公开(公告)号：DE3824958A1

公开(公告)日：1990-01-25

申请号：DE3824958

申请日：1988-07-22

Applicant: BASF AG

Inventor： MAERKL ROBERT DR ,  BERTLEFF WERNER DR ,  SCHUCH GUNTER DR ,  STOPS PETER ,  KUEHN GEBHARD ,  PANITZ PAUL

IPC: B01J31/20 ,  C07B61/00 ,  C07C67/38 ,  C07C69/533

公开(公告)号：ES2009826B3

公开(公告)日：1989-10-16

申请号：ES87111651

申请日：1987-08-12

Applicant: BASF AG

Inventor： KUMMER RUDOLF ,  BERTLEFF WERNER ,  MAERKL ROBERT DR

IPC: C07B61/00 ,  B01J31/00 ,  B01J31/20 ,  B01J31/24 ,  C07C41/00 ,  C07C41/48 ,  C07C43/315 ,  C07C67/00 ,  C07D317/22 ,  C07D319/06 ,  C07D321/06

Abstract: PREPARACION DE 1,1,2-TRIALCOXIETANO (EN EL QUE R1 A R3=RESTOS ALQUILO C1-C8 DONDE R1 Y R3 PUEDEN ESTAR JUNTOS COMBINADOS EN UN ANILLO DE 5 A 7 MIEMBROS) UTILIZANDO ACETALES DE FORMALDEHIDIALQUILO (II) CON MONOXIDO DE CARBONO E HIDROGENO EN LA PREPARACION POR MOL DE MONOXIDO DE CARBONO DE 0,5 A 1,5 MOLES DE HIDROGENO Y AL MENOS 1 MOL DE ALCOHOL R3OH POR MOL DE ACETAL DE FORMALDEHIOLDIALQUILO A TEMPERATURA Y PRESION ELEVADAS Y EN PRESENCIA DE UN CATALIZADOR FORMADO POR UN COMPUESTO DE COBALTO-CARBONILO Y UN COMPUESTO ORGANICO TRIVALENTE EN EL QUE A PUEDE SER FOSFORO, ARSENICO, ANTIMONIO O BISMUTO Y R4 A R6 SIGNIFICAN RESTOS ORGANICOS.

公开(公告)号：DE58902282D1

公开(公告)日：1992-10-22

申请号：DE58902282

申请日：1989-07-21

Applicant: BASF AG

Inventor： MAERKL ROBERT DR ,  HARDER WOLFGANG DR

IPC: B01J31/20 ,  B01J31/40 ,  C07B61/00 ,  C07C67/38 ,  C07C69/533

Abstract: Alkyl pentenoates are prepared by (a) reacting butadiene or a butadiene-containing hydrocarbon mixture with carbon monoxide and an alkanol in the presence of a tertiary aromatic heterocyclic nitrogen base and a cobalt carbonyl catalyst at from 80 DEG to 160 DEG C. under from 100 to 1,000 bar to obtain a reaction mixture which contains alkyl pentenoate, C6-diester, tertiary nitrogen base, alkanol, butadiene, hydrocarbon and by-product, (b) substantially removing from the reaction mixture obtained any excess hydrocarbon, nitrogen base, alkanol and alkyl pentenoate by distillation to obtain a residue which contains cobalt carbonyl catalyst, (c) bringing the residue which contains cobalt carbonyl catalyst into contact with a mixture of carbon monoxide and hydrogen at elevated temperature and elevated pressure, and (d) recycling the residue which contains cobalt carbonyl catalyst into alkyl pentenoate synthesis stage (a).

公开(公告)号：DE3920423A1

公开(公告)日：1991-01-03

申请号：DE3920423

申请日：1989-06-22

Applicant: BASF AG

Inventor： KOEFFER DIETER DR ,  MAERKL ROBERT DR ,  BERTLEFF WERNER DR

IPC: B01J31/04 ,  B01J31/20 ,  B01J31/24 ,  C07B61/00 ,  C07C45/49 ,  C07C45/50 ,  C07C47/198 ,  C07C49/175

公开(公告)号：DE3760955D1

公开(公告)日：1989-12-14

申请号：DE3760955

申请日：1987-08-18

Applicant: BASF AG

Inventor： BERTLEFF WERNER DR ,  MAERKL ROBERT DR ,  MAGNUSSEN PETER DR ,  KUEHN GEBHARD ,  STOPS PETER

IPC: C07C67/38 ,  C07C67/00 ,  C07C67/48 ,  C07C67/54 ,  C07C67/60 ,  C07C69/02 ,  C07C69/34 ,  C07C69/44 ,  C07C69/533 ,  C07D211/70 ,  C07D213/06

Abstract: Aqueous solutions which are obtained in the carbalkoxylation of olefinically unsaturated compounds and contain heterocyclic aromatic nitrogen bases, their transformation products and lower fatty acids and/or their salts are treated by a process in which (a) the aqueous solution is heated to 150 DEG -300 DEG C. under from 10 to 300 bar and (b) heterocyclic aromatic nitrogen bases which are formed again from the transformation products are then separated off.

