公开(公告)号：SK72003A3

公开(公告)日：2003-07-01

申请号：SK72003

申请日：2001-07-04

Applicant: BASF AG

Inventor： LANGEMANN KLAUS ,  MISSLITZ ULF ,  BAUMANN ERNST ,  VON DEYN WOLFGANG ,  KUDIS STEFFEN ,  VOLK THORSTEN ,  MAYER GUIDO

IPC: C07C45/42 ,  C07B61/00 ,  C07C17/00 ,  C07C45/27 ,  C07C45/29 ,  C07C45/67 ,  C07C49/433 ,  C07C49/443 ,  C07C255/47

Abstract: A process for preparing bicyclic 1,3-diketones of the formula IwhereR , R , R and R are hydrogen, C1-C4-alkyl, C1-C4-alkoxy-carbonyl, halogen, cyano, nitro, C1-C4-alkylthio, C1-C4-alkylsulfenyl or C1-C4-alkylsulfonyl andZ is C1-C4-alkylene, O, S, N-R whereR is C1-C4-alkyl or C1-C4-alkylcarbonyl,which comprisesa) reacting a bicyclic olefin of the formula II with haloform in the presence of a base to give the ring-expanded product of the formula IIIwhereR -R and Z are as defined above andX is halogen;b) hydrolyzing the allylic halogen of the compound of the formula III to the allyl alcohol of the formula IVc) oxidizing the allyl alcohol of the formula IV to the unsaturated ketone of the formula Vd) reacting the ketone of the formula V with a nucleophilic ion Y which stabilizes a negative charge to give the ketone of the formula VIe) hydrolyzing the ketone of the formula VI to the bicyclic 1,3-diketone of the formula I,novel intermediates and novel processes for preparing these intermediates are described.

公开(公告)号：AT234803T

公开(公告)日：2003-04-15

申请号：AT98924202

申请日：1998-04-24

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  VON DEYN WOLFGANG ,  ENGEL STEFAN ,  HILL REGINA LUISE ,  KARDORFF UWE ,  MAYER GUIDO ,  OTTEN MARTINA ,  RACK MICHAEL ,  RHEINHEIMER JOACHIM ,  WITSCHEL MATTHIAS ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT

IPC: C07D317/26 ,  A01N35/04 ,  A01N35/06 ,  A01N35/10 ,  A01N37/10 ,  A01N37/34 ,  A01N37/42 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/30 ,  A01N43/32 ,  C07C45/46 ,  C07C45/54 ,  C07C49/813 ,  C07C49/835 ,  C07C49/84 ,  C07C49/86 ,  C07C67/31 ,  C07C69/738 ,  C07C69/76 ,  C07C205/45 ,  C07C205/56 ,  C07C251/40 ,  C07C251/52 ,  C07C255/40 ,  C07C317/24 ,  C07C317/34 ,  C07C317/44 ,  C07C323/22 ,  C07D261/08 ,  C07D307/38 ,  C07D307/46 ,  C07D319/06 ,  C07D333/12 ,  C07D333/22

Abstract: The invention relates to 2-(3-alkenylbenzoyl)cyclohexane-1,3-diones of the formula Iwhere the variables have the following meanings:R1, R2 are hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, -OR6, -OCOR7, -OSO2R7, -SH, -S(O)nR8, -SO2OR6, -SO2NR6R9, -NR9SO2R7 or -NR9COR7;R3 is hydrogen, halogen, alkyl, haloalkyl, alkoxy, alkenyl, alkynyl;R4, R5 are hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, alkoxy, alkylthio, haloalkoxy, -COR10, -CO2R10, -COSR10, -CONR10R11, -C(R12)=NR13, -PO(OR10)(OR11); unsubstituted or substituted alkyl, heterocyclyl, heterocyclylalkyl, phenyl, phenylalkyl, hetaryl or hetarylalkyl; orR4 and R5 together form an alkanediyl chain which can be substituted and/or can be interrupted by a hetero atom;Q is an unsubstituted or substituted cyclohexane-1,3-dione ring which is linked in the 2-position;and agriculturally useful salts thereof;processes for the preparation of the compounds of the formula I; compositions comprising them; and the use of these derivatives or compositions comprising them for controlling undesired plants.

