2-O-[(pyrimidin-4-yl)methylenoxy]phenylacetic acid derivative and its use for fighting fungal and animal pest

    公开(公告)号:CZ290963B6

    公开(公告)日:2002-11-13

    申请号:CZ168698

    申请日:1996-12-11

    Applicant: BASF AG

    Abstract: In the present invention there is disclosed a 2-O-[(pyrimidin-4-yl)methylenoxy]phenylacetic acid derivative of the general formula I, in which Re1 represents hydrogen or alkyl containing 1 to 4 carbon atoms, Re2 represents a halogen, alkyl having 1 or 2 carbon atoms or a haloalkyl with 1 to 2 carbon atoms in the alkyl moiety, Re3 represents hydrogen, amino, OH, mercapto, a halogen, alkyl containing 1 to 8 carbon atoms being optionally substituted with phenyl, which itself can be optionally substituted with 1 or 2 substituents that are independent on each other and that are selected from the group comprising a halogen, CN, NOi2, alkyl containing 1 to 4 carbon atoms, haloalkyl containing 1 to 4 carbon atoms, haloalkoxy containing 1 to 4 carbon atoms or Re3 represents a haloalkyl containing 1 to 8 carbon atoms and alkoxyalkyl having 1 to 8 carbon atoms in the alkoxy and 1 to 4 carbon atoms in the alkyl moiety, alkoxy containing 1 to 8 carbon atoms, monoalkylamino containing 1 to 8 carbon atoms in the monoalkyl moiety, dialkylamino having 1 to 8 carbon atoms in the dialkyl moiety, alkylthio containing 1 to 8 carbon atoms, alkylsulfoxyl with 1 to 8 carbon atoms, alkylsulfonyl containing 1 to 8 carbon atoms, cycloalkyl having 3 to 8 carbon atoms, trialkylsilyloxy with 1 to 8 carbon atoms in the alkyl moiety, or phenyl, phenoxy, phenoxymethyl, benzyloxy or heteroaryl being optionally substituted in the aromatic ring, Re4 represents hydrogen, CN, a halogen, alkyl containing 1 to 4 carbon atoms, haloalkyl with 1 to 4 carbon atoms in the alkyl moiety or alkoxy containing 1 to 4 carbon atoms, Q represents the group {C(=NOCHi3)-CONHCHi3}, {C(=NOCHi3)-COOCHi3} or {N(OCHi3)-COOCHi3}. The invented derivative or salt and N-oxides thereof are effective compounds used for fighting fungal and animal pest.

    New phenyl carbamate derivatives
    17.
    发明专利

    公开(公告)号:DE19745650A1

    公开(公告)日:1999-04-22

    申请号:DE19745650

    申请日:1997-10-16

    Applicant: BASF AG

    Abstract: Substituted oxy- or oxymethylenephenyl-oxazolidine and -oxazolidinedione derivatives (I) are new. They are prepared from new activated phenyl-oxazolidine derivatives (IIA) and activated phenyl-oxazolidinedione derivatives (IVB), which in turn are obtained via new substituted nitrobenzene and aniline derivatives (1), phenyl isocyanates (2) and substituted anilides (3). Substituted oxy- or oxymethylenephenyl-oxazolidine and -oxazolidinedione derivatives (I) are new: Y = halo; 1-4C alkyl; 1-4C haloalkyl; or 1-4C alkoxy; n = 0-2; E = group of formula (a) or (b): Ra = halo; CN; 1-4C alkyl or 1-4C alkoxy optionally substituted by halo; 3-6C alkenyloxy, 3-6C alkynyloxy; 3-6C cycloalkyl; S(O)m-1-4C alkyl; or NRaRb; m = 0-2; Ra and Rb = H; 1-4C alkyl; 3-6C alkenyl; or 3-6C alkynyl; Rb = 1-4C alkyl; 1-4C haloalkyl; 3-6C cycloalkyl; or optionally substituted arylmethylene; T = O or oxymethylene; Z' = X; N=CWR ; or N=C(R )-C(R )=NOR ; X = optionally substituted heterocyclyl, aryl, heteroaryl, arylmethylene or heteroarylmethylene; W = optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl or heteroaryl; R = H; CN; 1-4C alkyl; 1-4C haloalkyl; 1-4C alkoxy; 1-4C alkoxy-1-4C alkyl; or 3-6C cycloalkyl; R = H; CN; halo; C(Rd)=NOR3; W; OW; SW or NRcW; Rc = H; alk yl; alkenyl; or alkynyl; Rd = H or alkyl; R = H; or optionally substituted alkyl, alkenyl or alkynyl. Independent claims are also included for: (A) activated phenyl-oxazolidine derivatives of formula (IIA); (B) activated phenyl-oxazolidinedione derivatives of formula (IVB); (C) substituted nitrobenzene and aniline derivatives of formula (1); (D) phenyl isocyanates of formula (2); and (E) Substituted anilides (3). L = OH; CH3; CH2L'; or L'; L' = nucleophilic leaving group; La = CH3; CH2L'; NO2; alkylsulphonate; or arylsulphonate; Q = NH2 or NO2; T' = OZ'; CH2O-X; or CH2O-N=C(R )-C(R )=NOR ; Z' = N=CWR or N=C(R )-C(R )=NOR ; E asterisk = NH-C(O)-NH-OH; NH-C(O)-O-NH-C(O)-OR; NH-C(S)-R'; or NH-C(NOH)-R'; R = 1-4C alkyl; R' = 1-4C alkyl; 1-4C haloalkyl; or 3-6C cycloalkyl.

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