公开(公告)号：DE3719938A1

公开(公告)日：1988-12-29

申请号：DE3719938

申请日：1987-06-15

Applicant: BASF AG

Inventor： BERTLEFF WERNER DR ,  MAERKL ROBERT DR ,  ROEPER MICHAEL DR

IPC: C07B61/00 ,  B01J31/20 ,  C07C67/313 ,  C07C67/38 ,  C07C69/67

Abstract: omega -Formylalkanecarboxylic esters are prepared by hydroformylation of alkenecarboxylic esters with carbon monoxide and hydrogen at elevated temperature and under elevated pressure in the presence of cobalt carbonyl complexes, in which alpha , beta -unsaturated alkenecarboxylic esters are hydroformylated in the presence of 0.01 to 1 mol% of cobalt carbonyl complexes, calculated as cobalt, while maintaining a conversion of alpha , beta -unsaturated alkenecarboxylic esters of 10 to 70 %.

公开(公告)号：DE3638220A1

公开(公告)日：1988-05-11

申请号：DE3638220

申请日：1986-11-08

Applicant: BASF AG

Inventor： BERTLEFF WERNER DR ,  MAERKL ROBERT DR ,  KUEHN GEBHARD ,  PANITZ PAUL ,  KUMMER RUDOLF DR

IPC: B01J31/20 ,  B01J31/00 ,  C07B61/00 ,  C07C67/38 ,  C07C69/52 ,  C07C69/533 ,  C07C69/44

公开(公告)号：DE3615835A1

公开(公告)日：1987-11-12

申请号：DE3615835

申请日：1986-05-10

Applicant: BASF AG

Inventor： MAERKL ROBERT DR ,  HARDER WOLFGANG DR

IPC: C07B61/00 ,  B01J23/00 ,  B01J31/00 ,  B01J31/22 ,  B01J31/28 ,  C07C27/00 ,  C07C27/06 ,  C07C29/15 ,  C07C29/158 ,  C07C31/20 ,  C07C67/00

Abstract: Ethylene glycol is prepared from carbon monoxide and hydrogen in a homogeneous liquid phase under superatmospheric pressure and at elevated temperatures in the presence of a rhodium-containing catalyst and in the presence of a porphyrin as organic nitrogen-containing promoter.

公开(公告)号：DE19643154A1

公开(公告)日：1998-04-23

申请号：DE19643154

申请日：1996-10-18

Applicant: BASF AG

Inventor： REHFINGER ALWIN DR ,  GANN MARTIN ,  MAERKL ROBERT DR ,  SCHMITT RUEDIGER

IPC: B01J31/24 ,  C07C27/12 ,  C07C29/32 ,  C07C29/44 ,  C07C29/50 ,  C07C31/135 ,  C07C33/02 ,  C07C33/03 ,  C07C33/035 ,  C07C35/08 ,  C07C45/33 ,  C07C45/51 ,  C07C49/403 ,  C07C49/603 ,  C07C49/303

Abstract: The invention concerns a process for preparing oxidation products from cyclohexane by catalytic oxidation with oxygenous gases in the liquid phase. In a reaction zone the gases are brought substantially uniformly into contact with the oxygenous gases, and liquid cyclohexane and the oxygenous gases are passed in counterflow through the reaction zone.

公开(公告)号：DE19626587A1

公开(公告)日：1998-01-08

申请号：DE19626587

申请日：1996-07-02

Applicant: BASF AG

Inventor： HEINEKE DANIEL DR ,  MEISNER RUPRECHT ,  HESSE MICHAEL DR ,  MAERKL ROBERT DR

IPC: B01J21/04 ,  B01J23/72 ,  B01J23/89 ,  B01J32/00 ,  B01J35/10 ,  B01J37/04 ,  C07C45/00 ,  C07C49/403

Abstract: The invention relates to a catalyst comprising alpha -aluminium oxide as the support material and copper as the active constituent, the BET surface (as defined in DIN 66131) of the aluminium oxide being not lower than 30 m /g. It also relates to a process for preparing said catalyst according to the invention, and the use thereof in dehydrogenation of cyclohexanol to form cyclohexanone, and also to the use of alpha -aluminium oxide, the BET surface (as defined in DIN 66131) of said aluminium oxide being not lower than 30 m /g, to prepare a catalyst.