公开(公告)号：DE19904261A1

公开(公告)日：2000-08-10

申请号：DE19904261

申请日：1999-02-03

Applicant: BASF AG

Inventor： HALBRITTER KLAUS ,  STERZEL HANS-JOSEF ,  TRAGUT CHRISTIAN ,  FREUDENTHALER EVA

IPC: C07D327/10 ,  C07B61/00 ,  C07C301/00

Abstract: The invention relates to a method of producing dimethyl sulfite by reacting a cyclic alkylene sulfite having at least 2 carbon atoms with methanol, optionally in the presence of a catalyst. The inventive method is carried out in a continuous manner in a column.

公开(公告)号：ZA9811614B

公开(公告)日：2000-06-19

申请号：ZA9811614

申请日：1998-12-18

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  BOTTCHER ARND ,  BREITSCHEIDEL BORIS ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  THILL LUCIEN ,  PINKOS ROLF

IPC: C07C51/36 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12 ,  C07C ,  B01J ,  C07B ,  C08K

公开(公告)号：AU2613399A

公开(公告)日：1999-07-12

申请号：AU2613399

申请日：1998-12-18

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  BOTTCHER ARND ,  BREITSCHEIDEL BORIS ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  THIL LUCIEN ,  PINKOS ROLF

IPC: B01J23/46 ,  C07B61/00 ,  C07C51/36 ,  C07C61/08 ,  C07C61/09 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12

Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.

公开(公告)号：CA2236614A1

公开(公告)日：1998-11-28

申请号：CA2236614

申请日：1998-05-27

Applicant: BASF AG

Inventor： FUCHS HARTWIG ,  AQUILA WERNER ,  W RZ OTTO ,  RUPPEL WILHELM ,  HALBRITTER KLAUS

IPC: B01J23/52 ,  B01J8/02 ,  B01J8/08 ,  C07B61/00 ,  C07C45/38 ,  C07C45/67 ,  C07C47/21 ,  C07C47/22

Abstract: A process for continuous industrial production of unsaturated aliphatic aldehydes having a boiling range from 95 to 136.degree.C by oxidative dehydrogenation of the corresponding alcohols with an oxygen-comprising gas over a supported catalyst consisting of copper, silver and/or gold on an inert support in a tube bundle reactor, rapid cooling of the reaction gases and removal of the aldehydes from the resulting condensate with recycling of the unconverted alcohols comprises a) vaporizing the alcohol, b) admixing the alcohol vapor with an oxygen-comprising gas, c) initially passing the resulting oxygen-comprising alcohol vapor at above the dew point of the alcohol but below the commencement temperature of the reaction through a layer of one of the abovementioned supported catalysts which is at least 0.5 cm in thickness and only then d) reacting the oxygen-comprising alcohol vapor at from 300 to 600.degree.C in a sufficient number, for the desired capacity, of parallel reaction tubes surrounded by a fluidic heat transfer medium, packed with the supported catalyst and having an internal diameter D of from about 0.5 to 3 cm and a length of at least 5 cm, to form the corresponding aldehyde.

公开(公告)号：DE3612213A1

公开(公告)日：1987-10-15

申请号：DE3612213

申请日：1986-04-11

Applicant: BASF AG

Inventor： BRENNER KARL ,  RUPPEL WILHELM ,  WOERZ OTTO ,  HALBRITTER KLAUS ,  SCHEIPER HANS-JUERGEN ,  AQUILA WERNER ,  FUCHS HARTWIG

IPC: B01J8/06 ,  C07B61/00 ,  C07C45/00 ,  C07C45/38 ,  C07C45/39 ,  C07C47/21 ,  C07C67/00 ,  B01J12/00 ,  B01J23/50 ,  C07C45/29

Abstract: In the reactor for carrying out catalytic organic reactions in the gas phase, having reaction tubes (A) arranged between tube plates (B), the reaction tubes have an internal diameter in the range from 0.5 to 3 cm, the reaction tube length/internal diameter ratio is between 2 and 10, and a fluid heat transfer medium flows in the lateral direction around the reaction tubes (A). The tube bundle reactor is particularly suitable for exothermic organic reactions. … …

公开(公告)号：CA1197858A

公开(公告)日：1985-12-10

申请号：CA448534

申请日：1984-02-29

Applicant: BASF AG

Inventor： ECKHARDT HEINZ ,  HALBRITTER KLAUS ,  GOETZ NORBERT ,  HEILEN GERD

IPC: C07D309/26

Abstract: 3-Formyl-5,6-dihydro-2H-pyran is prepared by conversion of acrolein in the presence of water, acids and halohydrocarbons of 1 to 6 carbon atoms and 1 to 6 halogen atoms as solvents at from 60 to 150.degree.C. The 3-formyl-5,6-dihydro-2H-pyran obtained by the novel process is a valuable starting material for the preparation of dyes and crop protection agents.

