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公开(公告)号:AT276220T
公开(公告)日:2004-10-15
申请号:AT01976290
申请日:2001-10-09
Applicant: BASF AG
Inventor: BOETTCHER ARND , OOST CARSTEN , HAAKE MATHIAS
IPC: C07B61/00 , C07C5/10 , C07C13/18 , C07C209/72 , C07C211/35
Abstract: In a process for hydrogenating unsubstituted monocyclic or polycyclic aromatics or monocyclic or polycyclic aromatics substituted by at least one alkyl group, amino group or hydroxyl group or a combination of two or more thereof to form the corresponding cycloaliphatics by means of gaseous hydrogen in the presence of at least one catalyst in a reaction column (4) in which the reactants are passed over the catalyst(s) (5) fixed in the reaction column (4), the cycloaliphatics are taken off at a side offtake (14) or from the bottom of the column (6) through a line (8) or at the side offtake (14) and from the bottom of the column (6) through a line (8).
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公开(公告)号:AT261940T
公开(公告)日:2004-04-15
申请号:AT00981362
申请日:2000-12-11
Applicant: BASF AG
Inventor: PREISS THOMAS , BOETTCHER ARND , PINKOS ROLF , LORENZ RUDOLF ERICH
IPC: C07D223/12 , C07B61/00 , C07C231/08 , C07D207/26 , C07D207/267 , C07D211/76 , C07D223/10
Abstract: A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises using as the cocatalyst diols of the general formula (I)where Xis branched or unbranched alkylene selected from the group consisting ofwhere R1 to R6 are independently hydrogen or C1- to C4-alkyl;orbranched or unbranched cyclic alkylene of 3 to 14 carbon atoms including 3 to 12 ring carbon atoms,their monoalkenyl ethers, their dialkenyl ethers or mixtures thereof.
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公开(公告)号:AT250020T
公开(公告)日:2003-10-15
申请号:AT01921359
申请日:2001-03-29
Applicant: BASF AG
Inventor: BOETTCHER ARND , PINKOS ROLF , LORENZ RUDOLF ERICH
IPC: C07B61/00 , C07C41/08 , C07C43/16 , C07C43/176
Abstract: Alkenyl ethers are prepared by reacting the corresponding alcohols or phenols with acetylenes in the liquid phase in the presence of basic alkali metal compounds and a cocatalyst comprising compounds of the formula (Ia) and/or (Ib)R1O-(CH2CH2CH2CH2O)n-H (Ia)R1O-(CH2CH2CH2CH2O)n-H2, (Ia)where R1, R2 are, independently of one another, C1-C6-alkyl or C2-C6-alkenyl, or R1 and R2 together form a butyl unit and n is 1, 2, 3, 4 or 5.
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公开(公告)号:DE59808306D1
公开(公告)日:2003-06-12
申请号:DE59808306
申请日:1998-12-18
Applicant: BASF AG
Inventor: BRUNNER MELANIE , BOETTCHER ARND , BREITSCHEIDEL BORIS , HALBRITTER KLAUS , HENKELMANN JOCHEM , THIL LUCIEN , PINKOS ROLF
Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.
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公开(公告)号:DE10145119A1
公开(公告)日:2003-04-03
申请号:DE10145119
申请日:2001-09-13
Applicant: BASF AG
Inventor: SCHAEFER MARTIN , BOETTCHER ARND , KRAMER ANDREAS , HOEHN ARTHUR , LIANG SHELUE , FUNKE FRANK
IPC: C07C209/22 , C07B61/00 , C07C209/26 , C07C211/07 , C07C211/03
Abstract: A process for the production of amines comprises catalytic hydrogenation-amination of carbonyl compounds and/or alcohols containing at least 50 ppm halogen (with respect to the mixture ) with nitrogen compounds in the presence of Co and/or Ni containing catalysts and solid acid cocatalysts. A process for the production of amines of formula R R CH-NR R (1) by catalytic hydrogenation-amination of carbonyl compounds of formula R -C(=O)-R (2) and/or alcohols of formula R -CH(OH)-R (3) containing at least 50 ppm halogen (with respect to the mixture ) with nitrogen compounds of formula HNR R (4) in the presence of Co and/or Ni containing catalysts and solid acid cocatalysts. R -R = H, 1-12C alkyl, 3-12C cycloalkyl, 6-10C aryl or 7-11C aralkyl.
