公开(公告)号：WO2014184138A1

公开(公告)日：2014-11-20

申请号：PCT/EP2014/059653

申请日：2014-05-12

Applicant: COMMISSARIAT À L'ÉNERGIE ATOMIQUE ET AUX ÉNERGIES ALTERNATIVES

Inventor： DELLEA, Olivier ,  CORONEL, Philippe ,  FUGIER, Pascal

IPC: B05D7/22 ,  B05D1/20

CPC classification number: B05C19/005 ,  B05C3/10 ,  B05C3/109 ,  B05C7/04 ,  B05C9/02 ,  B05C19/008 ,  B05D1/20 ,  B05D1/202 ,  B05D1/204 ,  B05D1/24 ,  B05D7/22 ,  B05D7/222 ,  B05D7/50

Abstract: L'invention concerne un procédé de dépôt d'un film compact de particules (4) sur la surface intérieure (10) d'une pièce (2), comprenant les étapes suivantes : a) placer la pièce (2) dans un liquide porteur (6); b) générer un flux de liquide porteur (44) dans le creux (8) de la pièce en direction de la surface (18) du liquide porteur, de manière à créer une protubérance (50); c) dispenser les particules (4) pour former un film compact flottant sur le liquide (6) entre une ligne de contact (20) et un front amont (60) de particules; et d) transférer du film (4) sur la surface intérieure (10) en opérant un déplacement relatif entre cette pièce (2) et la surface (18) du liquide porteur, tout en poursuivant la dispense des particules (4) sur le front amont (60).

Abstract translation: 本发明涉及一种在部分（2）的内表面（10）上沉积颗粒（4）的致密膜的方法，包括以下步骤：a）将部分（2）放置在载体液体（6）中， ; b）在所述载体液体的表面（18）的方向上产生载体液体（44）流入所述部分的所述中空部（8）中，以便产生突起（50）; c）分配颗粒（4）以形成漂浮在接触线（20）和颗粒的上游前部（6）之间的液体（6）上的致密膜; 以及d）通过在该部分（2）和载体液体的表面（18）之间进行相对位移，同时继续将颗粒（4）分配到上游前端（4）上，将膜（4）转移到内表面（10）上 （60）。

公开(公告)号：WO2006004952A1

公开(公告)日：2006-01-12

申请号：PCT/US2005/023322

申请日：2005-06-30

Applicant: HEWLETT-PACKARD DEVELOPMENT COMPANY L.P. ,  ZANG, Sean X ,  OHLBERG, Douglas A. ,  LI, Zhiyoung

Inventor： ZANG, Sean X ,  OHLBERG, Douglas A. ,  LI, Zhiyoung

IPC: B05D1/20

CPC classification number: B05D1/204 ,  B05D3/105 ,  B05D3/14 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00

Abstract: A molecule (18) for Langmuir-Blodgett (LB) deposition of a molecular layer. The molecule (18) includes at least one switching moiety (26), a hydrophilicity-modifiable connecting group (30) attached to one end of the moiety (26), and a hydrophilicity-non-modifiable connecting group (28) attached to the other end of the moiety (26). The hydrophilicity-modifiable connecting group (30) is transformable to a temporary end group (32) upon adjustment in pH of the aqueous environment containing the molecule (18). The temporary end group (32) is more hydrophilic than the hydrophilicity-modifiable connecting group (30) and the hydrophilicity-non-modifiable connecting group (28). The difference in hydrophilicity between the temporary end group (32) and the hydrophilicity-non-modifiable connecting group (28) causes formation of a substantially well-oriented, uniform LB film at a water/solvent and/or water/air interface (34).

