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公开(公告)号:BRPI0608709A2
公开(公告)日:2010-01-26
申请号:BRPI0608709
申请日:2006-03-15
Applicant: BASF AG
Inventor: DIETZ JOCHEN , GROTE THOMAS , BLETTNER CARSTEN , HUENGER UDO , SCHOFER PETER , RETHER JAN , EICKEN KARL , GEWEHR MARKUS , GRAMMENOS WASSILIOS , MUELLER BERND , SCHIEWECK FRANK , SCHWOEGLER ANJA , LOHMANN JAN KLAAS , RHEINHEIMER JOACHIM , STRATHMANN SIEGFRIED , STIERL REINHARD
IPC: C07D213/82 , A01N43/40
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公开(公告)号:BRPI0513720A
公开(公告)日:2008-05-13
申请号:BRPI0513720
申请日:2005-07-22
Applicant: BASF AG
Inventor: GRAMMENOS WASSILIOS , GROTE THOMAS , BLETTNER CARSTEN , GEWEHR MARKUS , HUENGER UDO , MUELLER BERND , RHEINHEIMER JOACHIM , SCHOFER PETER , SCHIEWECK FRANK , SCHWOEGLER ANJA , SCHOEFL ULRICH , KOELE HARALD , STRATHMANN SIEGFRIED , SCHERER MARIA , STIERL REINHARD , RETHER JAN
IPC: C07D401/04 , A01N43/54
Abstract: 2-Pyridyl pyrimidine derivatives (I) are new. 2-Pyridyl pyrimidine derivatives of formula (I) and their salts are new. k : 0-3; m : 0-5; n : 1-5; R 1>halo, OH, CN, NO 2, 1-4C (halo)alkyl, 104C (halo)alkoxy, 2-4C alkenyl, 2-4C alkynyl, 3-8C cycloalkyl, (1-4C)alkoxy(1-4C)alkyl, NH 2, phenoxy (optionally substituted with halo or 1-4C alkyl), NHR, NRR, C(Ra)=NORb, SO pA 1> or COA 2>; or R 1>+R 1>1-4C (halo)alkylenedioxy; R : 1-4C alkyl or 1-4C alkylcarbonyl; Ra : H or 1-4C alkyl; Rb : 1-4C alkyl, 3-4C alkenyl or 3-4C alkynyl; p : 0-2; A 1>1-4C alkyl, or also NH 2, 1-4C alkylamino or di(1-4C alkyl)amino when p = 2; A 2>H, OH, 1-4C alkyl, 1-4C alkylamino, di(1-4C alkyl)amino, 2-4C alkenyl or 1-4C (halo)alkoxy; R 2>1-4C haloalkyl, 1-4C (halo)alkoxy, OH, halo, CN or NO 2, or R 2> can be H or 1-4C alkyl if n = 3-5 and/or k = 1-3 and/or at least one R 1> is other than halo, 1-4C (halo)alkyl and 1-4C alkoxy; and R 3>1-4C alkyl. An independent claim is also included for controlling phytopathogenic fungi by treating the fungi, or materials, plants, soil or seeds to be protected from fungal attack, with a compound (I). [Image] ACTIVITY : Plant antifungal. In a protective test against Alternaria solani on tomato plants, plants treated with 2-(5-methyl-6-phenyl-2-pyridyl)-4,5-pentamethylene-pyrimidine (250 ppm) suffered no attack, whereas 90% of untreated plants were attacked. MECHANISM OF ACTION : None given.
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公开(公告)号:BRPI0512249A
公开(公告)日:2008-02-19
申请号:BRPI0512249
申请日:2005-06-14
Applicant: BASF AG
Inventor: BLETTNER CARSTEN , GEWEHR MARKUS , GRAMMENOS WASSILIOS , GROTE THOMAS , HUENGER UDO , MUELLER BERND , NIEDENBRUECK MATTHIAS , RHEINHEIMER JOACHIM , SCHOFER PETER , SCHIEWECK FRANK , WAGNER OLIVER , NAVE BARBARA , SCHERER MARIA , STRATHMANN SIEGFRIED , SCHOEFL ULRICH , STIERL REINHARD , SCHWOEGLER ANJA
IPC: A01N43/90 , C07D487/04
Abstract: Substituted triazolopyrimidines of the formula I in which the substituents are as defined below: R 1 is alkyl, halocycloalkyl, alkenyl, cycloalkyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle comprising one to four heteroatoms from the group consisting of O, N and S, R 2 is hydrogen, alkyl or one of the groups mentioned under R 1 ; R 1 and/or R 2 may carry one to four identical or different groups R a : R a is chlorine, bromine, iodine, cyano, nitro, hydroxyl, alkyl, alkylcarbonyl, cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, alkylamino, dialkyl-amino, alkenyl, cycloalkenyl, alkenyloxy, haloalkenyloxy, alkynyl, halo-alkynyl, alkynyloxy, haloalkynyloxy, cycloalkoxy, cycloalkenyloxy, oxyalkylenoxy, naphthyl, a five- to ten-membered saturated, partially unsaturated or aromatic heterocycle comprising one to four heteroatoms from the group consisting of O, N and S, where these aliphatic, alicyclic or aromatic groups for their part may be substituted according to the description; and X is halogen; processes for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.
