公开(公告)号：DE4143085C2

公开(公告)日：2000-07-06

申请号：DE4143085

申请日：1991-12-27

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  HASHIBA KUNIZO ,  KAWAKAMI TAKAHIRO

IPC: B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C29/17 ,  C07C31/02 ,  C07C31/125

Abstract: A process for producing an alcohol by continuously passing a fatty acid ester, a fatty acid triglyceride or a fatty acid through a hydrogenation catalyst to thereby produce the aimed alcohol through catalytic reduction is disclosed, wherein the employed reactor is a fixed bed reactor in which the liquid phase and the gas phase are continuously passed together in descending parallel flows through the hydrogenation catalyst fixed in the reactor; and at least one cooling mean for cooling the reaction system is provided at a position in the vertical direction of the reactor. According to the process of the present invention with the use of a fixed bed reactor, an alcohol, which has extremely high qualities and a high purity and is contaminated with little hydrocarbon and aldehyde by-products, can be produced. The process of the present invention further makes it possible to omit the post-treatment for eliminating the by-products.

公开(公告)号：DE69014040D1

公开(公告)日：1994-12-15

申请号：DE69014040

申请日：1990-03-30

Applicant: KAO CORP

Inventor： FUJITA TADAAKI ,  AIMONO KIYOSHI ,  HASHIBA KUNIZO ,  OHORI KOICHI

IPC: C07H1/06 ,  C07H15/04

Abstract: A process for the production of an alkyl glycoside or an aqueous solution thereof is disclosed, comprising the steps of (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing unreacted alcohol, (2) establishing a moving liquid film of the alkyl glycoside reaction product and (3) contacting the moving liquid film with steam or an inert gas at a temperature of from 50 to 200 DEG C. The alkyl glycoside or aqueous solution thus obtained contains little unreacted alcohol and is excellent in hue and odor.

公开(公告)号：DE4143085A1

公开(公告)日：1992-07-30

申请号：DE4143085

申请日：1991-12-27

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  HASHIBA KUNIZO ,  KAWAKAMI TAKAHIRO

IPC: B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C29/17 ,  C07C31/02 ,  C07C31/125

Abstract: A process for producing an alcohol by continuously passing a fatty acid ester, a fatty acid triglyceride or a fatty acid through a hydrogenation catalyst to thereby produce the aimed alcohol through catalytic reduction is disclosed, wherein the employed reactor is a fixed bed reactor in which the liquid phase and the gas phase are continuously passed together in descending parallel flows through the hydrogenation catalyst fixed in the reactor; and at least one cooling mean for cooling the reaction system is provided at a position in the vertical direction of the reactor. According to the process of the present invention with the use of a fixed bed reactor, an alcohol, which has extremely high qualities and a high purity and is contaminated with little hydrocarbon and aldehyde by-products, can be produced. The process of the present invention further makes it possible to omit the post-treatment for eliminating the by-products.

公开(公告)号：GB2164663B

公开(公告)日：1987-12-09

申请号：GB8523279

申请日：1985-09-20

Applicant: KAO CORP

Inventor： TANIGAKI MASANOBU ,  HASHIBA KUNIZO ,  WADA HIDETOSHI ,  SAKATA MASARU

IPC: C12Q1/00 ,  C12M1/00 ,  C12M1/12 ,  C12M1/40 ,  C12P1/00 ,  C12P7/20 ,  C12P7/64

公开(公告)号：GB2164663A

公开(公告)日：1986-03-26

申请号：GB8523279

申请日：1985-09-20

Applicant: KAO CORP

Inventor： TANIGAKI MASANOBU ,  HASHIBA KUNIZO ,  WADA HIDETOSHI ,  SAKATA MASARU

IPC: C12Q1/00 ,  C12M1/00 ,  C12M1/12 ,  C12M1/40 ,  C12P1/00 ,  C12P7/20 ,  C12P7/64

Abstract: An enzymatic or microbial reaction is conducted between at least two reactants by placing an enzyme, a microbe, an immobilized enzyme or an immobilized microbe in an inner space provided between two sheets of porous materials which do not allow the enzyme and the microbe to pass, placing the reactants in the two outer spaces provided outside the two sheets, respectively, allowing each of the reactants to pass through one sheet to conduct the enzymatic or microbial reaction in the inner space and allowing each product to pass outwardly through one sheet.

