公开(公告)号：JPH1095739A

公开(公告)日：1998-04-14

申请号：JP23921797

申请日：1997-09-04

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  ERDBRUEGGER CHRISTINA F ,  BROECKER FRANZ JOSEF ,  MEYER GERALD ,  SCHWAB EKKEHARD ,  HERION CHRISTOF

IPC: B01J23/56 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/60 ,  B01J23/62 ,  B01J35/06 ,  B01J37/02 ,  C07B61/00 ,  C07C5/05 ,  C07C5/09 ,  C07C7/163 ,  C07C11/02 ,  C07C11/06 ,  C07C11/08 ,  B01J23/63

Abstract: PROBLEM TO BE SOLVED: To hydrogenate polyunsaturated hydrcarbon(s) in a fluid by bringing the hydrocarbon(s) into contact with a catalyst pack in the presence of free hydrogen. SOLUTION: Polyunsaturated 2-8C hydrocarbon(s), esp. 2-8C alkyne and/or 4-8C alkynene and/or 4-8C alkadiene, is brought into contact with a catalyst pack in the presence of free hydrogen. The catalyst pack is prepared by applying an active substance as a catalyst and/or promoter to a woven mesh, knitwear or foil as support material; for example, the support may be coated with the catalytically active compound and promoter by e.g. vacuum deposition. By virtue of using the catalyst, the polyunsaturated hydrocarbon(s) can be converted to the corresponding monounsaturated hydrocarbon(s) in high selectivity and yield, and hydrogenation of isobutene does not occur.

公开(公告)号：WO0189683A2

公开(公告)日：2001-11-29

申请号：PCT/EP0106034

申请日：2001-05-25

Applicant: BASF AG ,  BROECKER FRANZ JOSEF ,  HAAKE MATHIAS ,  STROEZEL MANFRED ,  WOERZ OTTO ,  SCHWAB EKKEHARD

Inventor： BROECKER FRANZ JOSEF ,  HAAKE MATHIAS ,  STROEZEL MANFRED ,  WOERZ OTTO ,  SCHWAB EKKEHARD

IPC: B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C07B61/00 ,  C07C45/38 ,  C07C47/21 ,  F28D9/04

CPC classification number: F28D9/04 ,  B01J12/007 ,  B01J19/0013 ,  B01J19/24 ,  B01J19/248 ,  B01J2219/00085 ,  B01J2219/00096 ,  B01J2219/1944 ,  B01J2219/32466 ,  B01J2219/32475 ,  C07C45/38 ,  C07C47/21

Abstract: The invention relates to a device for carrying out, in a substantially isothermal manner, a heterogeneously catalysed reaction in a gas phase with high heat tonality. The inventive device comprises at least one reactor chamber (101) with an inlet (131, 141) and an outlet (143). The reactor chamber is defined by heat dissipating walls, lying at a substantially constant distance of /m and good thermal conductibility; the reaction gas in the reactor chamber flows at a rate of >/= 200 m per m surface area per hour; and a heat exchange medium flows on the side of the reactor wall opposite the reactor chamber.

Abstract translation: 本发明涉及一种设备，用于在基本等温进行在具有高放热性的气相中的非均相催化反应，其包含具有至少一个反应器室（101）入口（131，141）和出口（143），其中，所述反应器空间由除热壁限定，其 沿的50体积比/米<3>以及良好的导热性，使反应气体以> / = 200米<3>的每m <2>在零入射面的速率将反应器腔室并流过每小时， +和在反应器壁上的反应器空间的相反侧流动的热交换介质。

公开(公告)号：WO2007048853A2

公开(公告)日：2007-05-03

申请号：PCT/EP2006067938

申请日：2006-10-30

Applicant: BASF AG ,  KIESSLICH FRANK ,  CRONE SVEN ,  MACHHAMMER OTTO ,  VAN LAAR FREDERIK ,  SCHWAB EKKEHARD ,  SCHINDLER GOETZ-PETER

Inventor： KIESSLICH FRANK ,  CRONE SVEN ,  MACHHAMMER OTTO ,  VAN LAAR FREDERIK ,  SCHWAB EKKEHARD ,  SCHINDLER GOETZ-PETER

