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    MIXTURE OF ADIPIC OR PHTHALIC ACID DIESTERS AND ISOMERIC NONANOLS
    12.
    发明专利
    MIXTURE OF ADIPIC OR PHTHALIC ACID DIESTERS AND ISOMERIC NONANOLS 未知

    公开(公告)号：CA2367358A1

    公开(公告)日：2000-10-26

    申请号：CA2367358

    申请日：1999-11-26

    Applicant: BASF AG

    Inventor： DORNIK KNUT ,  MORSBACH BERND ,  THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  WALTER MARC ,  ZELLER EDGAR ,  DISTELDORF WALTER

    IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

    Abstract: The invention relates to a mixture of diesters of a dicarboxylic acid and isomeric nonanols. Said mixture is selected among a mixture of adipic acid diesters in whose 1H-NMR spectrum, obtained in CDCl3, the ratio of the surfa ce area below the resonance signals in case of chemical shifts of between 1.0 a nd 2.0 ppm towards TMS to the surface area below the resonance signals in case of chemical shifts of between 0.5 and 1.0 ppm towards TMS is between 1.20 and 5.00. Alternatively said mixture is selected among a mixture of phthalic aci d diesters in whose 1H-NMR spectrum, obtained in CDCl3, the ratio of the surfa ce area below the resonance signals in case of chemical shifts of between 1.1 a nd 3.0 ppm towards TMS to the surface area below the resonance signals in case of chemical shifts of between 0.5 and 1.1 ppm towards TMS is between 1.00 and 4.00. The above adipic and phthalic acid diesters are suitable for use as softeners for moulding materials on a PVC basis and characterized by high compatibility, low brittleness temperature, low stiffness in torsion and/or high thermal stability.

    MIXTURE OF ADIPIC OR PHTHALIC ACID DIESTERS AND ISOMERIC NONANOLS
    13.
    发明专利
    MIXTURE OF ADIPIC OR PHTHALIC ACID DIESTERS AND ISOMERIC NONANOLS 未知

    公开(公告)号：CA2367358C

    公开(公告)日：2010-02-02

    申请号：CA2367358

    申请日：1999-11-26

    Applicant: BASF AG

    Inventor： WALTER MARC ,  MORSBACH BERND ,  ZELLER EDGAR ,  THIL LUCIEN ,  DORNIK KNUT ,  DISTELDORF WALTER ,  BREITSCHEIDEL BORIS

    IPC: C07C69/44 ,  C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

    Abstract: The invention relates to a mixture of diesters of a dicarboxylic acid and isomeric nonanols. Said mixture is selected among a mixture of adipic acid diesters in whose 1H-NMR spectrum, obtained in CDCl3, the rat io of the surface area below the resonance signals in case of chemical shifts of between 1.0 and 2.0 ppm towards TMS to the surface are a below the resonance signals in case of chemical shifts of between 0.5 and 1.0 ppm towards TMS is between 1.20 and 5.00. Alternatively said mixture is selected among a mixture of phthalic acid diesters in whose 1H-NMR spectrum, obtained in CDCl3, the ratio of the surfa ce area below the resonance signals in case of chemical shifts of between 1.1 and 3.0 ppm towards TMS to the surface area below the resonan ce signals in case of chemical shifts of between 0.5 and 1.1 ppm towards TMS is between 1.00 and 4.00. The above adipic and phthalic acid diesters are suitable for use as softeners for moulding materials on a PVC basis and characterized by high compatibility, low brittleness temperature, low stiffness in torsion and/or high thermal stability.

    METHOD FOR THE PRODUCTION OF ALDEHYDES
    15.
    发明专利
    METHOD FOR THE PRODUCTION OF ALDEHYDES 未知

    公开(公告)号：MY118644A

    公开(公告)日：2004-12-31

    申请号：MYPI9900188

    申请日：1999-01-16

    Applicant: BASF AG

    Inventor： GEIBLER BERNHARD ,  ROPER MICHAEL ,  ZELLER EDGAR ,  PACIELLO ROCCO ,  DECKER JURGEN ,  VOB HARTWIG ,  MAHR NORBERT

    IPC: B01J31/22 ,  C07C45/50 ,  B01J31/16 ,  B01J31/18 ,  B01J31/20 ,  C07B61/00 ,  C07C27/20 ,  C07C29/16 ,  C07C31/125 ,  C07C47/02 ,  C08G73/02

