公开(公告)号：DE19636765A1

公开(公告)日：1998-03-12

申请号：DE19636765

申请日：1996-09-10

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FLICK KLEMENS ,  LUYKEN HERMANN ,  REHFINGER ALWIN ,  BASLER PETER

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C253/08

Abstract: The invention concerns a process for simultaneously preparing 6-aminocapronitrile and hexamethylene diamine proceeding from a mixture which contains a phosphorated compound and substantially adipodinitrile and is obtained by reacting butadiene with hydrocyanic acid in the presence of a catalyst containing a phosphorated compound. The process is characterized in that: (1) the portion by weight of a phosphorated compound, calculated as phosphorus, in the mixture is reduced; (2) the resultant mixture is partially hydrogenated in the presence of a catalyst in order to form an alpha-, omega aminonitrile; and (3) 6-aminocapronitrile and hexamethylene diamine are separated from the mixture.

公开(公告)号：DE102004042949A1

公开(公告)日：2006-03-09

申请号：DE102004042949

申请日：2004-09-02

Applicant: BASF AG

Inventor： SCHEIDEL JENS ,  JUNGKAMP TIM ,  BAUMANN ROBERT ,  LUYKEN HERMANN ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  PFAB PETER ,  SIEGEL WOLFGANG ,  BASLER PETER

IPC: C07C253/08 ,  C07C253/30 ,  C07C253/34 ,  C07C255/07

Abstract: Producing 3-pentenonitrile comprises isomerizing a 2-methyl-3-butenonitrile feed stream in the presence of a dissolved or dispersed catalyst, distilling the product stream to separate an overhead stream (2) from a catalyst-containing bottoms stream, distilling stream (2) to obtain an overhead stream enriched in (Z)-2-methyl-2-butenonitrile and a bottoms stream (5), and distilling stream (5) to produce a bottoms stream containing 3-pentenonitrile and an overhead stream containing 2-methyl-3-butenonitrile.

公开(公告)号：DE10328714A1

公开(公告)日：2005-01-13

申请号：DE10328714

申请日：2003-06-25

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  BASLER PETER ,  ROEPER MICHAEL

IPC: C07C51/44 ,  C07C67/54 ,  C07C231/24 ,  C07C253/32 ,  C07B63/00 ,  C07C253/34 ,  C07C255/07 ,  C07C255/03 ,  C07C255/04 ,  C07C67/48 ,  C07C69/44 ,  C07B37/02 ,  C07B35/02

Abstract: A process for removing a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group, from a mixture which comprises a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group, and a compound which is homogeneous with respect to the mixture and contains rhodium, by distillation.

公开(公告)号：DE10318697A1

公开(公告)日：2004-11-25

申请号：DE10318697

申请日：2003-04-24

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  BASLER PETER ,  ROEPER MICHAEL

IPC: C07C67/303 ,  C07C67/343 ,  C07B35/02 ,  C07C69/44 ,  C07C253/30 ,  C07C255/04 ,  C07C255/19

Abstract: A process for hydrogenating a monoolefinically unsaturated compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group, carboxamide group to a saturated compound which bears the same at least two functional groups, in the presence of a rhodium-containing compound, as a catalyst, which is homogeneous with respect to the reaction mixture.

公开(公告)号：ZA200301089B

公开(公告)日：2004-04-21

申请号：ZA200301089

申请日：2003-02-10

Applicant: BASF AG

Inventor： BASLER PETER ,  FISCHER ROLF-HARTMUTH ,  LOTH WOLFGANG ,  WINTERLING HELMUT

IPC: C08G69/04 ,  C08G69/00 ,  C08G69/08 ,  C08G69/16 ,  C08G

Abstract: The continuous process for preparing a polyamide by reacting at least one aminonitrile with water comprises:(1) reacting at least one aminonitrile with water in the presence of an organic liquid diluent at from 90 to 400° C. and from 0.1 to 35x10 Pa in a flow tube containing a Brönsted acid catalyst selected from a beta-zeolite catalyst, a sheet-silicate catalyst or a titanium dioxide catalyst comprising from 70 to 100% by weight of anatase and from 0 to 30% by weight of rutile and in which up to 40% by weight of the titanium dioxide may be replaced by tungsten oxide, to obtain a reaction mixture,(2) further reacting the reaction mixture at from 150 to 400° C. and a pressure which is lower than the pressure in stage 1 in the presence of a Brönsted acid catalyst selected from a beta-zeolite catalyst, a sheet-silicate catalyst or a titanium dioxide catalyst comprising from 70 to 100% by weight of anatase and from 0 to 30% by weight of rutile and in which up to 40% by weight of the titanium dioxide may be replaced by tungsten oxide, the temperature and pressure being selected so as to obtain a first gas phase and a first liquid phase or a first solid phase or a mixture of first solid and first liquid phases and so that the first gas phase is separated from the first liquid phase or first solid phase or from the mixture of first liquid and first solid phases, and(3) admixing the first liquid or the first solid phase or the mixture of first liquid and first solid phases with a gaseous or liquid phase comprising water at from 150 to 370° C. and from 0.1 to 30x10 Pa, to obtain a product mixture.