IPC: C07C2/84 ,  C07C15/00

CPC classification number: B01J29/46 ,  C01B3/50 ,  C01B2203/048 ,  C01B2203/0495 ,  C01C3/0212 ,  C07C2/84 ,  C07C2529/06 ,  C07C2529/48 ,  Y02P20/13 ,  C07C15/00

Abstract: The invention relates to a method for producing aromatic hydrocarbons from a C 1 -C 4 alkane or a mixture of C 1 -C 4 alkanes. Said method is characterized in that a) an educt flow A containing a C 1 -C 4 alkane or a mixture of C 1 -C 4 alkanes is brought in contact with a catalyst, and some of the C 1 -C 4 alkane or some of the mixture of C 1 -C 4 alkanes is reacted to aromatic hydrocarbon/s, b) the product flow B resulting from step a) is separated into a low-boiling flow C containing the main portion of the hydrogen and the non-reacted C 1 -C 4 alkane or mixture of C 1 -C 4 alkanes, and a high-boiling flow D or several high-boiling flows D' containing the main portion of the obtained aromatic hydrocarbon, and c) the low-boiling flow C is fed to another process consuming C 1 -C 4 alkane, the hydrogen contained in the low-boiling flow C being optionally eliminated beforehand.

Abstract translation: 本发明涉及一种用于从C _{1 -C 4 烷烃，或C的混合物 1 -C生产芳烃 4 烷烃，其特征在于，a）一种反应物流A，其为C 1 -C 4 烷烃或的混合物 ç 1 -C 4 包含烷烃，被带入与催化剂接触，而C的一部分 1 -C 4 烷烃或C的混合物的一部分 1 -C 4 烷烃芳烃（S），进行反应; b）由步骤a）的产品流B产生，成低沸流C是氢的主要部分和所述未反应的C 1 -C 4 烷烃，或混合 ç 1 -C 4 包含烷烃，和高沸点流D或多种高沸点流D”，其是，或包含所形成的芳香族烃的主要部分或包含导出; 和c）将低沸点流C 4 供给下一个C 1 -C 烷烃耗时的过程，其中，如果必要的话，包含在低锅炉流C的氢被预先分离。}

公开(公告)号：WO0189683A9

公开(公告)日：2004-11-11

申请号：PCT/EP0106034

申请日：2001-05-25

Applicant: BASF AG ,  BROECKER FRANZ JOSEF ,  HAAKE MATHIAS ,  STROEZEL MANFRED ,  WOERZ OTTO ,  SCHWAB EKKEHARD

Inventor： BROECKER FRANZ JOSEF ,  HAAKE MATHIAS ,  STROEZEL MANFRED ,  WOERZ OTTO ,  SCHWAB EKKEHARD

IPC: B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C07B61/00 ,  C07C45/38 ,  C07C47/21 ,  F28D9/04 ,  B01J37/02

CPC classification number: F28D9/04 ,  B01J12/007 ,  B01J19/0013 ,  B01J19/24 ,  B01J19/248 ,  B01J2219/00085 ,  B01J2219/00096 ,  B01J2219/1944 ,  B01J2219/32466 ,  B01J2219/32475 ,  C07C45/38 ,  C07C47/21

Abstract: The invention relates to a device for carrying out, in a substantially isothermal manner, a heterogeneously catalysed reaction in a gas phase with high heat tonality. The inventive device comprises at least one reactor chamber (101) with an inlet (131, 141) and an outlet (143). The reactor chamber is defined by heat dissipating walls, lying at a substantially constant distance of /m and good thermal conductibility; the reaction gas in the reactor chamber flows at a rate of >/= 200 m per m surface area per hour; and a heat exchange medium flows on the side of the reactor wall opposite the reactor chamber.