Abstract translation: 用于Langmuir-Blodgett（LB）沉积分子层的分子（18）。 分子（18）包括至少一个切换部分（26），连接到部分（26）的一端的亲水性可修饰连接基团（30）和附着到部分（26）的亲水性不可修饰的连接基团（28） 部分（26）的另一端。 当调节包含分子（18）的水性环境的pH时，亲水性可连接基团（30）可转变成临时端基（32）。 临时端基（32）比亲水性可连接基团（30）和亲水不可连接基团（28）更亲水。 临时端基（32）和亲水不连接基团（28）之间的亲水性差异导致在水/溶剂和/或水/空气界面（34）处形成基本上良好取向的均匀的LB膜 ）。

公开(公告)号：US12042819B1

公开(公告)日：2024-07-23

申请号：US18328194

申请日：2023-06-02

Applicant: Board of Trustees of the University of Alabama, for and on behalf of the University of Alabama in Huntsville

Inventor： Jeffrey J. Weimer ,  Jimmie L. Mitchell

IPC: B05D7/24 ,  B05D1/20 ,  C09D5/22 ,  C09K11/08

CPC classification number: B05D1/204 ,  B05D7/24 ,  C09D5/22 ,  C09K11/08

Abstract: The present disclosure is directed to methods for preparing nanoparticle monolayers on a sub-phase by controlling the spreading rate of the nanoparticles. The nanoparticles are first prepared in a nanoparticle solution at a predetermined concentration with a solvent. The sub-phase solution is prepared to have a density and viscosity compatible with the desired spreading rate. Additives, such as glycerol, are used to alter the density of the sub-phase solution. A volume of nanoparticle solution is deposited on the surface of the sub-phase solution and allowed to spread in a controlled manner on the unconstrained surface, forming a uniform nanoparticle monolayer. A substrate is then placed in contact with the nanoparticle monolayer to form a uniform nanoparticle coating on the surface of the substrate.

公开(公告)号：US20190027697A1

公开(公告)日：2019-01-24

申请号：US16038231

申请日：2018-07-18

Applicant: Purdue Research Foundation

Inventor： Shelley A. Claridge ,  Tyler Hayes ,  David McMillan

IPC: H01L51/00 ,  B05D1/20

CPC classification number: H01L51/0075 ,  B05D1/204 ,  B05D1/208 ,  H01L51/0012 ,  H01L51/0026

Abstract: This invention generally relates to a method for preparing and transferring a monolayer or thin film. In particular this present invention is an improved version of the Langmuir-Schaefer technique for preparing and transferring a monolayer or thin film, incorporating in situ thermal control of the substrate during the transfer process.

公开(公告)号：US20180212148A1

公开(公告)日：2018-07-26

申请号：US15744137

申请日：2016-05-19

Applicant: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Jung Yong Lee ,  Seon Ju Jeong ,  Jong Hyeon Noh

IPC: H01L51/00 ,  H01L51/42 ,  H01L51/50 ,  H01L51/05 ,  H01L51/56

CPC classification number: H01L51/0003 ,  B05D1/204 ,  H01L51/003 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0075 ,  H01L51/0077 ,  H01L51/0096 ,  H01L51/0097 ,  H01L51/0545 ,  H01L51/0558 ,  H01L51/4213 ,  H01L51/4253 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5056 ,  H01L51/56 ,  H01L2031/0344 ,  H01L2251/5338 ,  Y02E10/549 ,  Y02P70/521

Abstract: According to the present invention, an ultra-fast method for preparing an organic/inorganic thin film by using self-diffusion effects comprises the steps of: forming a solution by dissolving one or more organic/inorganic materials in a solvent; forming an organic/inorganic thin film by supplying the formed solution onto a liquid substrate; and transferring the formed thin film to a substrate, wherein the step of forming an organic/inorganic thin film forms a thin film on the liquid substrate from the organic/inorganic materials through the occurrence of a self-diffusion phenomenon caused by a difference in surface tension between the liquid substrate and the solution, and through the occurrence of the evaporation of the solvent and the dissolution process of the solvent to the liquid substrate.