公开(公告)号：CZ291468B6

公开(公告)日：2003-03-12

申请号：CZ276895

申请日：1994-04-13

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  BRATZ MATTHIAS ,  THEOBALD HANS ,  GERBER MATTHIAS ,  WESTPHALEN KARL OTTO ,  WALTER HELMUT ,  RADEMACHER WILHELM

IPC: C07D251/22 ,  A01N43/54 ,  A01N43/64 ,  A01N43/66 ,  A01N43/72 ,  A01P13/00 ,  A01P21/00 ,  C07C45/58 ,  C07C47/198 ,  C07C47/277 ,  C07C59/125 ,  C07C67/31 ,  C07C69/708 ,  C07C69/734 ,  C07C205/28 ,  C07C323/22 ,  C07C323/50 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D251/24 ,  C07D251/30 ,  C07D251/34 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D411/12 ,  C07D413/12 ,  C07D477/12 ,  C07D491/048 ,  C07D417/12

Abstract: In the present invention there is disclosed a 3-(het)arylcarboxylic acid derivative of the general formula I, in which the substituents have specific meaning, further process for preparing the derivative by reacting the corresponding carboxylic acid with pyrimidyl derivatives, a herbicidal agent containing the derivative of the general formula I, a method for controlling undesirable plant growth, wherein a herbicidal amount of a compound of the formula I is allowed to act on the plants or on their habitat, an agent for influencing plant growth, containing the derivative of the general formula I, as well as a method for regulating plant growth, wherein a bioregulatory amount of the derivative of the general formula I is allowed to act on the plants.

公开(公告)号：AU757752B2

公开(公告)日：2003-03-06

申请号：AU1667099

申请日：1998-11-06

Applicant: BASF AG

Inventor： RHEINHEIMER JOACHIM ,  WITSCHEL MATTHIAS ,  ENGEL STEFAN ,  BAUMANN ERNST ,  DEYN WOLFGANG VON ,  HILL REGINA LUISE ,  MAYER GUIDO ,  MISSLITZ ULF ,  WAGNER OLIVER ,  OTTEN MARTINA ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

IPC: A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D231/16 ,  C07D231/20 ,  C07D401/10 ,  C07D403/10 ,  C07D405/10 ,  C07D409/10 ,  C07D413/06 ,  C07D413/10 ,  C07D417/10 ,  C07D231/18

Abstract: Benzylidenepyrazolones of the formula I,Useful as herbicides.

公开(公告)号：BG106784A

公开(公告)日：2003-01-31

申请号：BG10678402

申请日：2002-06-06

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  VON DEYN WOLFGANG ,  KUDIS STEFFEN ,  LANGEMANN KLAUS ,  MAYER GUIDO ,  MISSLITZ ULF ,  NEIDLEIN ULF ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  WITSCHEL MATTHIAS

IPC: C07D261/04 ,  A01N43/80 ,  C07D409/14 ,  C07D413/00 ,  C07D413/10 ,  C07D413/12 ,  C07D413/14 ,  A01N53/00

Abstract: The invention relates to 3-(4,5-dihydroisoxalole-5-yl)benzoylpyrazole of the formula therein the variables have the following meanings: R1, R2 represent hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogen alkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl or halogenalkylsulfonyl; hydrogen, R3 represents halogen or alkyl; R4 represents hydrogen or alkyl; R5, R6 represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the latter six groups can be substituted; R7 represents halogen, cyano, hydroxy, alkyl, halogenalkyl, alkoxy, halogenalkoxyalkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, amino, alkylamino, dialkylamino, dialkoxymethyl, hydroxyiminoalkyl, alkoxyiminoalkyl or optionally substituted carbonyl; R11 represents optionally substituted pyrazole that is bound in the 4 position and carries a hydroxy group or a derivative thereof in the 5 position. The invention also relates to the agriculturally useful salts thereof, to methods and to intermediate products for preparing the 3-(4,5-dihydroisoxalole-5-yl)benzoylpyrazole, to agents containing them and to the use of said derivatives or the agents containing them for combatting undesired plants. 17 claims