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公开(公告)号:BRPI0511888A
公开(公告)日:2008-01-15
申请号:BRPI0511888
申请日:2005-06-08
Applicant: BASF AG
Inventor: BLETTNER CARSTEN , GEWEHR MARKUS , GRAMMENOS WASSILIOS , GROTE THOMAS , HUENGER UDO , MUELLER BERND , NIEDENBRUECK MATTHIAS , RHEINHEIMER JOACHIM , SCHOFER PETER , SCHIEWECK FRANK , GLER ANJA SCHW , WAGNER OLIVER , RAPADO LILIANA PARRA , RACK MICHAEL , NAVE BARBARA , SCHERER MARIA , STRATHMANN SIEGFRIED , FL ULRICH SCH , STIERL REINHARD
IPC: A01N43/90 , C07D487/04
Abstract: The invention relates to the use of triazolopyrimidines of the formula I In which: R 1 , R 2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, alkadienyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl, C 3 -C 6 -cycloalkynyl, phenyl, naphthyl, or a five- to ten-membered saturated, partially unsaturated or aromatic heterocycle which contains one, two, three or four heteroatoms from the group consisting of O, N and S, where R 1 , R 2 may be substituted as defined in the description or R 1 and R 2 together with the nitrogen atom to which they are attached may form five- to eight-membered heterocyclyl or heteroaryl which is attached via nitrogen and may contain one, two or three further heteroatoms from the group consisting of O, N and S as ring members and/or may be substituted as defined in the description; L independently of one another are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyloxy, cyano, C(-O)A 1 , S(-O) m A 2 , NR c R d or NR c -(C-O)-R d , where A 1 , A 2 , R c , R d and m are as defined in the description; L 1 is halogen, alkyl or haloalkyl; L 2 is nitro, a group -C(S)NR 3 R 4 , a group -C(-N-OR 5 )(NR 6 R 7 ) or a group -C(-N-NR 8 R 9 )(NR 10 OR 11 ); X is halogen, cyano, alkyl, alkoxy, haloalkyl or haloalkoxy; R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are independently of one another selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkenyl and alkynyl, where the 4 last-mentioned radicals may be substituted as defined in the description; or R 3 and R 4 , or R 6 and R 7 , or R 8 and R 9 or R 10 and R 11 together with the nitrogen atom to which they are attached form a four, five, or six-membered saturated or partially unsaturated ring which may be substituted as defined in the description; n is 0, 1, 2 or 3; and the agriculturally acceptable salts thereof, novel triazolopyrimidines, crop protection compositions comprising at least one compound of the formula I and at least one solid or liquid carrier, and a method for controlling phytopathogenic harmful fungi.
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公开(公告)号:AT383362T
公开(公告)日:2008-01-15
申请号:AT05762108
申请日:2005-07-06
Applicant: BASF AG
Inventor: BLETTNER CARSTEN , GEWEHR MARKUS , GRAMMENOS WASSILIOS , GROTE THOMAS , HUENGER UDO , MUELLER BERND , NIEDENBRUECK MATTHIAS , RHEINHEIMER JOACHIM , SCHAEFER PETER , SCHIEWECK FRANK , SCHWOEGLER ANJA , WAGNER OLIVER , NAVE BARBARA , SCHERER MARIA , STRATHMANN SIEGFRIED , SCHOEFL ULRICH , STIERL REINHARD
IPC: C07D487/04 , A01N43/90
Abstract: Substituted triazolopyrimidines of the formula I in which the substituents are as defined below: R 1 is alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or phenyl, naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle comprising one to four heteroatoms from the group consisting of O, N and S, R 2 is hydrogen or a group R 1 , R 1 and R 2 together with the nitrogen atom, to which they are attached, may also form a five- or six-membered heterocyclyl or heteroaryl which is attached via N and which may comprise one to three further heteroatoms from the groups consisting of O, N and S as ring member and/or may be substituted according to the description; L is fluorine, chlorine or methyl; X is cyano, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or C 1 -C 2 -haloalkoxy, where X is not methyl if R 1 and R 2 together are n-pentylene or 3-methyl-n-pentylene and L is fluorine, or R 1 and R 2 together are 3-methyl-n-pentylene and L is chlorine; processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.