Abstract translation: 本发明涉及一种设备，用于在基本等温进行在具有高放热性的气相中的非均相催化反应，其包含具有至少一个反应器室（101）入口（131，141）和出口（143），其中，所述反应器空间由除热壁限定，其 沿的50体积比/米<3>以及良好的导热性，使反应气体以> / = 200米<3>的每m <2>在零入射面的速率将反应器腔室并流过每小时， +和在反应器壁上的反应器空间的相反侧流动的热交换介质。

公开(公告)号：WO2006136541A3

公开(公告)日：2007-04-12

申请号：PCT/EP2006063323

申请日：2006-06-20

Applicant: BASF AG ,  VAN LAAR FREDERIK ,  BECKER MICHAEL ,  SCHWAB EKKEHARD ,  HENKELMANN JOCHEM ,  POLANEK PETER

Inventor： VAN LAAR FREDERIK ,  BECKER MICHAEL ,  SCHWAB EKKEHARD ,  HENKELMANN JOCHEM ,  POLANEK PETER

IPC: B01J21/08 ,  B01J23/46 ,  B01J23/656 ,  B01J35/10 ,  B01J37/02 ,  C07B35/00

CPC classification number: B01J23/462 ,  B01J21/08 ,  B01J35/1019 ,  B01J37/0205

Abstract: The invention relates to a shell catalyst containing ruthenium as an active metal, alone or together with at least one other metal of the auxiliary group IB, VIIB or VIII of the periodical system of the elements (CAS version), and applied to a carrier containing silicon dioxide as a carrier material. The invention also relates to a method for producing said shell catalyst, and to a method for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols, using the inventive shell catalyst. The invention further relates to the use of the inventive shell catalyst for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols.

Abstract translation: 本发明涉及一种含有壳催化剂作为活性金属钌单独或与过渡族IB，VIIB中的至少一种另外的金属或元素（CAS版本）的周期表第VIII一起施加到载体包括二氧化硅作为载体材料，用于制造这种壳催化剂的方法 含有氢化的有机化合物，可氢化基团，优选为碳环芳族基团的氢化成相应的碳环脂族基团或用于根据本发明和根据本发明的用于氢化的使用涂层催化剂的醛氢化成相应的醇，该涂层催化剂的Verwendüng下的处理 含有氢化的基团，优选为碳环基团aromatichen的氢化成相应的碳环脂族基团或氢化的有机化合物 醛为相应的醇的UNG。

公开(公告)号：WO02053520A2

公开(公告)日：2002-07-11

申请号：PCT/EP0200054

申请日：2002-01-05

Applicant: BASF AG ,  VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  BASSET JEAN-MARIE ,  THIVOLLE-CAZAT JEAN ,  TAOUFIK MOSTAPHA ,  SCHULZ MICHAEL ,  HOEHN ARTHUR

IPC: C07C6/08 ,  C07C6/10

CPC classification number: C07C6/10 ,  C07C6/08 ,  C07C2531/12

Abstract: The invention relates to a method for producing hydrocarbons having a modified carbon skeleton by reacting aliphatic hydrocarbons a) with themselves, b) with another aliphatic hydrocarbon or c) with aromatic alkyl substituted hydrocarbons, in the presence of a metal organic catalyst or the hybrid thereof, at a temperature of between 20 - 400 DEG C and a pressure of between 0.2 - 100 bars, wherein the reaction takes place in the presence of hydrogen.

Abstract translation: 通过脂族烃反应制备具有改性碳骨架的烃的方法：a）与其本身; b）与另一种脂族烃或c）与芳族烷基取代的烃在有机金属催化剂或其杂化物存在下，在20-400℃的温度和0.2-100巴的压力下，通过在氢存在下 执行。

公开(公告)号：HU229646B1

公开(公告)日：2014-03-28

申请号：HU0400780

申请日：2002-05-16

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  SCHWAB EKKEHARD ,  MUELLER JOERN ,  PENZEL ULRICH ,  GEORGI GUNTER ,  WEIDNER BERND ,  TITTELBACH-HELMRICH DIETRICH ,  DAHLHAUS JUERGEN

IPC: B01J23/755 ,  B01J23/76 ,  B01J21/06 ,  B01J23/78 ,  B01J23/83 ,  B01J35/10 ,  B01J37/03 ,  B01J37/16 ,  C07B61/00 ,  C07C209/36 ,  C07C211/46 ,  C07C211/47 ,  C07C211/50 ,  C07C211/51

Abstract: A catalyst comprising nickel on a TiO 2 support is obtainable by coprecipitation of nickel and at least one further metal selected from among Si, Zr, Hf, alkaline earth metals, Y, La and Ce, and optionally at least one dopant metal selected from groups 5 to 11 of the Periodic Table of the Elements, from a solution in which the corresponding metal salts are present onto a particulate TiO 2 support, subsequent drying, calcination and reduction and optionally passivation to give the nickel-containing catalyst. It is used, in particular, for the hydrogenation of nitroaromatic compounds.