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公开(公告)号:DE10144631A1
公开(公告)日:2003-03-27
申请号:DE10144631
申请日:2001-09-11
Applicant: BASF AG
Inventor: SCHAEFER MARTIN , BOETTCHER ARND , KRAMER ANDREAS , HOEHN ARTHUR , KACZMAREK REINHARD , HENKES ERHARD
IPC: B01J23/42 , B01J23/44 , B01J23/63 , C07B61/00 , C07D207/32 , C07D207/323 , C07D213/06 , C07D213/133 , C07D213/16 , C07D213/24
Abstract: Production of pyrroles (I) or pyridines (III), comprises dehydrogenating the corresponding pyrrolidines (II) or piperidines (IV) in the presence of a supported noble metal catalyst comprises performing the reaction in the presence of 1-50 wt.% water. Production of pyrroles of formula (I) or pyridines of formula (III), comprises dehydrogenating the corresponding pyrrolidines of formula (II) or piperidines of formula (IV) in the presence of a supported noble metal catalyst comprises performing the reaction in the presence of 1-50 wt.% water. R -R = H or 1-6C aliphatic group.
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公开(公告)号:AU2002314150A1
公开(公告)日:2002-12-23
申请号:AU2002314150
申请日:2002-06-07
Applicant: BASF AG
Inventor: BOETTCHER ARND , VANOPPEN DOMINIC , ARNDT JAN-DIRK , HENKELMANN JOCHEM , KNOLL KONRAD
IPC: B01J21/08 , B01J23/46 , B01J37/18 , C07C5/10 , C07C29/141 , C07C29/17 , C07C29/19 , C07C29/20 , C07C51/36 , C07C209/48 , C07C209/72 , C07C211/03 , C07C211/11 , C07C211/35 , C07C211/36 , C07D295/023 , C08F8/04
Abstract: Hydrogenation of organic compound(s) (I) comprises contacting (I) with a gas containing hydrogen in the presence of a catalyst (A) containing ruthenium, obtained by treating an amorphous silicon dioxide-based carrier material at least once with a halogen-free aqueous solution of a low molecular ruthenium compound and drying and immediately reducing the obtained solid with hydrogen. Hydrogenation of organic compound(s) (I) comprises contacting (I) with a gas containing hydrogen in the presence of a catalyst (A) containing ruthenium and optionally other Group I, VII or VIII transition metal(s), obtained by treating an amorphous silicon dioxide-based carrier material at least once with a halogen-free aqueous solution of a low molecular ruthenium compound and drying at less than 200 deg C and immediately reducing the obtained solid with hydrogen at 100-350 deg C.
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公开(公告)号:DE10128204A1
公开(公告)日:2002-12-12
申请号:DE10128204
申请日:2001-06-11
Applicant: BASF AG
Inventor: BOETTCHER ARND , VANOPPEN DOMINIC , ARNDT JAN-DIRK
IPC: B01J21/08 , B01J23/46 , B01J37/18 , C07B61/00 , C07D303/30 , C08G59/14 , C08G59/24 , C07D303/28
Abstract: Production of cycloaliphatic compounds that have side chains containing epoxy groups is claimed. A process for the production of cycloaliphatic compounds (I) that have side chains containing epoxy groups comprises heterogeneously catalyzed hydrogenation of a compound (II), having at least one carbocyclic aromatic group and at least one side chain having at least one epoxy group, at a ruthenium catalyst whereby the catalyst is prepared by: (A) a single or multiple treatment of an amorphous silicon dioxide support material with a halogen free solution of a low mol. wt. ruthenium compound followed by drying at below 200 deg C; (B) reduction of the resulting solid with hydrogen at 100-350 deg C such that step (B) is carried out immediately after step (A).
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公开(公告)号:DE10100752A1
公开(公告)日:2002-07-11
申请号:DE10100752
申请日:2001-01-10
Applicant: BASF AG
Inventor: BOETTCHER ARND , PINKOS ROLF , LORENZ RUDOLF ERICH
IPC: C07D201/18 , C07D223/10 , C07D227/087 , B65D90/06 , B65D88/74 , B65D81/18 , B65D81/38
Abstract: A method of storing and transporting N-vinyl-epsi-caprolactam is provided wherein the N-vinyl-epsi-caprolactam is kept in the liquid phase.
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公开(公告)号:DE10038747A1
公开(公告)日:2002-02-21
申请号:DE10038747
申请日:2000-08-09
Applicant: BASF AG
Inventor: LORENZ RUDOLF ERICH , BOETTCHER ARND , PINKOS ROLF
IPC: B01D3/14 , C07B63/00 , C07C41/42 , C07C43/16 , C07C209/84 , C07C211/21 , C07D223/10 , C07D223/12 , C07D233/58 , C07D521/00 , C07D201/16
Abstract: Purification of alkenyl compounds with a 2- or 3- times bonded heteroatom alpha to the double bond involves \- 2 distillations to condense purified alkenyl compounds from the gas phase, the process being such that: (i) the time gap between the first distillation following the synthesis and any further distillation is \- 1 day; and (ii) the purified compound has an APHA color index below 30.
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