-
公开(公告)号:BRPI0415542A
公开(公告)日:2006-12-26
申请号:BRPI0415542
申请日:2004-10-15
Applicant: BASF AG
Inventor: DIETSCHE FRANK , KLIPPEL FRANK , KLUEGLEIN MATTHIAS , GOETHLICH ALEXANDER
Abstract: The present invention relates to a substantially chromium-free process for passivating metallic surfaces of Zn, Zn alloys, Al or Al alloys by treating the surface with an acidic aqueous formulation which comprises at least one substantially noncrosslinked, water-soluble polymer or copolymer containing at least 50% by weight of (meth)acrylic acid units and comprises water or an aqueous solvent mixture comprising at least 50% by weight of water, and by further treating the surface with at least one water-soluble crosslinker comprising at least 2 crosslinking groups selected from the group consisting of azirane, oxirane, and thiirane groups. The invention further relates to passivating layers obtainable by means of the process and to a formulation suitable for this process.
-
公开(公告)号:DE102005027568A1
公开(公告)日:2006-12-21
申请号:DE102005027568
申请日:2005-06-14
Applicant: BASF AG
Inventor: WITTELER HELMUT , BERTKAU WALTER , HEIDENFELDER THOMAS , GOETHLICH ALEXANDER
IPC: C23C22/12
Abstract: Process for the passivation of metallic surfaces, in particular of strip metals, by treatment of the surface with an acidic, aqueous preparation which comprises at least one water-soluble acid group-containing polymer and at least one wax.
-
公开(公告)号:DE102005061317A1
公开(公告)日:2007-06-21
申请号:DE102005061317
申请日:2005-12-20
Applicant: BASF AG
Inventor: GOETHLICH ALEXANDER , VANDERMEULEN GUIDO , HICKL MARKUS , DORNBUSCH MICHAEL , WITTELER HELMUT , FERNANDEZ GONZALEZ MONICA
IPC: C09D5/08 , B05D7/16 , C09D5/12 , C09D5/46 , C09D175/06
Abstract: Method for applying integrated pre-treatment layers with a thickness of 1-25 mu m, comprises applying cross linkable preparation on the metallic surface and thermally- and/or photochemically cross linking the layer, where the preparation contains e.g. corrosion protection agent, which is a copolymer from (a) monoethylenic unsaturated hydrocarbon, (b) 4-8C monoethylenic unsaturated dicarboxylic acid and (c) other ethylenic unsaturated monomers. Method for applying integrated pre-treatment layers with a thickness of 1-25 mu m to metallic surfaces, comprises applying a cross linkable preparation (A) on the metallic surface and thermally- and/or photochemically cross linking the applied layer, where (A) contains at least 20-70 wt.% of at least one thermal and/or photochemical cross linkable binder system, 20-70 wt.% of at least fine particle-inorganic fillers with an average particle size of less than 10 mu m, 0.25-40 wt.% of at least one corrosion protection agent and optionally a solvent, where the corrosion protection agent is at least a copolymer, obtained from (a) 70-30 mol.% of at least a monoethylenic unsaturated hydrocarbon (a1) and/or at least one monomer (monoethylenic unsaturated hydrocarbons modified with functional groups X 1> (a2) and vinylethers (a3)), (b) 30-70 mol.% of at least 4-8C monoethylenic unsaturated dicarboxylic acid, its anhydride and/or derivatives (where the derivatives are esters of dicarboxylic acids with alcohols of formula (HO-R 1>-X 2> n), amides, imides with ammonia and/or amines of formula (HR 2>N-R 1>-X 2> n)) and (c) 0-10 mol.% of other ethylenic unsaturated monomers, which are different from (a) and (b), but are copolymerizable with (a) and (b), where the quantities in each case are referred to the total quantity of all monomer units in the copolymer. R 1>(n+1)-value of 1-40C hydrocarbons, optionally substituted with non-adjacent C-atoms and O and/or N; R 2>H, 1-10C hydrocarbon group or -(R 1>-X 2> n); n : 1-3; and X 2>a functional group. Independent claims are included for: (1) a molded article with a metallic surface, which is coated with an integrated pretreatment layer with a thickness of 1-25 mu m obtained by the above procedure; and (2) a preparation (A) for applying integrated pretreatment layers on metallic surfaces.
-
公开(公告)号:CA2595970A1
公开(公告)日:2006-08-03
申请号:CA2595970
申请日:2006-01-24
Applicant: BASF AG
IPC: C09D5/08 , C08F8/34 , C08F222/06 , C08F255/10 , C09D133/02 , C09D133/06 , C09D135/02
Abstract: Copolymers which comprise dicarboxylic acid units modified with -SR, -CSNR 2 and/or -CN units, and also at least one further comonomer. Processes for preparing them by polymer-analogous reaction, and their use as corrosion inhibitors.
