公开(公告)号：AU2002338398A1

公开(公告)日：2002-11-05

申请号：AU2002338398

申请日：2002-04-17

Applicant: BASF AG

Inventor： POPEL WOLFGANG JURGEN ,  DERNBACH MATTHIAS ,  KOCH MICHAEL ,  MAAS STEFFEN

IPC: B01J21/06 ,  B01J23/72 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C07B61/00 ,  C07C29/141 ,  C07C31/22

Abstract: In a process for the catalytic hydrogenation of a carbonyl compound or a mixture of two or more carbonyl compounds in the presence of catalyst tablets which comprise an inorganic, TiO2-containing support and, as active component, copper or a mixture of copper with at least one metal selected from the group consisting of zinc, aluminum, cerium, nobel metals and metals of transition group VIII and whose copper surface area is not more than 10 m /g, the diameter d and/or the height h of the tablets is less than 3 mm.

公开(公告)号：DE10119719A1

公开(公告)日：2002-10-24

申请号：DE10119719

申请日：2001-04-21

Applicant: BASF AG

Inventor： KOCH MICHAEL ,  MAAS STEFFEN ,  POEPEL WOLFGANG JUERGEN ,  DERNBACH MATTHIAS

IPC: B01J21/06 ,  B01J23/72 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C07B61/00 ,  C07C29/141 ,  C07C31/22 ,  C07B41/02 ,  C07B31/00

Abstract: A catalyst tablet (I) comprises an inorganic titania (TiO2)-containing support and copper as the active component, optionally with zinc, aluminum, cerium and a Group 8 metal. The copper surface area is up to 10 m /g. The tablet has a diameter d and/or height h of less than 3 mm. An Independent claim is also included for catalytic hydrogenation of carbonyl compound(s) in the presence of the catalyst tablets (I).

公开(公告)号：DE10050645A1

公开(公告)日：2002-04-18

申请号：DE10050645

申请日：2000-10-13

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS ,  SIGWART CHRISTOPH ,  HESSE MICHAEL ,  MAAS STEFFEN

IPC: B01J23/44 ,  C07C29/90 ,  C07C31/22 ,  C07C31/12

Abstract: A process for improving the color number of polyhydric alcohols (I), especially trimethylolpropane (TMP), involves catalytic hydrogenation of (I), which is purified by distillation after production. Hydrogenation is carried out in the presence of a macroporous, supported heterogeneous catalyst containing sub-group VII-X metal(s) as the active metal.

公开(公告)号：ES2286159T3

公开(公告)日：2007-12-01

申请号：ES01993593

申请日：2001-11-02

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS ,  KOCH MICHAEL ,  SCHULZ GERHARD ,  WEIGL HAGEN ,  MAAS STEFFEN

IPC: C07C29/141 ,  C07B61/00 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24 ,  C07C45/78 ,  C07C47/19

Abstract: Un proceso para la hidrogenación catalítica de un polimetiloalcanal o un monometiloalcanal de la fórmula (I) En donde R puede ser idéntico o diferente y cada uno es hidrocarburo alifático sustituido o no sustituido que tiene 1 a 22 átomos de carbono, un grupo aril o ariloalquilo que tiene de 6 a 22 pares de átomos de carbono o un grupo metilol, en la presencia de un catalizador que contiene cobre, en donde la alimentación de hidrogenación que comprende el polimetiloalcanal o monometiloalcanal tiene un contenido total de iones de metal de grupos 3 a 14 de la tabla periódica de elementos de hasta 5 ppm.