公开(公告)号：DE2800384A1

公开(公告)日：1978-07-27

申请号：DE2800384

申请日：1978-01-05

Applicant: KAO CORP

Inventor： MIYA BUNJI ,  SAWAMOTO YUZI ,  HASHIBA KUNIZO ,  HISAMITSU SHIZUO

IPC: C07D307/46 ,  B01J23/745 ,  B01J37/03 ,  C07B61/00 ,  C07C27/00 ,  C07C29/136 ,  C07C29/149 ,  C07C67/00 ,  B01J23/74

Abstract: Copper-iron-aluminum catalysts are prepared by dissolving a cupric salt, a ferrous salt and an aluminum salt in water, adding an alkali to the solution at a temperature higher than 60 DEG C. whereby to form a precipitate, separating the precipitate and water-washing, drying, calcining and pulverizing the separated precipitate.

公开(公告)号：DE4207787C2

公开(公告)日：2002-10-24

申请号：DE4207787

申请日：1992-03-11

Applicant: KAO CORP

Inventor： TAMURA HIROYUKI ,  HATTORI YASUYUKI ,  HASHIBA KUNIZO ,  TABATA OSAMU ,  TSUKADA KIYOSHI ,  FUKUOKA NORIAKI

IPC: C07C29/149 ,  C11B3/02 ,  B01J23/80 ,  B01J23/70 ,  C07C31/125 ,  C07C33/02

Abstract: A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm2 in the absolute pressure at a temperature of from 100 DEG to 350 DEG C. in the presence of a catalyst of the following formula (I): CuxXxxYyxOz(I) wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

公开(公告)号：DE4143091C2

公开(公告)日：2000-07-06

申请号：DE4143091

申请日：1991-12-27

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  MORI ATSUHITO ,  KAWAKAMI TAKAHIRO ,  HASHIBA KUNIZO ,  TSUKADA KIYOSHI

IPC: C07C29/149 ,  C07C29/17 ,  C07C31/02

Abstract: A process for producing an alcohol from a fatty acid ester, a fatty acid triglyceride or a fatty acid by continuously catalytically reducing the starting material in the presence of a hydrogenation catalyst is disclosed. In the process of the present invention, two reactors (i.e., the main reactor located upstream and the after reactor located downstream) being located in series are employed. In the process of the present invention, two reactors are employed and the temperatures thereof are individually controlled, whereby the conversion ratio is elevated while suppressing the formation of hydrocarbon and aldehyde by-products. Thus, an alcohol of extremely high quality and high purity can be produced. Further, the process of the present invention makes it possible to omit any post-treatment for eliminating the by-products. Furthermore, the active life of the hydrogenation catalyst can be remarkably prolonged by using three reactors (i.e., the guard reactor, the main reactor and the after reactor).

公开(公告)号：ID942B

公开(公告)日：1996-09-19

申请号：ID911277

申请日：1991-12-27

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  HASHIBA KUNIZO ,  KAWAKAMI TAKAHIRO

IPC: C07B61/00 ,  C07C29/149 ,  B01J23/86 ,  C07C29/17 ,  C07C31/02 ,  C07C31/125

Abstract: A process for producing an alcohol by continuously passing a fatty acid ester, a fatty acid triglyceride or a fatty acid through a hydrogenation catalyst to thereby produce the aimed alcohol through catalytic reduction is disclosed, wherein the employed reactor is a fixed bed reactor in which the liquid phase and the gas phase are continuously passed together in descending parallel flows through the hydrogenation catalyst fixed in the reactor; and at least one cooling mean for cooling the reaction system is provided at a position in the vertical direction of the reactor. According to the process of the present invention with the use of a fixed bed reactor, an alcohol, which has extremely high qualities and a high purity and is contaminated with little hydrocarbon and aldehyde by-products, can be produced. The process of the present invention further makes it possible to omit the post-treatment for eliminating the by-products.

公开(公告)号：DE69014040T2

公开(公告)日：1995-04-27

申请号：DE69014040

申请日：1990-03-30

Applicant: KAO CORP

Inventor： FUJITA TADAAKI ,  AIMONO KIYOSHI ,  HASHIBA KUNIZO ,  OHORI KOICHI

IPC: C07H1/06 ,  C07H15/04

Abstract: A process for the production of an alkyl glycoside or an aqueous solution thereof is disclosed, comprising the steps of (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing unreacted alcohol, (2) establishing a moving liquid film of the alkyl glycoside reaction product and (3) contacting the moving liquid film with steam or an inert gas at a temperature of from 50 to 200 DEG C. The alkyl glycoside or aqueous solution thus obtained contains little unreacted alcohol and is excellent in hue and odor.