MEZCLAS HERBICIDAS SINERGICAS QUE CONTIENEN UN DERIVADO DE UNA SULFONILUREA Y DICAMBA.

    公开(公告)号:ES2274363T3

    公开(公告)日:2007-05-16

    申请号:ES04019639

    申请日:1996-09-12

    Applicant: BASF AG

    Abstract: Mezcla herbicida que contiene a) al menos un derivado de sulfonilurea de la fórmula I en la que los substituyentes tienen el siguiente significado: R1 alquilo con 1 a 6 átomos de carbono, que puede portar uno a cinco de los siguientes grupos: metoxi, etoxi, SO2CH3, ciano, cloro, flúor, SCH3, S(O)CH3; halógeno; un grupo ER6 en el que E significa O, S o NR7; COOR8; NO2; S (O)oR9, SO2NR10R11, CONR10R11; R2 hidrógeno, alquilo con 1 a 4 átomos de carbono, alquenilo con 2 a 4 átomos de carbono, alquinilo con 2 a 4 átomos de carbono, halógeno, alcoxi con 1 a 4 átomos de carbono, alcoxi halogenado con 1 a 4 átomos de carbono, alquilo halogenado con 1 a 4 átomos de carbono, un grupo alquilsulfonilo con 1 a 2 átomos de carbono, nitro, ciano o alquiltio con 1 a 4 átomos de carbono, R3 F, CF3, CF2Cl, CF2H, OCF3, OCF2Cl o, si R1 representa CO2CH3 y simultáneamente R2 representa flúor, Cl, o, si R1 representa CH2CF3 o CF2CF3, metilo, o, si R4 representa OCF3 o OCF2Cl, OCF2H o OCF2Br; R4 alcoxi con 1 a 2átomos de carbono, alquilo con 1 a 2 átomos de carbono, alquiltio con 1 a 2 átomos de carbono, alquilamino con 1 a 2 átomos de carbono, dialquilamino con 1 a 2 átomos de carbono, halógeno, alquilo halogenado con 1 a 2 átomos de carbono, alcoxi halogenado con 1 a 2 átomos de carbono, R5 hidrógeno, alcoxi con 1 a 2 átomos de carbono, alquilo con 1 a 4 átomos de carbono; R6 alquilo con 1 a 4 átomos de carbono, alquenilo con 2 a 4 átomos de carbono, alquinilo con 2 a 4 átomos de carbono o cicloalquilo con 3 a 6 átomos de carbono, que pueden portar 1 a 5 átomos de halógeno, con excepción de alilo, difluormetoxi, clorodifluormetoxi y 2- cloroetoxi, si E significa O o S. Además, R6, en el caso de que E represente O o NR7, significa aún metilsulfonilo, etilsulfonilo, trifluormetilsulfonilo, alilsulfonilo, propargilsulfonilo o dimetilsulfamoilo.

    247.
    发明专利
    未知

    公开(公告)号:DE59505617D1

    公开(公告)日:1999-05-20

    申请号:DE59505617

    申请日:1995-01-27

    Applicant: BASF AG

    Abstract: 2-Aroyl-cyclohexane dione derivs. of formula (I) and the agriculturally acceptable salts of (I) with 1-10C carboxylic acids or inorganic acids are new. A = 1-6C alkylene; R = phenyl or 5-6 membered heteroaryl (each ring being opt. mono to tetra-substd. with halogen, CN, NO2, N = N-Ph, S(O)mR , (1-4C alkoxy)carbonyl, SO2NR R , NR COR , NR SO2R , 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy (these last 4 gps. themselves opt. mono or di substd. with 1-4C alkoxy, 1-4C alkylthio and/or CN) and 2 neighbouring C atoms on each ring being opt. linked by one of these chains: CR =CR CR =CR , XCR =N, XN=CR , CR =NCR R -X, XCR =NCR R , XCR =CR , XCR =CR -CR R , XCR R -CR R , CR R -X-CR R , X-CR R -Y, X-CR R -CR R -Y, X-CR R -CR R -CR R , CR R -X-CR R -CR R , XNR X, SNR X, CR R -NR X, XNR YNR , or NR XN=CR ); X and Y = each, S, O, SO, SO2, CO, CR R or NR ; R - R = each H, halogen, OH, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C alkylamino, di(1-4C alkyl)amino or phenyl; R , R = H, 1-4C alkyl, 1-4C alkoxy, (1-4C alkyl)carbonyl, phenyl or benzoyl; Ph = phenyl opt. mono to tri-substd. with halogen, CN, NO2 S(O)nR , (1-4C alkoxy)carbonyl, SO2NR R , NR COR , NR SO2R , 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, or 1-4C haloalkoxy (these last 4 gps.themselves opt. mono or di substd.with 1-4C alkoxy, 1-4C alkylthio and/or CN); m and n = 0-2; R and R = 1-4C alkyl or 1-4C halo-alkyl (each opt. mono- or di-substd. with 1-4C alkoxy, 1-4C alkylthio and/or CN); R ,R ,R and R = H, 1-4C alkyl, 1-4C haloalkyl, or phenyl (this last opt. mono to tri-substd. with halogen, 1-4C alkyl or 1-4C alkoxy); R and R = each 1-4C alkyl or 1-4C halo-alkyl (each opt. mono or di-substd. with CN, phenyl and/or benzyl); R -R = H or 1-4C alkyl; R = H, 1-4C alkyl or (1-4C alkoxy)carbonyl; R = 1-4C alkyl; provided that R is not mono or di-halo-phenyl.