公开(公告)号：DE102006009839A1

公开(公告)日：2007-09-06

申请号：DE102006009839

申请日：2006-03-01

Applicant: BASF AG

Inventor： MAAS STEFFEN ,  JOHANN THORSTEN ,  STEINIGER MICHAEL ,  SIRCH TILMAN ,  SCHLITTER STEPHAN ,  RITTINGER STEFAN

IPC: C07C29/141 ,  B01J23/72 ,  C07C31/18 ,  C07C31/20

公开(公告)号：DE102006009838A1

公开(公告)日：2007-09-06

申请号：DE102006009838

申请日：2006-03-01

Applicant: BASF AG

Inventor： MAAS STEFFEN ,  JOHANN THORSTEN ,  KOCH MICHAEL ,  SIRCH TILMAN ,  SCHLITTER STEPHAN ,  RITTINGER STEFAN ,  STEINIGER MICHAEL

IPC: C07C29/141 ,  B01J23/72 ,  C07C31/18 ,  C07C31/20

Abstract: A process for catalytically hydrogenating methylolalkanals of the general formula in which R1 and R2 are each independently a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase over a hydrogenation catalyst, which comprises setting a pH of from 7.0 to 9.0 in the hydrogenation effluent by adding at least one tertiary amine, an inorganic base or an inorganic or organic acid to the hydrogenation feed.

公开(公告)号：DE102005049135A1

公开(公告)日：2007-04-19

申请号：DE102005049135

申请日：2005-10-14

Applicant: BASF AG

Inventor： JOHANN THORSTEN ,  MAAS STEFFEN ,  SCHLITTER STEPHAN ,  SIRCH TILMAN ,  KOCH MICHAEL ,  RITTINGER STEFAN ,  STEINIGER MICHAEL ,  PETERSEN HERMANN

IPC: B01J35/02 ,  B01J37/03 ,  C07C29/141

公开(公告)号：DE102004058887A1

公开(公告)日：2006-06-08

申请号：DE102004058887

申请日：2004-12-06

Applicant: BASF AG

Inventor： GRAFMANS HORST ,  MAAS STEFFEN ,  WECK ALEXANDER ,  RUETTER HEINZ ,  SCHULZ MICHAEL ,  ROS KARL-HEINZ

IPC: C07C231/02 ,  C07C233/05

Abstract: A process for preparing N,N-dimethylacetamide (DMAC) by continuously reacting methyl acetate (MeOAc) with dimethylamine (DMA) in the presence of a basic catalyst, wherein MeOAc is used in the form of a methanolic solution and in the range from 0.0002 to 0.09 mol of catalyst per mole of MeOAc, and performing the reaction at a temperature in the range from 90 to 140° C. and at an absolute pressure in the range from 10 to 30 bar.

公开(公告)号：DE10317545A1

公开(公告)日：2004-11-04

申请号：DE10317545

申请日：2003-04-16

Applicant: BASF AG

Inventor： WARTINI ALEXANDER ,  DERNBACH MATTHIAS ,  MAAS STEFFEN ,  MELDER JOHANN-PETER ,  KLEIN ANDREAS ,  SIMON JOACHIM

IPC: C07C29/141 ,  C07C45/75 ,  C07C67/44 ,  C07C27/00 ,  C07C67/00 ,  C07C67/54 ,  C07C69/675

Abstract: Production of neopentyl glycol hydroxypivalate (I) and neopentyl glycol (II) comprises reacting isobutyraldehyde and formaldehyde in the presence of a tertiary amine to form a hydroxypivalaldehyde solution, distilling off low boilers and recycling them to the reaction, separating the bottoms into two streams, hydrogenating one stream to produce (II) and converting the other stream to (I).

公开(公告)号：DE10055180A1

公开(公告)日：2002-05-29

申请号：DE10055180

申请日：2000-11-08

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS ,  KOCH MICHAEL ,  SCHULZ GERHARD ,  WEIGL HAGEN ,  MAAS STEFFEN

IPC: C07B61/00 ,  C07C29/141 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24 ,  C07C45/78 ,  C07C47/19 ,  C07C31/18

Abstract: The invention relates to a method for catalytically hydrating a poly- or monomethylol alkanal of the general formula (I), wherein R is the same or different and may represent a substituted or unsubstituted aliphatic hydrocarbon with 6 to 22 carbon atoms, an aryl or arylalkyl group with 6 to 22 carbon atoms or a methylol group, in the presence of a copper-containing catalyst. The inventive method is characterized in that the poly- or monomethylol alkanal containing batch to be hydrated has a total content of up to 5 ppm of metal ions of the groups 3 to 14 of the periodic system.