公开(公告)号：DE19645948A1

公开(公告)日：1998-05-14

申请号：DE19645948

申请日：1996-11-07

Applicant: BASF AG

Inventor： BAUMGAERTEL MICHAEL DR ,  DEMBEK GERHARD DR ,  HAHN KLAUS DR ,  HOLOCH JAN DR ,  HUSEMANN WOLFRAM DR ,  KAEMPFER KNUT DR ,  LAY PETER N ,  RUECK SWEN ,  SCHIESL MICHAEL ,  WITT MICHAEL DR

IPC: C08F257/02 ,  C08J9/20 ,  C08F12/08 ,  C08L25/06

Abstract: The invention concerns a continuous process for preparing expandible styrene polymers by polymerizing styrene in the presence of expanding agents in three stages: a) preparing a solution of polystyrene in styrene; b) dispersing the solution in an aqueous phase; and c) continuously polymerizing out the prepolymer in an aqueous suspension.

公开(公告)号：DE59009920D1

公开(公告)日：1996-01-11

申请号：DE59009920

申请日：1990-09-15

Applicant: BASF AG

Inventor： HEEL HELMUT DR ,  HOLOCH JAN DR ,  ESSWEIN GERD DR ,  GOFFING FRIEDRICH DR

IPC: C08F283/01 ,  C08F299/04 ,  C08J3/22 ,  C08K3/00 ,  C08K3/04 ,  C08K5/00 ,  C08K5/04 ,  C08L67/06

Abstract: The invention relates to a process for the preparation of pigmented, curable polyester moulding materials which contain an unsaturated polyester, copolymerisable monomers, a thermoplastic polymer and a coloured pigment. The pigment is dispersed in the molten thermoplastic in an extruder. The moulding materials can be cured to give homogeneously coloured mouldings.

公开(公告)号：ES2056076T3

公开(公告)日：1994-10-01

申请号：ES88109089

申请日：1988-06-08

Applicant: BASF AG

Inventor： HOLOCH JAN DR ,  HESSE ANTON DR ,  LANG REINHOLD DR ,  TRAUTMANN WALTER DR

IPC: C08F299/04 ,  C08K5/20 ,  C08K9/04 ,  C08L67/06

公开(公告)号：DE3876053D1

公开(公告)日：1992-12-24

申请号：DE3876053

申请日：1988-09-09

Applicant: BASF AG

Inventor： HESSE ANTON DR ,  HOLOCH JAN DR ,  PETER ROLAND DR

IPC: C08G18/62 ,  C08F283/00 ,  C08G18/32 ,  C08G18/50 ,  C08G18/63 ,  C08G18/65 ,  C08G18/67 ,  C08G18/68 ,  C08L75/02

Abstract: Thickened, uncured moulding compsn., which is stable at 23 deg.C and cures at temps. above 50 deg.C, contains a liq. reactive system (I), which can be polymerised by free radicals, 1-80 (wt.)%, w.r.t. (I), of a thickener (II) contg. NCO gps., 0.01-5%, w.r.t. (I), of a polymerisation initiator (III), which decomposes above 50 deg.C, and opt. conventional additives. The novelty is that (II) consists of a combination of 0.001-0.5 amine equiv. of an aminobenzoic acid deriv. (IIA), w.r.t. 1000 g (I)+(IIA), and 0.001-1.5 NCO equiv. of an isocyanate (IIB) w.r.t. one equiv. of all NCO-reactive gps. in the moulding compsn. (IIA) is pref. of the formula (H2N-Ar-CO-)nX where Ar = a (substd.) divalent aromatic gp.; n = 1 or 2; X = -O-R1, -NH-R1, -N(R1)2, -O-R-O-, -NH-R-NH-, -NH-R-O-, -NH-R-NR1-, -NR1-R-NR1- or -NR1-R-O-; pref. -O-R-O-or -NH-R-NH-; R = an alkylene, arylene, polyether, polyester, polyamido or polycarbamate gp.; pref. a polyether gp. with a deg. of polymerisation of 1-300 or a 2-20C alkylene gp.; R1 = alkyl or aryl. (I) is a monomer (IA); or a mixt. of min. 5% (IA) and max. 95% satd. or unsatd. oligomer or polymer (IB) dissolved or dispersed in (IA). (IB) pref. is an unsatd. polyester, vinyl ester, vinyl ether urethane, allylated prepolymer, bismaleimide resin or hydrocarbon resin; or a satd. polyester, polyester polyol, polyether polyol, epoxide resin, thermoplastics or elastomer. Suitable additives are 10-400% fibrous reinforcements or 25-300% filler powder or granules w.r.t. (I). When filled with 150 pts. CaCO3 w.r.t. 100 pts. (I)+(II), the compsn. has a viscosity of min. 500000 mPa.s at 23 deg.C. Without fillers and reinforcing fibres, it is soluble in suitable organic solvents, e.g. DMF, and esp. is still practically completely in these solvents, e.g. DMF, after keeping at 23 deg.C for at least 1 day.