    New 3-aryl-methyl-uracil derivatives

    公开(公告)号:DE19738084A1

    公开(公告)日:1999-03-04

    申请号:DE19738084

    申请日:1997-09-01

    Applicant: BASF AG

    Abstract: 3-Arylmethyluracil derivatives (I.1)-(I.4) are new, where A = H, 1-4C alkyl, NH2, 1-4C alkylamino or di-(1-4C alkyl)amino; X = O or S; n = not defined; R1 = 1-4C haloalkyl; R2 = H, halo or 1-3C alkyl; R3-R5 = H, CN, thiocyanato, halo, 1-4C haloalkyl, 1-4C haloalkoxy, 1-4C haloalkylthio, 1-4C alkyl or 1-4C alkoxy; R6, R7 = 1-4C alkyl, NH2, 1-4C alkylamino or di(1-4C alkyl)amino, or R6 and R7 together form =O; R8 may be in position alpha or beta and R3 is in the other position; R8 = (1) H, halo, amino, 1-4C alkylsulphonylamino or di(1-4C alkyl)amino; (2) 1-6C alkoxy, 1-6C alkylthio, 3-6C cycloalkoxy, 3-6C cycloalkylthio, 2-6C alkenyloxy, 5-7C cycloalkenyloxy, 2-6C alkenylthio, 2-6C alkynyloxy, 2-6C alkynylthio, (1-6C alkyl)carbonyloxy, (1-6C alkyl)carbonylthio, (1-6C alkoxy)carbonyloxy, (2-6C alkenyl)carbonyloxy, (2-6C alkenyl)carbonylthio, (2-6C alkynyl)carbonyloxy, (2-6C alkynyl)carbonylthio, 1-6C alkylsulphonyloxy or 1-6C alkylsulphonyl, where the last 18 groups may contain 1-4 substituents; (3) CT-R11, C(R11)(Y1R12)(Y2R13), C(R11)=C(R14)CN, C(R11)=C(R14)CO-R15, CH(R11)-CH(R14)CO-R15, C(R11)=C(R14)-CH2-CO-R15, C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, C(R11)=C(R14)-CH2-CH(R18)CO-R15, CO-OR19, CO-SR19, CO-N(R19)-OR20, C?=C-CO-NH-OR20, C?=C-CO-N(R19)-OR20, , C?=C-CS-NH-OR20, C?=C-CS-N(R19)-OR20, C(R11)=C(R14)-CO-NH-OR20, C(R11)=C(R14)-CO-N(R19)-OR20, C(R11)=C(R14)-CS-NH-OR20, C(R11)=C(R14)-CS-N(R19)-OR20, C(R11)=C(R14)-C(R21)=N-OR20, C(R21)=N-OR20, C?=C-C(R21)=N-OR20, C(Y1R12)(Y2R13)-OR19, C(Y1R12)(Y2R13)-SR19, C(Y1R12)(Y2R13)-N(R23)(R24), N(R23)(R24), CO-N(R23)(R24), or groups of formula (i), (ii), -C?=C-(i), -C?=C-(ii), -C(R11)=C(R14)-(i) or -C(R11)=C(R14 )-(ii); Y1, Y2 = S or O; theta = 1-3C alkylene optionally substituted by 1-6C alkyl; R11 = H, CN, 1-6C alkyl, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 3-6C cycloalkyl, 1-6C alkoxy-(1-6C alkyl) or (1-6C alkoxy)carbonyl; R12, R13 = 1-6C alkyl, 1-6C haloalkyl, 3-6C alkenyl, 3-6C alkynyl or 1-6C alkoxy-(1-6C alkyl) or R12 and R13 together form a 2-4 membered carbon chain which is optionally substituted and can contain non-adjacent O, S or N atoms instead of C atoms or be condensed or form a spiro attachment with a 3-7 membered ring; R14 = H, CN, halo, 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy, (1-6C alkyl)carbonyl or (1-6C alkoxy)carbonyl; R15 = H, OR22, SR22, 1-6C alkyl (optionally substituted by one or two 1-6C alkoxy groups), 2-6C alkenyl, 2-6C alkynyl, 1-6C haloalkyl, 3-6C cycloalkyl, 1-6C alkylthio-(1-6C alkyl), 1-6C alkyliminooxy, N(R23)(R24) or optionally substituted phenyl; R22 has the same meanings as R19; R16 = H, CN, halo, 1-6C alkyl, 3-6C alkenyl, 3-6C alkynyl, 1-6C alkoxy-(1-6C alkyl), (1-6C alkyl)carbonyl, (1-6C alkoxy)carbonyl, N(R25)(R26) or optionally substituted phenyl; R25, R26 have the same meanings as R23 and R24; R17 = H, halo, CN, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl, (1-6C alkyl)carbonyl or (1-6C alkoxy)carbonyl; R18 = H, CN, 1-6C alkyl or (1-6C alkoxy)carbonyl; R19 = H, 1-6C alkyl, 1-6C haloalkyl, 2-6C alkenyl or 2-6C alkynyl (where the latter four groups are optionally substituted), (1-6C alkyl)carbonyl, (1-6C haloalkyl)carbonyl, (1-6C alkoxy)carbonyl, 1-6C alkylaminocarbonyl, di-(1-6C alkyl)aminocarbonyl, 1-6C alkoxyimino-(1-6C alkyl), 3-6C cycloalkyl, phenyl or phenyl-(1-6C alkyl), where the phenyl ring is optionally substituted; R20 = H, 1-6C alkyl, 1-6C haloalkyl, 3-6C cycloalkyl, 3-6C alkenyl, 3-6C alkynyl, hydroxy-(1-6C alkyl), 1-6C alkoxy-(1-6C alkyl), 1-6C alkylthio-(1-6C alkyl), cyano-(1-6C alkyl), (1-6C alkyl)carbonyl-(1-6C alkyl), (1-6C alkoxy)carbonyl-(1-6C alkyl), (1-6C alkoxy)carbonyl-(2-6C alkenyl), (1-6C alkyl)carbonyloxy-(1-6C alkyl) or phenyl-(1-6C alkyl), where the phenyl ring may contain 1-3 substituents; R

