REMOCION DE UN CATALIZADOR HOMOGENEO QUE CONTIENE RODIO.

    公开(公告)号:MXPA05013608A

    公开(公告)日:2006-03-10

    申请号:MXPA05013608

    申请日:2004-06-19

    Applicant: BASF AG

    Inventor: STUER WOLFRAM

    Abstract: Un proceso para remover un compuesto que contiene cuando menos dos grupos funcionales que se seleccionan cada uno independientemente del grupo que consiste en grupo nitrilo, grupo de acido carboxilico, grupo de ester carboxilico y grupo carboxamida, de una mezcla que comprende un compuesto que contiene cuando menos dos grupos funcionales que se seleccionan cada uno independientemente a partir del grupo que consiste en grupo nitrilo, grupo de acido carboxilico, grupo de ester carboxilico, y grupo carboxamida, y un compuesto que es homogeneo con respecto a la mezcla y contiene rodio, mediante destilacion.

    METHOD FOR SEPARATING A HOMOGENEOUS CATALYST

    公开(公告)号:CA2528895A1

    公开(公告)日:2004-12-29

    申请号:CA2528895

    申请日:2004-06-11

    Applicant: BASF AG

    Abstract: The invention relates to a method for separating a mixture containing a) a monoethylenically unsaturated compound that can be obtained by adding two terminal olefins carrying the functional groups necessary for producing the monoethylenically unsaturated compound containing at least two functional groups, or a saturated compound obtained by hydrogenating one such compound, b) a compound that can be obtained by adding more than two of the terminal olefins cited in a) or a compound obtained by hydrating one such compound, a nd c) a compound which contains a transition metal, is homogeneous in relation to the mixture, and is suitable as a catalyst for producing a monoethylenically unsaturated compound by adding two terminal olefins carrying the functional groups necessary for producing the monoethylenically unsaturated compound containing at least two functional groups. According to said method, the mixture is separated by means of a semi-permeable membrane, obtaining a permeate and a retentate, in such a way that the weight ratio of constituent b) to constituent c) in the mixture supplied to the semi-permeable membrane is smaller than in the retentate.

    16.
    发明专利
    未知

    公开(公告)号:DE59802654D1

    公开(公告)日:2002-02-21

    申请号:DE59802654

    申请日:1998-08-20

    Applicant: BASF AG

    Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

    17.
    发明专利
    未知

    公开(公告)号:ID24110A

    公开(公告)日:2000-07-06

    申请号:ID20000268

    申请日:1998-08-20

    Applicant: BASF AG

    Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

    REMOCION DE UN CATALIZADOR HOMOGENEO.

    公开(公告)号:MXPA05013611A

    公开(公告)日:2006-03-10

    申请号:MXPA05013611

    申请日:2004-06-11

    Applicant: BASF AG

    Inventor: STUER WOLFRAM

    Abstract: Un proceso para separar una mezcla que comprende a) un compuesto monoolefinicamente insaturado que se puede obtener anadiendo dos olefinas terminales que llevan los grupos funcionales requeridos para preparar el compuesto monoolefinicamente insaturado que contiene cuando menos dos grupos funcionales, o un compuesto saturado obtenido mediante hidrogenacion de dicho compuesto, b) un compuesto que se obtiene anadiendo mas de dos de las olefinas terminales mencionadas en a) o un compuesto obtenido hidrogenando dicho compuesto, y c) un compuesto que contiene un metal de transicion, es homogeneo con respecto a la mezcla y es apropiado como un catalizador para preparar un compuesto monoolefinicamente insaturado anadiendo dos olefinas terminales que llevan los grupos funcionales requeridos para preparar el compuesto monoolefinicamente insaturado que contiene cuando menos dos grupos funcionales por medio de una membrana semipermeable para obtener un permeado y un retentado de tal manera que la relacion en peso del componente b) al componente c) en la mezcla alimentada a la membrana semipermeable es menor que en el retentado.

    19.
    发明专利
    未知

    公开(公告)号:BR0315375A

    公开(公告)日:2005-08-23

    申请号:BR0315375

    申请日:2003-10-21

    Applicant: BASF AG

    Abstract: Disclosed is a method for jointly producing (i) formic acid (III); (ii) a carboxylic acid comprising at least two carbon atoms (II) and/or the derivatives thereof; and (iii) a carboxylic acid anhydride (VII). According to said method, (a) a formic acid ester (I) is transesterfied to formic acid (III) and the corresponding carboxylic acid ester (IV) by means of a carboxylic acid comprising at least two carbon atoms (II); (b) at least one portion of the carboxylic acid ester (IV) formed in step (a) is carbonylated in order to obtain the carboxylic acid anhydride (V); and (c) at least one portion of the carboxylic acid anhydride (V) formed in step (b) is further dehydrated by means of a carboxylic acid (VI) so as to form a carboxylic acid anhydride (VII) and the carboxylic acid (II).

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