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公开(公告)号:CH642377A5
公开(公告)日:1984-04-13
申请号:CH1147379
申请日:1979-12-27
Applicant: DEGUSSA
Inventor: SCHWARZ RUDOLF DR , KLEINSCHMIT PETER DR , LIEDTKE-MOELLER CHRISTA , WOLFF SIEGFRIED
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公开(公告)号:CH640872A5
公开(公告)日:1984-01-31
申请号:CH421979
申请日:1979-05-04
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , TAN EWE HONG
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公开(公告)号:RO72488A
公开(公告)日:1983-04-29
申请号:RO8108275
申请日:1975-01-10
Applicant: DEGUSSA
Inventor: POCHERT JOHANNES , WOLFF SIEGFRIED , THURN FRIEDRICH
IPC: C08L7/00 , B29C35/00 , B29C55/00 , B29C65/00 , B29C65/70 , C08J5/10 , C08K3/00 , C08K5/00 , C08K5/548 , C08K7/00 , C08L21/00 , C08L61/10 , C08L67/00 , C08L77/00
Abstract: Silica containing mixtures for the improvement of the adhesion of vulcanizable mixtures of natural and/or synthetic rubber to reinforcing fillers or supports of textile and/or metallic fabrics after the vulcanization are prepared that substantially consist of (A) active synthetically produced silica or silicates having a specific surface area according to the BET procedure of about 50 to 500 m2/g and an average primary particle size of from about 5 to 100 and at least one of (B) phenolic resin or aminoplast forming components, namely on the one hand phenols and/or amines and on the other hand aldehydes or aldehyde donors, and/or at least (C) one organosilane which can be a bisalkoxysilylalkyl-oligosulfide of the formula I. Z-Alk-Sn-Alk-Z, in which Z stands for the group R1 R1 R2 ¦ ¦ ¦ (a)-Si-R1, (b)-Si-R2 or (c)-Si-R2 ¦ ¦ ¦ R
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公开(公告)号:HU180711B
公开(公告)日:1983-04-29
申请号:HUDE000865
申请日:1974-10-10
Applicant: DEGUSSA
Inventor: BURMESTER KURT , WOLFF SIEGFRIED , KLOETZER ERHARD , THURN FRIEDRICH
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公开(公告)号:CA1144936A
公开(公告)日:1983-04-19
申请号:CA342418
申请日:1979-12-20
Applicant: DEGUSSA
Inventor: SCHWARZ RUDOLF , KLEINSCHMIT PETER , LIEDTKE CHRISTA , WOLFF SIEGFRIED
IPC: C08L7/00 , C07F7/08 , C07F7/12 , C07F7/18 , C08G75/02 , C08G75/14 , C08K5/5425 , C08K5/548 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K5/54
Abstract: Bis-(silyl-ethyl)-oligosulphide obtained by reacting a vinyl silane having the formula (CH2=CH)m-SiR?R4-(m+n) wherein R represents chlorine, iodine, C1-C3-alkoxy, 2-methoxy-ethoxy, 2-ethoxy-ethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m + n is 1, 2 or 3, with sulphur and, when required, with hydrogen sulphide in a molar ratio ranging from 1:2.5 to 1:10 and of vinyl silane to hydrogen sulphide from 1:0 to 0:5 at a temperature between approximately 100 and 200.degree.C under a pressure ranging from 1 to 25 bars (total pressure at the reaction temperature) and in the presence of Sulphidation catalysts and when required hydrolysis or partial hydrolysis of the reaction product. The corresponding process of production and the use of a bis-(silyl-ethyl)-oligosulphide as a reinforcing additive (adhesion promoter) in a crosslinkable rubber mixture containing a silicate filler and when required carbon black as well as sulphur and other conventional mixture components are also disclosed.
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公开(公告)号:RO67260A
公开(公告)日:1981-09-24
申请号:RO7656073
申请日:1973-11-07
Applicant: DEGUSSA
Inventor: THURN FRIEDRICH , BURMESTER KURT , POCHERT JOHANNES , WOLFF SIEGFRIED
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公开(公告)号:AU6118280A
公开(公告)日:1981-02-19
申请号:AU6118280
申请日:1980-08-08
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , TAN EWE-HONG
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公开(公告)号:DE2910991A1
公开(公告)日:1980-10-02
申请号:DE2910991
申请日:1979-03-21
Applicant: DEGUSSA
Inventor: KREHER ALFONS DR , KUEHNER GERHARD DR , ROTHBUEHR LOTHAR DR , TUERK GUENTER DR , WOLFF SIEGFRIED
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公开(公告)号:NO142310B
公开(公告)日:1980-04-21
申请号:NO743298
申请日:1974-09-13
Applicant: DEGUSSA
Inventor: BURMESTER KURT , WOLFF SIEGFRIED , KLOETZER ERHARD , THURN FRIEDRICH
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公开(公告)号:CH602841A5
公开(公告)日:1978-08-15
申请号:CH25175
申请日:1975-01-10
Applicant: DEGUSSA
Inventor: POCHERT JOHANNES , WOLFF SIEGFRIED , THURN FRIEDRICH
IPC: C08L7/00 , B29C35/00 , B29C55/00 , B29C65/00 , B29C65/70 , C08J5/10 , C08K3/00 , C08K5/00 , C08K5/548 , C08K7/00 , C08L21/00 , C08L61/10 , C08L67/00 , C08L77/00 , C08K3/34
Abstract: Silica containing mixtures for the improvement of the adhesion of vulcanizable mixtures of natural and/or synthetic rubber to reinforcing fillers or supports of textile and/or metallic fabrics after the vulcanization are prepared that substantially consist of (A) active synthetically produced silica or silicates having a specific surface area according to the BET procedure of about 50 to 500 m2/g and an average primary particle size of from about 5 to 100 and at least one of (B) phenolic resin or aminoplast forming components, namely on the one hand phenols and/or amines and on the other hand aldehydes or aldehyde donors, and/or at least (C) one organosilane which can be a bisalkoxysilylalkyl-oligosulfide of the formula I. Z-Alk-Sn-Alk-Z, in which Z stands for the group R1 R1 R2 ¦ ¦ ¦ (a)-Si-R1, (b)-Si-R2 or (c)-Si-R2 ¦ ¦ ¦ R
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