    HERBICIDAL MIXTURES EXHIBITING SYNERGETIC ACTIVITY

    公开(公告)号:CZ79298A3

    公开(公告)日:1998-09-16

    申请号:CZ79298

    申请日:1996-09-12

    Applicant: BASF AG

    Abstract: Herbicidal mixt. comprises: (a) at least one fluoro-substd. sulphonyl urea derivs. of formula (I) or their salts; and (b) at least one herbicide in a synergistic amt. selected from e.g. buthidazole or cyprazole; allidochlor (CDDA), benzoylprop-ethyl, bromobutide, chlorthiamid, dimepiperate, dimethenamid, diphenamid, etobenzanid (benzchlomet), flampropmethyl, fosamin, isoxaben, monalide, naptalame, pronamid (propyzamid) or propanil; bilanafos (bialophos), buminafos, glufosinate ammonium, glyphospate or sulfosate; amitrole, anilofos or mefenacet; 2,4-D, 2,4-DB, clomeprop, dichlorprop, dichlorprop-P, dichlorprop-P (2,4-DP-P), fenoprop (2,4,5-TP, fluoroxypyr, MCPA, MCPB, mecoprop, mecoprop-P, napropamide, napropanilide or triclopyr, or salts of these. Z = N or CH; R1 = 1-6C alkyl opt. substd. by 1-5 OMe, OEt, SO2Me; CN; Cl; F; SMe; or S(O)Me; halo; ER6; COOR8; NO2; S(O)oR9, SO2NR10R11,; or CONR10R11; E = O; S or NR7; R2 = H; 1-4C alkyl or 1-4C alkoxy opt. substd. by halo; 2-4C alkenyl; 2-4C alkynyl; halo; SO2Me; SO2Et; NO2; CN; or 1-4C alkylthio; R3 = F, CF3; CF2Cl; CF2H; OCF3; OCF2Cl; Cl (when R1 - CO2Me and R2 = F); Me (when R1 = CH2CF3 or CF2CF3); or OCF2H or OCF2Br (when R4 =- OCF3 or OCF2Cl); R4 = OMe; OEt; Me or Et opt. substd. by halo; SMe; SEt; NHMe; NHEt; N(1-2C alkyl)2; or halo; R5 = H, OMe; OEt; or 1-4C alkyl; R6 = 1-4C alkyl, 2-4C alkenyl, 2-4C alkynyl or 3-6C cycloalkyl opt. substd by 1-5 halo (except allyl, OCH2F, OCF2Cl or 2-Cl-Et) when E = O or S; or SO2Me, SO2Et, SO2CF3, SO2-allyl or SO2-propargyl when E = O or NR7; R7 = H; Me; or Et; R8 = 1-6C alkyl opt. mono-, di- or trisubstd. by halo, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkoxy, 1-4C alkoxy-1-2C alkoxy, 3-7C cycloalkyl and/or Ph; 5-7C cycloalkyl opt. mono-, di- or trisubstd. by 1-4C alkyl; 3-6C alkenyl; or 3-6C alkynyl; R10 = H; OMe; OEt; or 1-6C alkyl; and R11 = 1-4C alkyl opt. substd by 1-4 halo or 1-4C alkoxy; or 3-6C cycloalkyl; or R10+R11 = 4-6C alkylene with 1 CH2 opt. replaced by O or 1-4C alkylimino; n = 0-3; and o = 1-2.

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