公开(公告)号：DE50106337D1

公开(公告)日：2005-06-30

申请号：DE50106337

申请日：2001-09-17

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: In a process for the hydroformylation of ethylenically unsaturated compounds, at least one complex of a metal of transition group VIII. with at least one phosphorus-, arsenic- or antimony-containing compound as ligand is used as hydroformylation catalyst, where the compound used as ligand in each case comprises two groups which comprise a P, As or Sb atom and at least two further hetero atoms and are bound to a xanthene-like molecular framework. New compounds of this type and catalysts which comprise at least one complex of a metal of transition group VIII. with at least one such compound as ligand are also provided.

公开(公告)号：CA2543673A1

公开(公告)日：2005-05-12

申请号：CA2543673

申请日：2004-10-28

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  SCHEIDEL JENS ,  LUYKEN HERMANN ,  FLORES MIGUEL ANGEL ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG

IPC: C07F9/50 ,  B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/07 ,  C07C255/09 ,  C07F9/12 ,  C07F9/48 ,  C07F9/6574

Abstract: The invention relates to phosphinite phosphites I of formula 1, 2, 3, 4, 5 or 6 and mixtures thereof, wherein R1, R2, R4 independently represent an alkyl or alkylene group with 1 to 8 carbon atoms, provided that at least one of the groups R1, R2, R4 is different from H; R5 to R22 independently represent H, an alkyl or alkylene group with 1 to 8 carbon atoms; R3 is H, methyl or ethyl; X is F, Cl or CF3, if n=1 or 2 and X is H, if n=0.

公开(公告)号：DE10314761A1

公开(公告)日：2004-10-14

申请号：DE10314761

申请日：2003-03-31

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J23/755 ,  B01J31/02 ,  B01J31/14 ,  B01J31/18 ,  C07C253/10 ,  C07C255/04 ,  B01J31/12 ,  B01J31/24 ,  C07B43/08

Abstract: A system which is suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds and comprises a) Ni(0) b) a compound which complexes Ni(0) as a ligand and contains trivalent phosphorus, c) a Lewis acid and d) a compound of the formula M Rn where M: Al or Ti R: identical or different monovalent alkoxy radicals, in which case a plurality of alkoxy radicals may be bonded together, and additionally, in the case that M=Al, R may be identical or different monovalent alkyl radicals, in which case a plurality of alkyl radicals may be bonded together or one or more alkyl radicals may be bonded to one or more of the abovementioned alkoxy radicals, n: valency of M, and processes for hydrocyanating an olefinically unsaturated compound in the presence of such a system.

公开(公告)号：DE10311119A1

公开(公告)日：2004-09-23

申请号：DE10311119

申请日：2003-03-12

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE

IPC: C07C255/07 ,  C07C253/30

Abstract: Isomerization of 2-methyl-3-butenonitrile (I) to linear pentenonitrile (II) in the presence of zero-valent nickel, a tridentate phosphorus ligand and a Lewis acid comprises removing a mixture of (I) and (II) from the reaction mixture during isomerization.

公开(公告)号：AU2003246375A1

公开(公告)日：2004-02-02

申请号：AU2003246375

申请日：2003-07-04

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  SCHEIDEL JENS

IPC: B01J31/18 ,  B01J27/32 ,  B01J31/40 ,  B01J38/00 ,  C07B61/00 ,  C07C253/10 ,  C07C255/04 ,  C07C255/07

Abstract: A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound. The method comprises a) removing the complex compound from mixture (I) to give a mixture (II), b) adding water to mixture (II) and placing mixture (II) under pressure and temperature conditions to provide a phase (III) and a phase (IV), c) adding a liquid diluent (V) which c1) does not form an azeotrope with water and whose boiling point under certain pressure conditions is higher than that of water, or c2) forms an azeotrope or heteroazeotrope with water under certain pressure conditions, to phase (III), d) subjecting the mixture of phase (III) and liquid diluent (V) to distillation under the pressure conditions mentioned in step c1) or c2), and e) subjecting mixture (VII) to hydrocyanation of an olefinically unsaturated compound to give the nitrile.

公开(公告)号：CA2464710A1

公开(公告)日：2003-04-24

申请号：CA2464710

申请日：2002-10-04

Applicant: BASF AG

Inventor： MOLNAR FERENC ,  HADERLEIN GERD ,  ALTMAYER MARCO ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BARTSCH MICHAEL ,  BAUMANN ROBERT

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylen e group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2.