公开(公告)号：CA2435918C

公开(公告)日：2010-03-23

申请号：CA2435918

申请日：2002-01-29

Applicant: BASF AG

Inventor： HAAKE MATHIAS ,  SCHWAB EKKEHARD ,  KOCH MICHAEL ,  MUELLER HANS-JOACHIM ,  STROEZEL MANFRED ,  PETERSEN HERMANN ,  SCHREYER PETER

IPC: C07C51/487 ,  B01J21/18 ,  B01J23/44 ,  B01J32/00 ,  B01J35/02 ,  B01J35/06 ,  B01J35/10 ,  C07B35/02 ,  C07C29/17 ,  C07C63/26

Abstract: The invention relates to a method for cleaning crude terephthalic acid by means of catalytic, hydrogenating aftertreatment using a catalyst material containing at least one hydrogenation metal applied to a carbon carrier consisting of carbon fibres. The invention also relates to a catalyst consisting of the at least one catalyst material containing the at least one hydrogenation metal applied to the carbon fibres, the BET surface of the carbon carrier being

公开(公告)号：CA2393984C

公开(公告)日：2009-09-08

申请号：CA2393984

申请日：2000-12-06

Applicant: BASF AG

Inventor： FRENZEL ANDREA ,  HESSE MICHAEL ,  ANSMANN ANDREAS ,  SCHWAB EKKEHARD

IPC: B01J23/56 ,  B01J23/48 ,  B01J23/50 ,  B01J23/66 ,  B01J35/00 ,  C07B61/00 ,  C07B63/02 ,  C07C5/02 ,  C07C5/08 ,  C07C7/163 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C11/10 ,  C07C11/167

Abstract: The invention relates to a catalytic converter for the selective hydrogenati on of alkines and dienes in C2-C5+ olefin mixtures. Said catalytic system contains (a) a metal from the tenth group of the periodic table of elements, (b) a metal from the eleventh group of the periodic table of elements, (c) optionally, a compound of a metal of the first or second group of the periodic table of elements, whereby said metals are supported on a carrier selected from the group consisting of silicium dioxide, titanium dioxide, zirconium oxides, spinelles, zinc aluminates, zinc titanates, aluminium silicates or mixtures of said substances. The metal stemming from the eleventh group of the periodic table of elements is homogeneously distributed over the cross-section of catalyst particles. The metal stemming from the tenth group of the periodic table of elements is located at the surface-proximate edge layer of said catalyst particles. Said catalytic converter is preferably produced by applying the metal from the eleventh group is preferably applied already during the production of the carrier by dipping it into a solution of a suitable metal salt.

公开(公告)号：DE102005019540A1

公开(公告)日：2006-11-09

申请号：DE102005019540

申请日：2005-04-27

Applicant: BASF AG

Inventor： EBERHARDT JAN ,  HOFFER BRAM WILLEM ,  SCHWAB EKKEHARD ,  MELDER JOHANN-PETER ,  RHEUDE UDO

IPC: B01J35/02 ,  B01J23/00 ,  B01J37/00 ,  C07B43/04 ,  C07C209/60 ,  C07C211/03 ,  C07D265/30

Abstract: Processes for preparing amines comprising reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound in the presence of a heterogeneous catalyst, wherein the heterogeneous catalyst comprises a catalyst packing prepared by applying at least one compound selected from the group consisting of catalytically active metals, compounds of catalytically active metals, and mixtures thereof to a support material selected from the group consisting of woven fabrics, knitted fabrics, foils, and combinations thereof.