公开(公告)号：DE50304518D1

公开(公告)日：2006-09-14

申请号：DE50304518

申请日：2003-12-03

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  HAUNERT ANDREA ,  ROEPER MICHAEL ,  SIRCH TILMAN ,  STUEER WOLFRAM

IPC: C07C29/17 ,  C07C29/149 ,  C07C31/20 ,  C07C67/347 ,  C07C69/593

Abstract: Production of 1,6-hexanediol of purity at least 99.5 % comprises: (1) catalytically dimerizing a 1-8C acrylic acid ester in presence of rhodium compounds to a mixture mainly of 2- and 3-hexenedioic acid diesters; (2) hydrogenating the ester mixture in chromium-free mainly copper-containing catalysts; and (3) purifying the resulting diol mixture by fractional distillation.

公开(公告)号：DE10328715A1

公开(公告)日：2005-01-13

申请号：DE10328715

申请日：2003-06-25

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  VOS HARTWIG ,  BASLER PETER ,  ROEPER MICHAEL

IPC: C07C51/353 ,  C07C51/36 ,  C07C51/47 ,  C07C67/303 ,  C07C67/347 ,  C07C67/56 ,  C07B41/00 ,  C07B41/08 ,  C07B41/12 ,  C07B43/06 ,  C07B43/08 ,  C07F15/00 ,  B01J31/12 ,  B01D61/00 ,  B01D3/00 ,  C07B35/02 ,  B01D71/02 ,  B01D71/06

Abstract: A process for continuously preparing a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group.

公开(公告)号：CA2523013A1

公开(公告)日：2004-11-04

申请号：CA2523013

申请日：2004-04-21

Applicant: BASF AG

Inventor： BASSLER PETER ,  ROEPER MICHAEL ,  SCHEIDEL JENS ,  STUEER WOLFRAM

IPC: C07C67/303 ,  C07C67/343 ,  C07C69/44

Abstract: Disclosed is a method for hydrating a monoolefinically unsaturated compound carrying at least two functional groups that are independently selected amon g a nitrile group, carboxylic acid group, carboxylic acid ester group, and carboxylic acid amide group, to a saturated compound carrying the same at least two functional groups in the presence of a rhodium-containing compound which acts as a catalyst and is homogeneous regarding the reaction mixture.

公开(公告)号：CA2419368A1

公开(公告)日：2003-02-10

申请号：CA2419368

申请日：2001-08-10

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  JUNG STEFAN ,  KARL JORN ,  ROPER MICHAEL ,  WERNER HELMUT ,  WOLF JUSTIN

IPC: B01J31/22 ,  C07B61/00 ,  C07C211/09 ,  C07C217/08 ,  C07C323/25 ,  C07F5/02 ,  C07F9/50 ,  C07F9/54 ,  C07F15/00 ,  C07F17/00 ,  C07F17/02

Abstract: In ruthenium complexes of general formula A or B, X1, X2 independently represent single or multidentate anionic ligands; R, R', R'' independently represent hydrogen or optionally substituted C1-20-alkyl, C6-20-aryl or C7-2 0- alkylaryl radicals; and L1, L2 independently represent neutral electron dono r ligands which are co-ordinated at the metallic centre as carboids, and which can be linked by a bridge W having 0 to 20 carbon atoms. Said bridge can be a constituent of a cyclic or aromatic group and can be split by heteroatoms, with the exception of C,N-heterocyclic five-membered ring systems.

公开(公告)号：AU8767701A

公开(公告)日：2002-02-25

申请号：AU8767701

申请日：2001-08-10

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  KARL JORN ,  ROPER MICHAEL ,  JUNG STEFAN ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: B01J31/22 ,  C07B61/00 ,  C07C211/09 ,  C07C217/08 ,  C07C323/25 ,  C07F5/02 ,  C07F9/50 ,  C07F9/54 ,  C07F15/00 ,  C07F17/00 ,  C07F17/02

Abstract: In the ruthenium complexes of the general formula A or B, X 1 >and X 2>, independently of one another, are monodentate or polydentate anionic ligands, R, R' and R'', independently of one another, are hydrogen or substituted or unsubstituted C 1-20 -alkyl, C 6-20 -aryl or C 7-20 -alkylaryl radicals, and L 1 >and L 2>, independently of one another, are neutral electron donor ligands which are coordinated as carbenoids to the metal center and may be linked via a bridge W having 0 to 20 carbon atoms, which may be part of a cyclic or aromatic group and may be interrupted by heteroatoms, with the exception of C,N-heterocyclic five-membered ring systems.

公开(公告)号：NO331010B1

公开(公告)日：2011-09-05

申请号：NO20051652

申请日：2005-04-04

Applicant: BASF AG

Inventor： MACHHAMMER OTTO ,  PASTRE JORG ,  STUEER WOLFRAM ,  EXNER KAI MICHAEL ,  GEISSLER ELKE

IPC: C07C51/54 ,  C07C51/09 ,  C07C51/56

Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).

公开(公告)号：BRPI0411733A

公开(公告)日：2006-08-08

申请号：BRPI0411733

申请日：2004-06-11

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  VOSS HARTWIG ,  BASSLER PETER ,  PER MICHAEL R

IPC: C07C51/353 ,  C07C51/36 ,  C07C51/47 ,  C07C67/303 ,  C07C67/347 ,  C07C67/56 ,  C07C69/593

Abstract: A process for continuously preparing a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group.

公开(公告)号：NO20051652L

公开(公告)日：2005-05-25

申请号：NO20051652

申请日：2005-04-04

Applicant: BASF AG

Inventor： MACHHAMMER OTTO ,  PASTRE JORG ,  STUEER WOLFRAM ,  EXNER KAI MICHAEL ,  GEISSLER ELKE

IPC: C07C51/09 ,  C07C51/54 ,  C07C51/56 ,  C07C67/10

Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).

公开(公告)号：DE10328714A1

公开(公告)日：2005-01-13

申请号：DE10328714

申请日：2003-06-25

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  BASLER PETER ,  ROEPER MICHAEL

IPC: C07C51/44 ,  C07C67/54 ,  C07C231/24 ,  C07C253/32 ,  C07B63/00 ,  C07C253/34 ,  C07C255/07 ,  C07C255/03 ,  C07C255/04 ,  C07C67/48 ,  C07C69/44 ,  C07B37/02 ,  C07B35/02

Abstract: A process for removing a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group, from a mixture which comprises a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group, and a compound which is homogeneous with respect to the mixture and contains rhodium, by distillation.

公开(公告)号：DE10318697A1

公开(公告)日：2004-11-25

申请号：DE10318697

申请日：2003-04-24

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  BASLER PETER ,  ROEPER MICHAEL

IPC: C07C67/303 ,  C07C67/343 ,  C07B35/02 ,  C07C69/44 ,  C07C253/30 ,  C07C255/04 ,  C07C255/19

Abstract: A process for hydrogenating a monoolefinically unsaturated compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group, carboxamide group to a saturated compound which bears the same at least two functional groups, in the presence of a rhodium-containing compound, as a catalyst, which is homogeneous with respect to the reaction mixture.