = H, 1-12C alkyl, 5-8C cycloalkyl, 7-10C aralkyl or 6-10C aryl; or NR3R4 is a 5- to 7-membered ring opt. contg. another N or O atom.
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