公开(公告)号：SK282886B6

公开(公告)日：2003-01-09

申请号：SK86799

申请日：1997-12-19

Applicant: BASF AG

Inventor： KARDORFF UWE ,  HILL REGINA LUISE ,  RACK MICHAEL ,  VON DEYN WOLFGANG ,  ENGEL STEFAN ,  OTTEN MARTINA ,  WITSCHEL MATTHIAS ,  BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  MAYER GUIDO ,  MISSLITZ ULF ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

IPC: A01N33/24 ,  A01N33/26 ,  A01N37/18 ,  A01N37/42 ,  A01N41/10 ,  A01N43/08 ,  A01N43/16 ,  A01N43/18 ,  A01N43/32 ,  C07C45/46 ,  C07C233/65 ,  C07C235/78 ,  C07C243/38 ,  C07C251/60 ,  C07C251/86 ,  C07C259/10 ,  C07C317/44 ,  C07C317/46 ,  C07C327/56 ,  C07D309/04 ,  C07D309/06 ,  C07D319/12 ,  C07D333/28 ,  C07D335/02

Abstract: The invention concerns 2-benzoyl-cyclohexan-1,3-diones of formula (I), in which R1, R2 stand for hydrogen, nitro, halogen, cyano, rhodano, alkyl, halogen alkyl, alkoxyalkyl, alkenyl, alkinyl, -OR5, -OCOR6, -OSO2R6, -SH, -S(O)nR7, -SO2OR5, -SO2NR5R8, -NR8SO2R6 or -NR8COR6; R3 stands for hydrogen, alkyl, halogen alkyl or alkinyl; R4 stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkinyl, -COR9, -CO2R9, -COSR9 or -CONR8R9; X stands for oxygen or sulphur; m equals 0 or 1; n equals 0, 1 or 2; R5 stands for hydrogen, alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R6 stands for alkyl or halogen alkyl; R7 stands for alkyl, halogen alkyl, alkoxyalkyl, alkenyl or alkinyl; R8 stands for hydrogen or alkyl; R9 stands for alkyl, alkenyl, alkinyl, phenyl or benzyl; R10 stands for alkyl, halogen alkyl, alkenyl or alkinyl; Q stands for optionally substituted cyclohexan-1,3-dione ring linked in position 2, whereas m equals 1 when R3 stands for hydrogen. Also disclosed are the salts of these compounds useful in agriculture; processes and intermediate products for preparing the compounds of formula (I), agents containing the same and the use of these derivatives or agents containing the same for controlling undesirable plants.

公开(公告)号：DE59903358D1

公开(公告)日：2002-12-12

申请号：DE59903358

申请日：1999-12-02

Applicant: BASF AG

Inventor： NEIDLEIN ULF ,  GOETZ NORBERT ,  MISSLITZ ULF ,  GOETZ ROLAND ,  BAUMANN ERNST ,  VON DEYN WOLFGANG ,  KUDIS STEFFEN ,  LANGEMANN KLAUS ,  MAYER GUIDO ,  WITSCHEL MATTHIAS ,  OTTEN MARTINA ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

IPC: A01N43/50 ,  A01N43/56 ,  A01N43/74 ,  A01N43/80 ,  C07B61/00 ,  C07D231/20 ,  C07D413/10 ,  C07D413/12

Abstract: 3-(Heterocyclyl)benzoylpyrazole derivatives of the formula Iwhere:X is O, NH or N-alkyl;R1 is nitro, halogen, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfonyl or haloalkylsulfonyl;R2,R3,R4,R5 are hydrogen, alkyl or haloalkyl;R6 is halogen, nitro, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfonyl or haloalkylsulfonyl;R7 is hydroxyl, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, (alkylthio)carbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, where the phenyl radical may be substituted;R8,R9 are alkyl;R10 is hydrogen or alkyl;R11 is hydrogen or alkyl;and their agriculturally useful salts,compounds for their preparation, and the use of these compounds or of compositions comprising them for controlling undesirable plants are described.