公开(公告)号：US20170050212A1

公开(公告)日：2017-02-23

申请号：US14634854

申请日：2015-03-01

Applicant: Weixing Lu ,  Allan Roberts

Inventor： Weixing Lu ,  Allan Roberts

IPC: B05D1/20 ,  B05D3/02 ,  B05D7/24 ,  B05D3/10 ,  B05D5/00 ,  B05D7/00

CPC classification number: B05D1/208 ,  B05D1/204 ,  B05D3/0254 ,  B05D3/104 ,  B05D3/108 ,  B05D5/00 ,  B05D5/08 ,  B05D7/24 ,  B05D7/54

Abstract: The field of the invention relates to systems and methods for surface treatments, and more particularly to systems and methods for surface treatments, modifications or coatings using micro- and nano-structure particles for both super-hydrophobic and super-oleophobic properties. In one embodiment, a method of treating surfaces to impart both super-hydrophobic and super-oleophobic properties includes the steps of pre-treating a substrate surface; assembling dual-scale nanoparticles onto the surface of the substrate; and treating the dual-scale nanoparticle coated surface with SiCl4 to cross-link the nanoparticles to each other and to the surface of the substrate creating a robust nano-structured topographic surface having both super-hydrophobic and super-oleophobic properties.

Abstract translation: 本发明的领域涉及用于表面处理的系统和方法，更具体地涉及使用用于超疏水和超疏油性质的微结构和纳米结构颗粒的表面处理，改性或涂层的系统和方法。 在一个实施方案中，处理表面以赋予超疏水性和超疏油性两者的方法包括预处理基材表面的步骤; 将双尺寸纳米颗粒组装到所述基底的表面上; 并且用SiCl 4处理双尺度纳米颗粒涂覆的表面以将纳米颗粒彼此交联并连接到衬底的表面，产生具有超疏水和超疏油性质的稳健的纳米结构形貌表面。

公开(公告)号：US20170021604A1

公开(公告)日：2017-01-26

申请号：US15285445

申请日：2016-10-04

Applicant: IMEC ,  St. Petersburg Electrotechnical University

Inventor： Victor Luchinin ,  Svetlana Goloudina ,  Vyacheslav Pasyuta ,  Alexey Ivanov ,  Mikhail Baklanov ,  Mikhail Krishtab

IPC: B32B37/15 ,  B05D1/20 ,  B32B27/28

CPC classification number: C08J5/18 ,  B05D1/20 ,  B05D1/204 ,  B05D1/208 ,  B05D2505/50 ,  B32B18/00 ,  B32B27/04 ,  B32B27/281 ,  B32B37/15 ,  B32B2260/046 ,  B32B2305/026 ,  B32B2305/07 ,  B32B2307/00 ,  B32B2307/204 ,  B32B2379/08 ,  B32B2457/00 ,  B82Y30/00 ,  B82Y40/00 ,  C08G73/1067 ,  C08J2379/08 ,  C08J2483/02 ,  C09D179/08 ,  H01L21/02285 ,  H01L21/02318 ,  H01L23/5329 ,  H05K1/03 ,  H05K3/143 ,  H05K2201/01 ,  H05K2201/0104 ,  H05K2201/0116 ,  H05K2201/0154 ,  H05K2201/0162 ,  Y10T428/249979 ,  Y10T428/249991 ,  C08K5/175

Abstract: Method for pore sealing a porous substrate, comprising: forming a continuous monolayer of a polyimide precursor on a liquid surface, transferring said polyimide precursor monolayer onto the porous substrate with the Langmuir-Blodgett technique, and imidization of the transferred polyimide precursor monolayers, thereby forming a polyimide sealing layer on the porous substrate. Porous substrate having at least one surface on which a sealing layer is provided to seal pores of the substrate, wherein the sealing layer is a polyimide having a thickness of a few monolayers and wherein there is no penetration of the polyimide into the pores.