-
公开(公告)号:AU5839701A
公开(公告)日:2001-11-20
申请号:AU5839701
申请日:2001-05-11
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , PACIELLO ROCCO , ROPER MICHAEL , HOFMANN PETER , TENSFELDT MARKUS , GOETHLICH ALEXANDER
-
公开(公告)号:DE10023471A1
公开(公告)日:2001-11-15
申请号:DE10023471
申请日:2000-05-12
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , PACIELLO ROCCO , ROEPER MICHAEL , HOFMANN PETER , TENSFELDT MARKUS , GOETHLICH ALEXANDER
Abstract: Hydroformylation of olefins is carried out in presence of a catalyst comprising a Sub-Group VIII metal complex with a ligand in which two phenyl groups substituted with phosphorus-, arsenic- or antimony-containing residues are attached to a non-aromatic, 3- to 8-membered, carbo- or hetero-cyclic, divalent bridging group. A method for the hydroformylation of compounds with ethylenic double bond(s) by reaction with hydrogen and carbon monoxide in presence of a hydroformylation catalyst, in which the catalyst comprises complex(es) of Sub-Group VIII metal(s) with ligand(s) of formula (I). X = a non-aromatic, 3- to 8-membered, carbo- or hetero-cyclic divalent bridging group with 1, 2 or 3 double bonds and 1, 2, 3 or 4 substituents selected from alkyl, cycloalkyl, aryl, heteroaryl, alkoxy, acyl, carboxyl, alkoxycarbonyl, hydroxy, nitro, cyano, trifluoromethyl, oxo (or their ketals) or -NE E , and X may be part of a condensed ring system with 1, 2 or 3 other rings (optionally with 1, 2 or 3 substituents as above), and X itself may be bridged by -O-, -S-, -N(Ra)- or another bridging group; E , E = alkyl, cycloalkyl or aryl; Ra = H, alkyl, cycloalkyl or aryl; Z , Z = a phosphorus-, arsenic- or antimony-containing residue. An Independent claim is also included for a catalyst as above.
-
公开(公告)号:BRPI0605834A
公开(公告)日:2007-12-18
申请号:BRPI0605834
申请日:2006-06-13
Applicant: BASF AG
Inventor: WITTELER HELMUT , BERTKAU WALTER , HEIDENFELDER THOMAS , GOETHLICH ALEXANDER , HAAS JENS , KLIPPEL FRANK , SCHORNICK GUNNAR
Abstract: Process for the passivation of metallic surfaces by treatment of the surface with an acidic, aqueous preparation which comprises at least one water-soluble acid group-containing polymer and Zn, Ca, Mg or Al ions, said process being in particular a continuous process for the passivation of strip metals.
-
公开(公告)号:CA2611399A1
公开(公告)日:2006-12-21
申请号:CA2611399
申请日:2006-06-13
Applicant: BASF AG
Inventor: WITTELER HELMUT , BERTKAU WALTER , HEIDENFELDER THOMAS , GOETHLICH ALEXANDER
IPC: C23C22/53 , C08L33/14 , C09D133/14 , C23C22/56
Abstract: Process for the passivation of metallic surfaces, in particular of strip metals, by treatment of the surface with an acidic, aqueous preparation which comprises at least one water-soluble acid group-containing polymer and at least one wax.
-
公开(公告)号:DE102004041127A1
公开(公告)日:2006-03-02
申请号:DE102004041127
申请日:2004-08-24
Applicant: BASF AG
Inventor: MICHL KATHRIN , GERST MATTHIAS , KLIPPEL FRANK , GOETHLICH ALEXANDER , DIETSCHE FRANK , WITTELER HELMUT
IPC: C08F220/04 , C08F220/06 , C08F222/04 , C08F222/06 , C09J133/00 , C23C22/00
Abstract: Partially neutralized carboxylate-rich copolymers, processes for their preparation and methods of using the same are disclosed, the copolymers comprising: monomers (A), (B), and (C); wherein monomer (A) comprises at least one monoethylenically unsaturated monocarboxylic acid, and is present in an amount of 30% to 79.99% by weight; wherein monomer (B) comprises at least one monoethylenically unsaturated dicarboxylic acid selected from the group consisting of acids corresponding to general formula I, acids corresponding to general formula II, anhydrides thereof, and other hydrolyzable derivatives thereof, and is present in an amount of 20.01% to 70% by weight: (HOOC)R1C-CR2(COOH) (I) R1R2C-C(-(CH2)n-COOH)(COOH) (II) wherein R1 and R2 each independently represent H or a straight-chain or branched, optionally substituted alkyl radical having 1 to 20 carbon atoms, or, in the case of (I), R1 and R2 together being an optionally substituted alkylene radical having 3 to 20 carbon atoms, and n represents an integer from 0 to 5; wherein monomer (C) comprises at least one additional ethylenically unsaturated comonomer, and is present in an amount of 0% to 40% by weight; wherein the carboxylate-rich copolymer is partially neutralized with at least one amine and the carboxylate-rich copolymer has a degree of neutralization of 2 to 18 mol %, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids; and wherein the carboxylate-rich copolymer has an average molecular weight Mw of at least 3000 g/mol.
-
公开(公告)号:DE10349728A1
公开(公告)日:2005-05-25
申请号:DE10349728
申请日:2003-10-23
Applicant: BASF AG
Inventor: DIETSCHE FRANK , KLIPPEL FRANK , KLUEGLEIN MATTHIAS , GOETHLICH ALEXANDER
Abstract: The present invention relates to a substantially chromium-free process for passivating metallic surfaces of Zn, Zn alloys, Al or Al alloys by treating the surface with an acidic aqueous formulation which comprises at least one substantially noncrosslinked, water-soluble polymer or copolymer containing at least 50% by weight of (meth)acrylic acid units and comprises water or an aqueous solvent mixture comprising at least 50% by weight of water, and by further treating the surface with at least one water-soluble crosslinker comprising at least 2 crosslinking groups selected from the group consisting of azirane, oxirane, and thiirane groups. The invention further relates to passivating layers obtainable by means of the process and to a formulation suitable for this process.
-
-
-
-
-
-
-
-
-