公开(公告)号：CA2315223C

公开(公告)日：2010-02-09

申请号：CA2315223

申请日：1998-12-18

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  BOTTCHER ARND ,  BREITSCHEIDEL BORIS ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  THIL LUCIEN ,  PINKOS ROLF

IPC: B01J23/46 ,  C07C69/75 ,  C07B61/00 ,  C07C51/36 ,  C07C61/08 ,  C07C61/09 ,  C07C67/303 ,  C08K5/12

Abstract: The invention relates to a method for hydrogenating a benzene polycarboxylic acid or a derivative thereof or of a mixture comprised of two or more thereof with a gas containing hydrogen in the presence of a catalyst. Said catalyst comprises ruthenium as an active metal which is deposited alone or together with at least one metal of subgroups I, VII, or VIII of the periodic table on a support, whereby the support contains macropores. The invention also relates to novel hydrogenated products obtained by hydrogenating benzene polycarboxylic acid (derivatives) and to the use thereof as plasticizers in plastics.

公开(公告)号：DE102005007285A1

公开(公告)日：2006-08-24

申请号：DE102005007285

申请日：2005-02-17

Applicant: BASF AG

Inventor： GRIESBACH ULRICH ,  PUETTER HERMANN ,  HALBRITTER KLAUS ,  FARDEL ROMAIN ,  COMNINELLIS CHRISTOS

IPC: C25B3/23

Abstract: Preparation of trimethyl orthoformate (I) or tetramethyl orthocarbonate (II) by oxidation, at an electrode, of an electrolyte containing (a) a mixture of methanol (III) and at least one of formaldhyde or formaldehyde dimethylacetal (FMDA), to produce (I); or (b) a mixture of (III) and (I), to produce (II).

公开(公告)号：AR038161A1

公开(公告)日：2004-12-29

申请号：ARP030100139

申请日：2003-01-17

Applicant: BASF AG

Inventor： MASSONNE KLEMENS ,  HALBRITTER KLAUS ,  NOE RALF ,  BARTSCH MICHAEL ,  SIEGEL WOLFGANG ,  FLORES MIGUEL ,  HUTTENLOCH OLIVER ,  BECKER MICHAEL ,  MAASE MATTHIAS ,  STEGMANN VEIT

IPC: C07D233/58 ,  B01J31/24 ,  C07B61/00 ,  C07B63/00 ,  C07B63/02 ,  C07C1/30 ,  C07C7/10 ,  C07C13/23 ,  C07C45/50 ,  C07C67/14 ,  C07C67/58 ,  C07C69/14 ,  C07C69/78 ,  C07C403/12 ,  C07D233/60 ,  C07D403/12 ,  C07F7/18 ,  C07F9/02 ,  C07F9/12 ,  C07F9/142 ,  C07F9/145 ,  C07F9/22 ,  C07F9/46 ,  C07F9/48 ,  C07F9/50 ,  C07F9/52 ,  C07F9/572 ,  C07F9/6503 ,  C07F9/6574 ,  C07F9/6584

Abstract: Procedimiento para separar ácidos de mezclas de reacción mediante una base auxiliar, en donde: a) la base auxiliar forma una sal con el ácido, cuya sal es líquida a temperaturas a las que el producto de valor no es descompuesto significativamente durante la separación de la sal líquida; y b) la sal de la base auxiliar forma con el producto de valor o la solución del producto de valor en un disolvente apropiado dos fases líquidas no miscibles entre sí. La base auxiliar c) actúa simultáneamente como catalizador nucleófilo, y la sal de la base auxiliar tiene un punto de fusión por debajo de 160°C. En dicho procedimiento se usa una base, que es seleccionada de entre las fórmulas (a) a (r), en donde: R1, R2, R3, R4, R5 y R6 significan, independientemente, hidrógeno, alquilo C1-18, alquilo C2-18, arilo C6-12, cicloalquilo C5-12 eventualmente interrumpidos por uno o varios átomos de oxígeno y/o átomos de azufre y/o uno o varios grupos imino sustituidos o no sustituidos, o un heterociclo de 5 a 6 miembros que presenta átomos de oxígeno, nitrógeno y/o átomos de azufre, cuyos radicales mencionados pueden estar sustituidos en cada caso por grupos funcionales, arilo, alquilo, ariloxi, alquiloxi, halógeno, heteroátomos y/o heterocicleno. Uso de una fosfina, de ésteres de ácido fosfínico, ésteres de ácido fosfinoso (fosfinitas), ésteres de ácido fosfónico, haluros de ácido fosfónico, amidas de ácido fosfónico, ésteres de ácido fosfonoso (fosfonitas), amidas de ácido fosfonoso, haluros de ácido fosfonoso, ésteres de ácido fosfórico, haluros de diésteres de ácido fosfórico, amidas de diésteres de ácido fosfórico, dihaluros de ésteres de ácido fosfórico, diamidas de ésteres de ácido fosfórico, ésteres de ácidos fosforosos (fosfitas), haluros de diésteres de ácido fosforoso, amidas de diésteres de ácido fosforoso, dihaluros de ésteres de ácido fosforoso o de diamidas de ésteres de ácido fosforoso, obtenidos según el procedimiento descripto como ligandos para catalizadores.

公开(公告)号：AT273949T

公开(公告)日：2004-09-15

申请号：AT00905013

申请日：2000-02-03

Applicant: BASF AG

Inventor： HALBRITTER KLAUS ,  STERZEL HANS-JOSEF ,  EIERMANN MATTHIAS ,  FREUDENTHALER EVA

IPC: C07C303/02 ,  C07B61/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/26 ,  C07C309/04 ,  C07C309/66 ,  C07D327/10 ,  H05K3/34