    Abstract: IN A PROCESS FOR PREPARING ALDEHYDES OR ALDEHYDES AND ALCOHOLS BY HYDROFORMYLATION OF OLEFINS IN THE PRESENCE OF A CATALYST COMPLEX WHICH IS HOMOGENEOUSLY DISSOLVED IN THE REACTION MIXTURE AND COMPRISES A METAL OF GROUP VIIIA OF THE PERIODIC TABLEE OF THE ELEMENTS AND AS LIGAND A PHOSPHORUS-FREE, POLYDENTATE NITROGEN COMPOUND CAPABLE OF COMPLEX FORMATION, AT FROM 50 TO 100oC AND PRESSURES OF FROM 20 TO 1000 BAR, AND RECYCLING OF THE CATALYSTCOMPLEX TO THE HYDROFORMYLATION REACTION, A ) THE LIGANDS USED ARE MODIFIED POLYAMINES WHICH ARE ESSENTIALLY INSOLUBLE IN WATER, ARE CAPABLE OF COMPLEX FORMATION, HAVE A MEAN MOLECULAR WEIGHT OF GREATER THAN 1000 DALTON AND CONTAIN AT LEAST 10 NITROGEN ATOMS, B ) AFTER THE HYDROFORMYLATION REACTION IS COMPLETE AND THE ALDEHYDES AND ALCOHOLS HAVE BEEN SEPARATED OR PARTIALLY SEPARATED FROM THE REACTION MIXTURE BY DISTILLATION, THE CATALYST COMPLEX AND EXCESS LIGAND REMAINING IN THE DISTILLATION BOTTOMS ARE COMPLETELY OR PARTIALLY RECYCLED TO THE HYDROFORMYLATION AND C ) AT LEAST PART OF THE HIGH BOILERS ARE BLED OFF, CONTINUOUSLY OR AT LEAST BATCHWISE, FROM THE BOTTOMS FROM THE DISTILLATION OF THE REACTION MIXTURE.

    16.
    发明专利
    未知

    公开(公告)号：DE59908919D1

    公开(公告)日：2004-04-22

    申请号：DE59908919

    申请日：1999-11-26

    Applicant: BASF AG

    Inventor： THIL LUCIEN ,  BREITSCHEIDEL BORIS ,  DISTELDORF WALTER ,  ZELLER EDGAR ,  WALTER MARC ,  MORSBACH BERND ,  DORNIK KNUT

    IPC: C07B61/00 ,  C07C29/14 ,  C07C31/125 ,  C07C67/08 ,  C07C69/44 ,  C07C69/80 ,  C08K5/05 ,  C08K5/10 ,  C08K5/11 ,  C08K5/12 ,  C08L27/06

    Abstract: The mixture described is a mixture of isomeric nonanol diesters of a dicarboxylic acid, selected from the class consisting of a mixture of diesters of adipic acid in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.0 to 2.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.0 ppm with respect to TMS is from 1.20 to 5.00 and a mixture of diesters of phthalic acid, in the 1H NMR spectrum of which, observed in CDCl3, the ratio of the area under the resonance signals at chemical shifts in the range from 1.1 to 3.0 ppm with respect to TMS to the area under the resonance signals at chemical shifts in the range from 0.5 to 1.1 ppm with respect to TMS is from 1.00 to 4.00.The diesters of adipic and phthalic acid are suitable as plasticizers for PVC-based molding compositions and have high compatibility, a low cold crack temperature, low torsional rigidity and/or high thermal stability.

    19.
    发明专利
    未知

    公开(公告)号：BR9815077A

    公开(公告)日：2000-10-03

    申请号：BR9815077

    申请日：1998-11-30

    Applicant: BASF AG

    Inventor： LEUBE HARTMANN F ,  SCHMIDT-THUEMMES JUERGEN ,  ZELLER EDGAR ,  MAAS HEIKO

    IPC: C08C19/02 ,  C08F8/04

    Abstract: A process for selectively hydrogenating ethylenically unsaturated double bonds in polymers P involves reacting the polymers P with hydrogen in the presence of at least one hydrogenation catalyst selected from the salts and complex compounds of rhodium and/or of ruthenium in an aqueous dispersion of the polymers P that comprises not more than 20% by volume of an organic solvent. This process can be used to give hydrogenated polymer dispersions and, from these dispersions, polymers. Also claimed are aqueous polymer dispersions comprising polymers P', which include structural units I, II and III as in claim 10, with or without structural units IV and/or V as in claim 11.

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