公开(公告)号：ES2173916T3

公开(公告)日：2002-11-01

申请号：ES94913588

申请日：1994-04-13

Applicant: BASF AG

Inventor： BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  VOGELBACHER UWE JOSEF ,  BRATZ MATTHIAS ,  THEOBALD HANS ,  GERBER MATTHIAS

IPC: A01N43/54 ,  A01N43/64 ,  A01N43/66 ,  A01N43/72 ,  A01P13/00 ,  A01P21/00 ,  C07C45/58 ,  C07C47/198 ,  C07D251/22 ,  C07C47/277 ,  C07C59/125 ,  C07C67/31 ,  C07C69/708 ,  C07C69/734 ,  C07C205/28 ,  C07C323/22 ,  C07C323/50 ,  C07D239/26 ,  C07D239/30 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D251/24 ,  C07D251/30 ,  C07D251/34 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D411/12 ,  C07D413/12 ,  C07D477/12 ,  C07D491/048

Abstract: PCT No. PCT/EP94/01141 Sec. 371 Date Oct. 19, 1995 Sec. 102(e) Date Oct. 19, 1995 PCT Filed Apr. 13, 1994 PCT Pub. No. WO94/25442 PCT Pub. Date Nov. 10, 19943-(Het)arylcarboxylic acid derivatives of the formula I I where R is formyl, CO2H or a radical hydrolyzable to COOH and the other substituents have the following meanings: R2 and R3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR14, where R14 is hydrogen or, together with R3, forms an alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R4 is phenyl or naphthyl, each of which is unsubstituted or substituted or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; R5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R6 is C1-C8-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C3-C4-cyclo-alkyl, each of which may be mono- or polysubstituted; Y is sulfur, oxygen or a single bond; and Z is sulfur or oxygen; with the proviso that R6 is not unsubstituted C1-C4-alkyl when R4 is unsubstituted phenyl, Z is oxygen and simultaneously R5 is methyl or hydrogen.

公开(公告)号：BR0016086A

公开(公告)日：2002-08-06

申请号：BR0016086

申请日：2000-11-27

Applicant: BASF AG

Inventor： KUDIS STEFFEN ,  BAUMANN ERNST ,  DEYN WOLFGANG VON ,  LANGEMANN KLAUS ,  MAYER GUIDO ,  MISSLITZ ULF ,  NEIDLEIN ULF ,  WITSCHEL MATTHIAS ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT

IPC: A01N43/80 ,  C07D261/04 ,  C07D413/10 ,  C07D413/00

Abstract: 3-(4,5-Dihydroisoxazol-3-yl)-substituted benzoylpyrazoles of the formula Iin which R4 is C1-C4-haloalkyl and R1 to R3 and R5 to R10 are as defined in the description are described. The compounds have herbicidal activity.

公开(公告)号：EA002599B1

公开(公告)日：2002-06-27

申请号：EA199900994

申请日：1998-04-24

Applicant: BASF AG

Inventor： ENGEL STEFAN ,  BAUMANN ERNST ,  VON DEYN WOLFGANG ,  HILL REGINA LUISE ,  KARDIRFF UWE ,  MAYER GUIDO ,  ITTEN MARTINA ,  RHEINHEIMER JOACHIM ,  WAGNER OLIVER ,  WITSCHEL MATTHIAS ,  MISSLITZ ULF ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  KOLESNIKOVA M V

IPC: A01N43/04 ,  A01N43/20 ,  C07D303/32 ,  C07D305/08 ,  C07D305/10 ,  C07D305/12 ,  C07D405/04 ,  C07D407/04 ,  C07D409/04 ,  C07D493/10 ,  C07F7/08 ,  C07F7/18 ,  C07F9/655

Abstract: Настоящееизобретениеотноситсяк замещенным 2-бензоилциклогексан-1,3-дионамформулы Iвкоторойзаместителиимеютследующиезначения:R, Rводород, меркапто, нитро, галоген, циано, родано, C-Cалкил, C-Cгалогеналкил, C-Cалкокси, C-Cалкенил, C-Cалкинил, -OR, -OCOR, -OSOR, -S(O)R, -SOOR, -SONRR-NRSORили -NRCOR;Q обозначаетнеобязательнозамещенное, связанноев положении 2 циклогексан-1,3-дионовоекольцо;Аобозначаетгруппуформулы IIa, IIb или IIIвкоторойзаместителиимеютприведенныев п.1 формулыизобретениязначения, атакжек ихприменимымв сельскомхозяйствесолям.