公开(公告)号：DE3875279D1

公开(公告)日：1992-11-19

申请号：DE3875279

申请日：1988-06-08

Applicant: BASF AG

Inventor： HOLOCH JAN DR ,  HESSE ANTON DR ,  LANG REINHOLD DR ,  TRAUTMANN WALTER DR

IPC: C08F299/04 ,  C08K5/20 ,  C08K9/04 ,  C08L67/06

Abstract: Compsns. (I) comprise (A) unsatd. polyester (B) 10-90%, on (A)+ (B) of a cpd. copolymerisable with (A) (C) 5-300%, on (A)+(B) of an inorganic filler (D) 0.1-10%, on (A)+(B) of maleamic acid of formula (I) R = alkyl, alkenyl, alkynyl, aryl, or alkylaryl with up to 30C; R1 = H or R.

公开(公告)号：DE3777731D1

公开(公告)日：1992-04-30

申请号：DE3777731

申请日：1987-09-17

Applicant: BASF AG

Inventor： HOLOCH JAN DR ,  DEMMLER KURT DR

IPC: C08F299/04 ,  C08G63/54 ,  C08G63/553

Abstract: Heat-stable mouldings, with high heat distortion temp., are prepd. from unsatd. polyester resins contg. cyclopentene or cyclohexane gps. by hardening in 2 stages: (a) at below 100 deg.C, in the presence of radical-forming cpds. which dissociate at these temps., and (b) at 120-200 deg.C, in presence of radical-forming cpds. with half-life of more than 30 mins. at 120 deg.C.

公开(公告)号：DE3719634A1

公开(公告)日：1988-12-29

申请号：DE3719634

申请日：1987-06-12

Applicant: BASF AG

Inventor： HOLOCH JAN DR ,  SCHWABEN HANS-DIETER DR ,  LAWONN HORST

IPC: C08L67/06 ,  C08L81/04 ,  C08K7/02 ,  C08L9/00 ,  C08L25/06

公开(公告)号：DE3800084A1

公开(公告)日：1988-07-28

申请号：DE3800084

申请日：1988-01-05

Applicant: BASF AG

Inventor： HOLOCH JAN DR ,  SCHOLZ DANKMAR

IPC: C08L67/06 ,  C08L71/02 ,  C08K5/10

Abstract: The invention relates to curable moulding compositions comprising unsaturated polyester resins containing cyclopentene or cyclohexene groups, a product of the reaction of hydroxyl-terminated polyoxybutylene and mono(dicyclopentenyl) maleate, and copolymerisable monomers. They can be cured to give mouldings with a high heat distortion temperature and reduced susceptibility to cracking.

公开(公告)号：DE3701009A1

公开(公告)日：1988-07-28

申请号：DE3701009

申请日：1987-01-15

Applicant: BASF AG

Inventor： HOLOCH JAN DR

IPC: C08L67/06 ,  C08F299/04 ,  C08G63/54 ,  C08G63/553 ,  C08K5/50 ,  C08K5/51 ,  C08K5/524 ,  C08K5/08 ,  C08K5/09 ,  C08K5/13 ,  C08K5/14 ,  C08K5/52

公开(公告)号：DE19710442A1

公开(公告)日：1998-09-17

申请号：DE19710442

申请日：1997-03-13

Applicant: BASF AG

Inventor： GLUECK GUISCARD DR ,  HAHN KLAUS DR ,  HENN ROLF DR ,  WASMER KARL-HEINZ DR ,  LOTH WOLFGANG DR ,  KNOLL KONRAD DR ,  HOLOCH JAN DR ,  GEIGER THOMAS

IPC: C08J9/00 ,  C08J9/14 ,  C08L25/06 ,  C08L53/02 ,  C08L25/10 ,  B29C47/00 ,  C08J9/18 ,  E04B1/74 ,  F16L59/00

Abstract: An expandable styrene polymer (I) contains: (A) a polymer matrix consisting of 70-95 wt.% polystyrene or a styrene copolymer containing up to 50% comonomers and 5-30 wt.% of a styrene-butadiene block copolymer; (B) 1-15 wt.% (with respect to (A)) of a volatile blowing agent; and optionally (C) conventional additives. The block copolymer structure: S-B/S(-S)n, in which S = polystyrene block; B/S = butadiene/styrene copolymer block with a statistical distribution of monomers; and n = 0 or 1, with S blocks comprising 5-40 vol. %. Also claimed are: (i) a process for the preparation of (I) by the addition of (B) during or after mixing of (A); and (ii) an elastomeric foam having density 5-150g/cm , which is prepared from (I).