Abstract translation: 用于孔密封多孔基材的方法，包括：在液体表面上形成聚酰亚胺前体的连续单层，使用Langmuir-Blodgett技术将所述聚酰亚胺前体单层转移到多孔基材上，并将转移的聚酰亚胺前体单层酰亚胺化，从而形成 多孔基材上的聚酰亚胺密封层。 具有至少一个表面的多孔基材，其上设有密封层以密封基材的孔，其中密封层是具有几个单层厚度的聚酰亚胺，并且其中聚酰亚胺不渗透到孔中。

公开(公告)号：US08911852B2

公开(公告)日：2014-12-16

申请号：US13063584

申请日：2009-09-10

Applicant: Armin Gölzhäuser ,  André Beyer ,  Adelheid Godt

Inventor： Armin Gölzhäuser ,  André Beyer ,  Adelheid Godt

IPC: B32B3/10 ,  G03F7/20 ,  B29C35/08 ,  B82Y40/00 ,  B05D1/20 ,  B05D1/18 ,  B82Y30/00 ,  B05D1/00 ,  B05D1/26 ,  B05D3/06

CPC classification number: B05D1/204 ,  B05D1/005 ,  B05D1/185 ,  B05D1/26 ,  B05D1/60 ,  B05D3/067 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/24802

Abstract: The present invention relates to a structured monolayer that is composed of low-molecular aromatics and fully cross-linked in the lateral direction, the monolayer having a pattern of functional groups on one of the two surfaces, and to a method for preparing such a structured monolayer, as well as to the use thereof.

Abstract translation: 本发明涉及一种结构单层，其由低分子芳族化合物构成并且在横向方向上完全交联，单层在两个表面之一上具有官能团的图案，以及制备这种结构化单体的方法 单层，以及其用途。

公开(公告)号：US5143828A

公开(公告)日：1992-09-01

申请号：US815213

申请日：1991-12-31

Applicant: Joseph A. Akkara ,  David L. Kaplan ,  Lynne A. Samuelson ,  Braja K. Mandal ,  Sukant K. Tripathy ,  Ferdinando F. Bruno ,  Kenneth A. Marx

Inventor： Joseph A. Akkara ,  David L. Kaplan ,  Lynne A. Samuelson ,  Braja K. Mandal ,  Sukant K. Tripathy ,  Ferdinando F. Bruno ,  Kenneth A. Marx

IPC: B05D1/20 ,  C08G61/10 ,  C08G73/02 ,  C12P7/22 ,  C12P13/00

CPC classification number: B82Y30/00 ,  B05D1/204 ,  B82Y40/00 ,  C08G61/10 ,  C08G73/0266 ,  C12P13/001 ,  C12P7/22

Abstract: A method for synthesizing enzyme-catalyzed polymers using the Langmuir-Blodgett technique. In one embodiment, the process comprises spreading one or more enzyme-polymerizable monomers on a water-miscible solvent. The monomers are sufficiently surface active that they align themselves on the air-solvent interface. Next, pressure is applied to the interface to form a monolayer made up of the monomers. An enzyme is then introduced into the solvent, causing polymerization of the monomers in the monolayer. The polymeric monolayers produced by the present method are easier to process and have reduced cross-linking and branching as compared to similar polymers produced in bulk by enzyme-catalyzed reactions.

Abstract translation: 使用Langmuir-Blodgett技术合成酶催化聚合物的方法。 在一个实施方案中，该方法包括将一种或多种可酶聚合的单体铺在水混溶性溶剂上。 单体具有足够的表面活性，使得它们自己在空气 - 溶剂界面上对准。 接下来，向界面施加压力以形成由单体组成的单层。 然后将酶引入溶剂中，引起单体在单层中的聚合。 通过本发明方法制备的聚合物单层与通过酶催化反应在本体产生的类似聚合物相比更容易加工并且具有减少的交联和支化。

公开(公告)号：EP2678120B1

公开(公告)日：2015-05-13

申请号：EP12704426.1

申请日：2012-02-20

Applicant: Commissariat à l'Énergie Atomique et aux Énergies Alternatives

Inventor： DELLEA, Olivier ,  FUGIER, Pascal ,  CORONEL, Philippe

IPC: B05D1/00 ,  B05D1/20

CPC classification number: B05C19/02 ,  B05C19/00 ,  B05D1/00 ,  B05D1/20 ,  B05D1/204 ,  B05D2252/02