公开(公告)号：BR0015200A

公开(公告)日：2002-06-18

申请号：BR0015200

申请日：2000-10-25

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  FISCHER JAKOB ,  JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  SIEGEL WOLFGANG

IPC: B01J31/22 ,  B01J31/02 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/03 ,  C07C255/07 ,  C07C255/19 ,  C07F9/145 ,  C07F15/04

Abstract: New phosphites (I), with alkylaryl, arylaryl and/or condensed aryl groups, have 1, 2 or 3 o-substituted and optionally 1 or 2 m- and/or p-substituted aryl groups. New phosphites of formula (I), with alkylaryl, arylaryl and/or condensed aryl groups, have 1, 2 or 3 o-substituted and optionally 1 or 2 m- and/or p-substituted aryl groups; P(O-R 1>)(O-R 2>) y(O-R 3>) z(O-R 4>) p (I) R 1>an aromatic group with a 1-18 carbon (C) alkyl, an aromatic substituent or a condensed aromatic system in the o-position to the oxygen (O) atom linking the phosphorus (P) atoms to the aromatic system; R 2>a similar aromatic group substituted in the m-position; R 3>a similar aromatic group substituted in the p-position; R 4>an aromatic group with a different substituent in the o-, m- or p-position and a hydrogen (H) atom in the o-position; x : 1 or 2; y, z, p : 0, 1 or 2; (x+y+z+p) : 3 Independent claims are also included for: (a) new transition metal complexes (II) with (I) as ligand; (b) the preparation of (I); (c) the preparation of (II); (d) the addition of hydrogen cyanide to an olefinic double bond in the presence of (II) as catalyst; and (e) the isomerization of organic nitriles in the presence of (II) as catalyst.

公开(公告)号：DE10049265A1

公开(公告)日：2002-04-11

申请号：DE10049265

申请日：2000-09-28

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCAL ,  BAUMANN ROBERT ,  BASLER PETER ,  SIEGEL WOLFGANG

IPC: C07C253/34 ,  C07C255/07 ,  C07C253/32

Abstract: The invention relates to a method for separating pentenenitrile isomers having a relative volatility alpha in the region 1.0 - 1.3 in a pressure range of 1 - 500 kPa by means of separation. According to said method, the distillation is carried out in the presence of a liquid diluent which forms azeotropes with the pentenenitrile isomers in the same pressure conditions, whose relative volatility alpha is higher than the pentenenitrile isomers which are to be separated.

公开(公告)号：AU8991901A

公开(公告)日：2002-04-08

申请号：AU8991901

申请日：2001-09-25

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  BASSLER PETER ,  SIEGEL WOLFGANG

IPC: C07C253/34 ,  C07C255/07

Abstract: A process is provided for the distillative separation of pentene nitrile isomers which have a relative volatility alpha ranging from 1.0 to 1.3 in the pressure range from 1 to 500 kPa, wherein the distillation is carried out in the presence of a liquid diluent which forms with the pentene nitrile isomers, under the same pressure conditions, azeotropes whose relative volatility alpha is higher than that of the pentene nitrile isomers to be separated.

公开(公告)号：DE10046025A1

公开(公告)日：2002-03-28

申请号：DE10046025

申请日：2000-09-18

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCAL ,  HADERLEIN GERD ,  SIEGEL WOLFGANG ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  B01J31/12 ,  C07F15/04

Abstract: Production of adiponitrile from butadiene and hydrogen cyanide uses a catalyst comprising a Group VIII metal complex having at least one tricyclic bifunctional phosphorus, arsenic or antimony ligand. Production of adiponitrile by: (a) reacting butadiene with hydrogen cyanide in the presence of a catalyst, (b) optionally catalytically isomerizing the resulting mixture of pentenonitriles to covert branched nitriles to linear nitriles, and (c) reacting the nitrile mixture with hydrogen cyanide in the presence of a catalyst comprises performing steps (a), (b) and/or (c) in the presence of a catalyst comprising a Group VIII metal complex having at least one ligand of formula (I). A , A = O, Si, SiRR, NR or CRR; R = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; Y , Y = groups comprising one or more P, As or Sb atoms, each directly bonded to at least two O, S or NR' heteroatoms; R' = H, alkyl, cycloalkyl or aryl; R -R = R, COOR', COOM, SO2R', SO3M, N(R')2, N(R')3 X , OR', SR', (CHR''CH2O)xR', (CH2NR')xR', (CH2CH2NR')xR', halogen, CF3, NO2, acyl or CN, or R and/or R can form fused ring systems with 1-3 rings; R = H, Me or Et; M = a cation; X = an anion; x = 1-120. An Independent claim is also included for a process for isomerizing branched aliphatic monoalkenonitriles to linear aliphatic monoalkenonitriles using such a catalyst.