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    NEW TRANSITION METALLIC COMPOUND AND CATALYST FOR POLYMERIZING OLEFIN COMPRISING THE SAME TRANSITION METALLIC COMPOUND
    14.
    发明专利
    NEW TRANSITION METALLIC COMPOUND AND CATALYST FOR POLYMERIZING OLEFIN COMPRISING THE SAME TRANSITION METALLIC COMPOUND 失效

    公开(公告)号：JPH08325283A

    公开(公告)日：1996-12-10

    申请号：JP13186695

    申请日：1995-05-30

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： KAWAI KOJI ,  KITAHARA TAKUMI ,  FUJITA TERUNORI

    IPC: C07F17/00 ,  C08F4/60 ,  C08F4/642 ,  C08F4/6592 ,  C08F10/00

    Abstract: PURPOSE: To obtain the subject new compound, comprising a transition metallic complex having a specific o-indenylphenol derivative, etc., as a ligand, useful as a catalyst component for polymerizing an olefin and capable of providing a high-molecular weight polymer having a narrow distribution of molecular weight and composition and a high-molecular weight. CONSTITUTION: The new transition metallic compound of formula I [M is a group IVb, Vb or VIb transition metallic atom of the periodic table; R to R are each H, a halogen or a (halogenated) 1-20C hydrocarbon; R to R are each capable of binding two mutually adjacent groups and, together with the bound C atoms, may form an aromatic or an alicyclic ring; R to R are each the same species as that of R to R ; X and X are each H, a halogen, a (halogenated) 1-20C hydrocarbon or a group containing oxygen or sulfur; Q is O or SNR (R is H or a l-20C hydrocarbon), etc.]. The compound is useful as a component of a catalyst for polymerizing an olefin. This compound is obtained by deprotecting an o-indenylphenol derivative of formula II (R* is a protecting group of Q) with butyllithium and then forming a complex with a transition metallic compound such as ZrCl4 .

    COLOR DEVELOPING RECORDING MATERIAL
    17.
    发明专利
    COLOR DEVELOPING RECORDING MATERIAL 失效

    公开(公告)号：JPH06312574A

    公开(公告)日：1994-11-08

    申请号：JP10331993

    申请日：1993-04-28

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： FUJITA TERUNORI ,  NITAHARA MASATOSHI ,  KAWAI KOJI ,  KISO YOSHIHISA

    IPC: B41M5/132 ,  B41M5/26 ,  B41M5/30 ,  B41M5/323

    Abstract: PURPOSE:To obtain a color developing recording material which has high whiteness of a skin, and high preservation stability such as moisture vapor resistance, light resistance, etc., of a color developer by incorporating quinone compound, amine compound represented by specific general formulae and acidic substance. CONSTITUTION:A color developing recording material such as heat-sensitive, pressure recording sheet, etc., useful for a record reader using a visible light and/or near infrared ray comprises three elements of quinone compound represented by a first general formula, amine compound represented by a second general formula, and acidic substance. In the first formula, A, B are hydrocarbon group, R -CO, R -O-CO-, R R N-CO-, and C, D are hydrogen, hydrocarbon group, halogen, R -CO-, R -COO-, R -O-CO-, etc. In the second formula, I, J are hydrogen or hydrocarbon group, K, L are hydrogen, hydrocarbon group, halogen, R -CO-, R -COO-, R -OCO-, etc.

    COLOR DEVELOPING RECORDING MATERIAL
    18.
    发明专利
    COLOR DEVELOPING RECORDING MATERIAL 失效

    公开(公告)号：JPH05221121A

    公开(公告)日：1993-08-31

    申请号：JP5658592

    申请日：1992-02-10

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： FUJITA TERUNORI ,  ISHIBASHI MASAYASU ,  MIKI HISAYA

    IPC: B41M5/136 ,  B41M5/30 ,  B41M5/323

    Abstract: PURPOSE:To enhance developed color intensity, to intensify absorption from a visible region to a near infrared region and to stably develop a color regardless of the change of acidity and basicity by adding an aromatic amine derivative represented by a predetermined general formula and an inorg. compd. having both of acid properties and oxidizing capacity. CONSTITUTION:An aromatic amine derivative represented by formula I (wherein R and R are a substituted or non-substituted aryl group, R and R are a hydrogen atom, a lower alkyl group or a substituted or non-substituted aryl group and X is a substituted or non-substituted arylene group), for example, N'-diphenyl-O-phenylenediamine and a heteropoly compd. as an inorg. compd having acid properties and oxidizing capacity or a metal salt thereof, for example, sodium phosphomolybdate are added to form a color forming recording material. By this constitution, the aromatic amine derivative can be efficiently converted to a color developing aluminum compd. and high absorption intensity and high fastness can be obtained within a range from a visible region to a near infrared region.

    COLOR DEVELOPING RECORDING MATERIAL
    19.
    发明专利
    COLOR DEVELOPING RECORDING MATERIAL 失效

    公开(公告)号：JPH0593982A

    公开(公告)日：1993-04-16

    申请号：JP27897191

    申请日：1991-10-01

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： KAWAI KOJI ,  NITAHARA MASATOSHI ,  KISHIKAWA YOSHIKI ,  KAWAMURA MASATO ,  FUJITA TERUNORI ,  MIKI HISAYA

    IPC: B41M5/323 ,  G03C1/675

    Abstract: PURPOSE:To obtain the color developing recording material capable of developing color in a practicablly sufficient intensity soon after color development operation and having absorption in a wide region from the visible region to a near infrared region in its color developing part by incorporating a specified compound, an oxidant, and an acidic material. CONSTITUTION:This recording material contains the compound of formula I, the oxidant, and the acidic material. In formula I, A is a univalent aromatic group; each of B and X is, an independently divalent aromatic group; Y is -O-, -NH-, -N (lower alkyl)-, -N(,aryl)-, or -N(aralkyl)=; Z is H, alkyl, aryl, aralkyl, alkoxy, aryloxy, aralkyloxy, alkylated amino, or arylated amino; each of R and R is, independently to each other, H, lower alkyl, aryl, or aralkyl. The oxidant is a quinoid type electron acceptor, and the acidic material is an aromatic carboxylic acid.

    PRODUCTION OF AROMATIC CARBONATE
    20.
    发明专利
    PRODUCTION OF AROMATIC CARBONATE 失效

    公开(公告)号：JPH0525095A

    公开(公告)日：1993-02-02

    申请号：JP20363691

    申请日：1991-07-19

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： FUJITA TERUNORI ,  KISO YOSHIHISA ,  NAGATA TAKUJI ,  IWASAKI HIROSHI

    IPC: B01J27/08 ,  B01J27/232 ,  B01J31/12 ,  C07B61/00 ,  C07C68/00 ,  C07C69/96

    Abstract: PURPOSE:To industrially and advantageously produce an aromatic carbonate in high selectivity. CONSTITUTION:A process for producing an aromatic carbonate which comprises thermally reacting with heating under pressure, an aromatic hydroxy compound with carbon monoxide and molecular oxygen in the presence of a catalyst comprising (a) at least one kind selected from the group consisting of palladium and palladium compounds; (b) at least one kind of cobalt compound; (c) at least one kind selected from the group consisting of organic halide compounds and inorganic halide compounds; and (d) a basic compound.

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