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公开(公告)号：DE3260698D1
公开(公告)日：1984-10-18
申请号：DE3260698
申请日：1982-03-30
Applicant: BASF AG
Inventor： FISCHER KARL DR , GRENACHER ARMIN VOLKER DR , HERR MANFRED , STROHMEYER MAX DR
IPC: B01J23/00 , B01J23/46 , C07B61/00 , C07C45/00 , C07C45/50 , C07C45/81 , C07C45/82 , C07C47/02 , C07C67/00
Abstract: Aldehydes are obtained from the gaseous product of the hydroformylation of olefinically unsaturated compounds using a rhodium catalyst by a process (cf. FIG. 2) in which (a) this gaseous product is introduced, without being cooled or depressured, into a distillation column D, (b) the top fraction from this column is cooled in a condenser K so that the greater part of the aldehydes contained therein is condensed, (c) the condensate is separated, in a separator A, into a gas phase and a liquid phase, (d) the gas phase from A, after waste gas has been separated off, is again brought to the hydroformylation pressure by means of a compressor P, and is returned to the reactor as a recycle gas, (e) the liquid phase from A is returned to D, and (f) the aldehydes are taken off from column D as liquid bottom products and/or as a vaporous side stream.
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公开(公告)号：DE2139630A1
公开(公告)日：1973-02-22
申请号：DE2139630
申请日：1971-08-07
Applicant: BASF AG
Inventor： NIENBURG HANS-JUERGEN DR , KUMMER RUDOLF DR , HOHENSCHUTZ HEINZ DR , STROHMEYER MAX DR , TAVS PETER DR
Abstract: Unbranched aldehydes are made by hydroformylation of alkylenically unsatd. cpds. with 2-20 C with CO and H2 at elevated temps. and pressures in the pres. of cobalt carbonyl cpds. by (a) treating aq. soln. of cobalt salts with CO and H2 at 50-200 degrees C and 100-400 atm. in thepres. of active carbon, zeolites or basic ion exchangers charged with cobalt carbonyl, (b) in a second stage, without releasing the pressure, extracting the mixture at 20-100 degrees C and 100-400 atm. with a satd. hydrocarbon or with the unsatd. cpd. to be hydroformylated (provided this is insoluble in water and is liquid under the prevailing conditions) or with (hydrogenated) oxo reaction products is water insoluble, (c) removing the aq. phase and (d) subjecting the resulting carbonyl complex-contg. organic phase and the mixture of CO and H2 (after addition of the alkylenically unsatd. cpds. to be hydroformylated if not used in stage (b)) to hydroformylation at 70-170 degrees C and 100-400 atm. Suitable starting materials are 2-20C alkenes with terminal double bonds, alkene mixtures made by cracking waxes and polymers of ethylene, styrene, butyl, acrylate, etc. Process gives good selectivity to prodn. of unbranched aldehydes, useful in the prodn. of alkanols for washing agents and plasticisers, etc.
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公开(公告)号：MY127613A
公开(公告)日：2006-12-29
申请号：MYPI20012329
申请日：2001-05-17
Applicant: BASF AG
Inventor： HOFFMANN HERWIG DR , ROEPER MICHAEL PROF DR , BLANKERTZ HEINRICH-JOSEF DR , STROHMEYER MAX DR , WALZ HELMUT DR , ZINKE-ALLMANG HELMUT DR
IPC: C07C29/14 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/10 , C07C31/12 , C07C31/125
Abstract: THE INVENTION RELATES TO A PROCESS FOR THE PREPARATION OF SATURATED C3-C20-ALCOHOLS IN WHICH A LIQUID HYDROGENERATION FEED COMPRISING AT LEAST ONE C3-C20-ALDEHYDE IS PASSED OVER A BED OF A HYDROGENERATION CATALYST IN THE PRESENCE OF A HYDROGEN-CONTAINING GAS , WHICH COMPRISES ADDING TO THE HYDROGENERATION FEED AN AMOUNT , HOMOGENEOUSLY SOLUBLE THEREIN , OF A SALT-LIKE BESE . THE ADDITION OF BASE SUPPRESSES SIDE REACTIONS, SUCH AS ACETALIZATION , ALDOLIZATION , TISCHTSCHENKO REACTION OR ETHER FORMATION .