公开(公告)号：DE10233382A1

公开(公告)日：2004-01-29

申请号：DE10233382

申请日：2002-07-23

Applicant: BASF AG

Inventor： BASLER PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  RUDOLF PETER

IPC: B01D3/14 ,  C07D301/32 ,  C07C29/80 ,  C07C31/20 ,  C07D301/14

公开(公告)号：DE10059716A1

公开(公告)日：2002-06-06

申请号：DE10059716

申请日：2000-11-30

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  BENISCH CHRISTOPH ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  BASLER PETER ,  MAIXNER STEFAN

IPC: C07C209/84 ,  C07C211/09 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for reducing the content of an aliphatic, monounsaturated amine (III) in a mixture (IV) containing an aminonitrile (I) or a diamine (II), or mixtures thereof and an amine (III). Said method is characterised in that a) mixture (IV) is reacted with an anionic nucleophile (V) in a quantity ranging between 0.01 and 10 mol per mol of amine (III) in mixture (IV) to obtain a mixture (VI). The invention is also characterised in that b) aminonitrile (I) or diamine (II) or mixtures thereof are removed by distillation from mixture (VI), at a temperature ranging between 50 and 170 DEG C and a pressure of between 0.5 and 100 kPa.

公开(公告)号：DE10021199A1

公开(公告)日：2001-11-08

申请号：DE10021199

申请日：2000-05-03

Applicant: BASF AG

Inventor： BASLER PETER ,  BAUMANN DIETER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  MELDER JOHANN-PETER ,  OHLBACH FRANK

IPC: C07D223/10 ,  C07B61/00 ,  C07D201/08 ,  C07D201/16

Abstract: The invention relates to a method for producing caprolactam, characterized in that a) a mixture (I) containing 6-aminocapronitrile and water in the liquid phase is converted into a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers in the presence of a catalyst; b) ammonia is then removed from mixture (II), leaving a mixture (III) containing caprolactam, water, high boilers and low boilers; c) water is then removed from mixture (III) leaving a mixture (IV) containing caprolactam, high boilers and low boilers, and d) a solid (V) containing caprolactam is obtained from mixture (IV) by crystallization, the proportion by weight of caprolactam in the solid (V) being greater than that in the mixture (IV).

公开(公告)号：DE10021191A1

公开(公告)日：2001-11-08

申请号：DE10021191

申请日：2000-05-03

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  WINTERLING HELMUT ,  ANSMANN ANDREAS ,  FISCHER ROLF ,  MELDER JOHANN-PETER ,  MAIXNER STEFAN ,  BASLER PETER ,  LUYKEN HERMANN

IPC: C08J5/18 ,  C08G69/04 ,  C08G69/14 ,  C08G69/16 ,  C07D201/08 ,  C07D201/16 ,  C07D223/10

Abstract: The invention relates to a method for producing a polymer. Said method is characterized as follows: a) a mixture (I) containing 6-aminocapronitrile and water is converted into a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers in the presence of a catalyst; then b) the ammonia is removed from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers; subsequently c) the water is completely or partially eliminated from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers; and finally d) mixture (IV) is subjected to a polymerization reaction. The invention also relates to a polymer obtained according to said method, to its use in the production of fibres, flat material and moulded bodies that are obtained using a polymer of this type.

公开(公告)号：DE10015246A1

公开(公告)日：2001-10-04

申请号：DE10015246

申请日：2000-03-28

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  RIEBER NORBERT ,  WALCH ANDREAS ,  BASLER PETER ,  REHFINGER ALWIN ,  WENZEL ANNE ,  HARDER WOLFGANG

IPC: B01J8/02 ,  B01J29/90 ,  C07D301/12 ,  C07B33/00 ,  B01J38/00 ,  B01J8/00

Abstract: Continuous reaction of an organic compound with hydroperoxide using a catalyst comprises using at least two parallel reactors and a high stream flow. An independent claim is included for the apparatus used comprising at least two parallel isothermal fixed bed reactors, a separator(s) and an adiabatic fixed bed reactor(s).