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    GAS-PHASE PROCESS FOR THE POLYMERIZATION OF PROPYLENE
    15.
    发明申请
    GAS-PHASE PROCESS FOR THE POLYMERIZATION OF PROPYLENE 审中-公开
    丙烯聚合的气相工艺

    公开(公告)号：WO2017021454A1

    公开(公告)日：2017-02-09

    申请号：PCT/EP2016/068555

    申请日：2016-08-03

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MORINI, Giampiero ,  COVEZZI, Massimo ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

    IPC: C08F2/34 ,  C08F110/06 ,  C08F4/651 ,  C08F4/649

    CPC classification number: C08F110/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/34 ,  C08F2500/15 ,  C08F2500/18 ,  C08F2500/12 ,  C08F110/02 ,  C08F4/6492

    Abstract: A gas-phase process for the homo or copolymerization of propylene with other olefins, carried out in the presence of a catalyst system comprising: (a) a solid catalyst component comprising Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor compound selected from specific classes; said components (a) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from 2 to 200. The process is capable to give polypropylene product having good morphological properties, high stereoregularity, and capable to show self- extinguishing properties such that the negative effects caused by the fine catalyst particle polymerization can be selectively solved or mitigated.

    Abstract translation: 丙烯与其它烯烃同时或共聚的气相方法，在催化剂体系存在下进行，该催化剂体系包含：（a）包含Mg，Ti，卤素的固体催化剂组分，选自1,3-二醚的电子给体和 特定量的烯烃聚合物; （b）烷基铝化合物和（c）选自特定类别的外部电子给体化合物; 所述组分（a）和（c）的用量使得Al /（ED）的摩尔比范围为2-200。该方法能够得到具有良好形态特性，高立构规整性并能显示自身的聚丙烯产物 - 可以选择性地解决或减轻由催化剂微粒聚合引起的负面影响的灭火性能。

    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS
    17.
    发明申请
    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS 审中-公开
    制备多孔丙烯聚合物的方法

    公开(公告)号：WO2015059117A1

    公开(公告)日：2015-04-30

    申请号：PCT/EP2014/072501

    申请日：2014-10-21

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GADDI, Benedetta ,  BOCCHINO, Marco ,  COLLINA, Gianni ,  FUSCO, Ofelia ,  GUIDOTTI, Simona ,  MAZZUCCO, Antonio ,  PANTALEONI, Roberto ,  PIEMONTESI, Fabrizio

    IPC: C08F10/06 ,  C08F210/06

    CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

    Abstract: Process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55°C; optionally, ii) pre-polymerizing with one or more olefins of formula CH 2 =CHR, where R is H or a C 1 -C 10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C 4 -C 10 alpha olefins producing said porous propylene (co)polymer.

    Abstract translation: 在催化剂体系存在下进行的多孔丙烯的制备方法，该催化剂体系包含（a）含有至少两种电子给体化合物的齐格勒 - 纳塔催化剂，其中一种催化剂体系以50至90摩尔％的量存在， 相对于供体的总量，选自琥珀酸盐，另一种选自1,3-二醚，（b）烷基铝，包括以下步骤：i）使催化剂组分（a）和（b）接触一段时间 时间为1至60分钟，温度范围为35至55℃; 任选地，ii）使用一种或多种式CH 2 = CHR的烯烃进行预聚合，其中R是H或C1-C10烃基，直至每克固体催化剂组分约0.1至约1000g的聚合物的形成量 （一个）; 和iii）在少量乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯，生产所述多孔丙烯（共）聚合物。

    PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE
    18.
    发明申请
    PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE 审中-公开
    制备1-BOTENE聚合物的方法

    公开(公告)号：WO2010118962A1

    公开(公告)日：2010-10-21

    申请号：PCT/EP2010/054356

    申请日：2010-03-31

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  VITALE, Gianni ,  PIEMONTESI, Fabrizio ,  MINGOZZI, Ines ,  CAMURATI, Isabella, Maria, Vittoria ,  PELLEGATTI, Giampaolo

    Inventor： VITALE, Gianni ,  PIEMONTESI, Fabrizio ,  MINGOZZI, Ines ,  CAMURATI, Isabella, Maria, Vittoria ,  PELLEGATTI, Giampaolo

    IPC: C08F10/08 ,  C08F4/649 ,  C08F4/654

    CPC classification number: C08F10/08 ,  C08F110/08 ,  C08F210/08 ,  C08F4/6494 ,  C08F2500/03 ,  C08F2500/15 ,  C08F2500/17 ,  C08F210/06 ,  C08F210/16

    Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH 2 =CHZ wherein Z is a C 3 -C 20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl 2 (b) an alkylaluminum co catalyst; and (c) a compound of formula (I) as external donor Wherein: R 1 , R 2 , R 3 and R 4 , equal to or different from each other, are hydrogen atoms or C 1 -C 20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two R 1 , R 2 , R 3 and R 4 can be joined to form a C 5 -C 20 , saturated or unsaturated ring.

    Abstract translation: 一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法，其中α-烯烃选自式CH 2 = CHZ的乙烯，丙烯或α-烯烃，其中Z为C 3 -C 20烷基，其包括使1- 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下，包括：（a）固体组分，其包含Ti化合物和负载在MgCl 2上的内部电子给体化合物（b）烷基铝助催化剂 ; 和（c）作为外部给体的式（I）化合物，其中R1，R2，R3和R4彼此相同或不同，是氢原子或任选含有属于第13-17族的杂原子的C 1 -C 20烃基 的元素周期表; 或两个R 1，R 2，R 3和R 4可以连接形成C 5 -C 20饱和或不饱和环。

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