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公开(公告)号：DE3935796A1
公开(公告)日：1991-05-02
申请号：DE3935796
申请日：1989-10-27
Applicant: BASF AG
Inventor： HOFFMANN HERWIG DR , ROEPER MICHAEL DR , SCHULZE JOACHIM DR , STROHMEYER MAX DR , ULRICH BERNHARD DR
IPC: B01J21/16 , B01J31/14 , C07B61/00 , C07C2/30 , C07C29/141 , C07C29/16 , C07C31/125 , C07C67/08 , C07C69/80
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Patent Agency Ranking
公开(公告)号：DE3660488D1
公开(公告)日：1988-09-15
申请号：DE3660488
申请日：1986-11-27
Applicant: BASF AG
Inventor： GRENACHER ARMIN VOLKER DR , STROHMEYER MAX DR , HOFFMANN HERWIG DR , ELLIEHAUSEN HEINRICH DR
IPC: C07B61/00 , B01J23/00 , B01J23/88 , C07C27/00 , C07C29/14 , C07C29/141 , C07C31/02 , C07C31/125 , C07C67/00
Abstract: Preparation of C3- to C25-alkanols by catalytic hydrogenation of corresponding crude C3- to C25-alkanols, as obtained in the cobalt-catalyzed hydroformylation of C2- to C24-olefins, by partial 80-95% hydrogenation conversion in a first stage using a silica supported nickel and molybdenum oxide catalyst and then completing the conversion in a second stage using a cobalt catalyst containing copper, manganese, molybdenum and,optionally other activating additives. The process is especially adapted to the economic preparation of C9-C11- and C13-C15-alkanols which are used to prepare high-grade plasticizer esters.
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公开(公告)号：AT36310T
公开(公告)日：1988-08-15
申请号：AT86116461
申请日：1986-11-27
Applicant: BASF AG
Inventor： GRENACHER ARMIN VOLKER DR , STROHMEYER MAX DR , HOFFMANN HERWIG DR , ELLIEHAUSEN HEINRICH DR
IPC: C07B61/00 , B01J23/00 , B01J23/88 , C07C27/00 , C07C29/14 , C07C29/141 , C07C31/02 , C07C31/125 , C07C67/00
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公开(公告)号：DE3542595A1
公开(公告)日：1987-06-04
申请号：DE3542595
申请日：1985-12-03
Applicant: BASF AG
Inventor： GRENACHER ARMIN VOLKER DR , STROHMEYER MAX DR , HOFFMANN HERWIG DR , ELLIEHAUSEN HEINRICH DR
IPC: C07B61/00 , B01J23/00 , B01J23/88 , C07C27/00 , C07C29/14 , C07C29/141 , C07C31/02 , C07C31/125 , C07C67/00 , B01J23/85 , B01J23/68
Abstract: Preparation of C3- to C25-alkanols by catalytic hydrogenation of corresponding crude C3- to C25-alkanols, as obtained in the cobalt-catalyzed hydroformylation of C2- to C24-olefins, by partial 80-95% hydrogenation conversion in a first stage using a silica supported nickel and molybdenum oxide catalyst and then completing the conversion in a second stage using a cobalt catalyst containing copper, manganese, molybdenum and,optionally other activating additives. The process is especially adapted to the economic preparation of C9-C11- and C13-C15-alkanols which are used to prepare high-grade plasticizer esters.
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公开(公告)号：DE2962305D1
公开(公告)日：1982-04-29
申请号：DE2962305
申请日：1979-01-15
Applicant: BASF AG
Inventor： BRUNNER ERWIN DR , SCHUBERT ECKART DR , LINDNER ALFRED DR , MERGER FRANZ DR , VOLKAMER KLAUS DR , STROHMEYER MAX DR , SANDROCK GERHARD DR
Abstract: A process for obtaining isobutene from a C4-hydrocarbon mixture containing isobutene, by reacting the mixture with a primary alcohol in the presence of an acid condensing agent and decomposing the resulting tertiary ether in the presence of an acid catalyst at an elevated temperature, wherein a primary C3- or C4-alcohol is used.
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公开(公告)号：DE4205932A1
公开(公告)日：1993-09-02
申请号：DE4205932
申请日：1992-02-27
Applicant: BASF AG
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