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公开(公告)号:DE102005055841A1
公开(公告)日:2007-05-31
申请号:DE102005055841
申请日:2005-11-23
Applicant: BASF AG
Inventor: HUENGER UDO , NOACK RAINER , GOETZ ROLAND , STUERMER RAINER , LOHMANN JAN KLAAS
IPC: C07D303/36 , B01J31/04 , B01J31/36 , B01J31/38
Abstract: Preparation of an optically active oxirane compound (A) comprises epoxidation of a phenyl compound (A1) using a chiral metal containing epoxidizing catalyst and an oxidizing agent or an achiral metal containing epoxidizing catalyst and a chiral oxidizing agent. Preparation of an optically active oxirane compound (A) of formula (I), (Ib), (Ic) and/or (Id) comprises epoxidation of a phenyl compound (A1) of formula (IIa) or (IIb) using a chiral metal containing epoxidizing catalyst and an oxidizing agent or an achiral metal containing epoxidizing catalyst and a chiral oxidizing agent. R : CH2X, CHO, CH=NR1>, CH=NNR2>, COOH, COOR3>, CONR4>R5> or CN; Rs : CH2OH; X : OH, O-SO2R6> or halo; R1>H, OH, 1-8C alkyl or aryl; R2>H, 1-8C alkyl or aryl; R3>1-8C alkyl, 2-8C hydroxyalkyl or arylalkyl; either R4>, R5>H, 1-8C alkyl, 2-8C hydroxyalkyl, aryl or arylalkyl; or NR4>R5>5-6 membered optionally saturated ring with 1-3 heteroatom; and R6>1-8C (halo)alkyl or aryl. [Image] [Image] ACTIVITY : Fungicide. MECHANISM OF ACTION : None given.
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公开(公告)号:DE102005051514A1
公开(公告)日:2007-05-03
申请号:DE102005051514
申请日:2005-10-26
Applicant: BASF AG
Inventor: DIETZ JOCHEN , GRAMMENOS WASSILIOS , HUENGER UDO , LOHMANN JAN KLAAS , RENNER JENS , RHEINHEIMER JOACHIM
IPC: C07D471/04 , A01N43/90 , A01P3/00
Abstract: Amino-substituted pyridinoazines (I) are new. Amino-substituted pyridinoazines of formula (I) are new. R1>1-14C alkyl, 1-12C alkoxy(1-12C)alkyl, 1-6C alkoxy(2-12C)-alkenyl or -alkynyl, 5-8C cycloalkyl, phenyl, phenyl(1-4C)alkyl, 2-12C alkenyl or alkynyl, where the carbon chain may be substituted by 1-3, same or different, Ra> and/or Rb>; Ra>halo, cyano, nitro, hydroxy, 1-6C alkylthio, 3-12C alkenyloxy or alkynyloxy, NR11>R12>, or phenyl or 3-6C cycloalkyl optionally substituted by 1-4, same or different, Rb>, and carbon chains in Ra> may themselves be halogenated; Rb>halo, cyano, hydroxy, mercapto, 1-6C (halo)alkyl, 3-8C cycloalkyl, 2-10C alkenyl or alkynyl, 1-6C alkoxy or alkylthio, 1-6C alkoxy(1-6C)alkyl or NR11>R12>; R11> and R12>hydrogen or 1-6C alkyl; R2>1-12C alkyl, or 2-12C alkenyl or alkynyl, optionally substituted by 1-3 Rc>; Rc>cyano, nitro, hydroxy, NR11>R12> or 3-6C cycloalkyl (optionally substituted by 1-4 of, same or different, 1-4C alkyl, halo, cyano, nitro, hydroxy, 1-6C alkoxy or alkylthio, 3-6C alkenyloxy or alkynyloxy, or NR11>R12>; W1 and X1, W1 and Y1, W1 and Z1, X1 and Y1, X1 and Z1, or Y1 and Z1 each : N and the others CR3>, or W1, Z1 and one of X1 and Y1 = N and the other CR3>; each R3>hydrogen, halo, or 1-4C alkyl or alkoxy . Independent claims are included for the following: (1) several methods for preparing (I); (2) intermediates of formulae (V), (VI), (VII) and (IX); and (3) seeds treated with (I) at 1-1000 g per 100 kg. in (VI) and (VII) X on the pyrido ring : halo; R22>hydrogen or 1-11C alkyl; R : 1-4C alkyl . [Image] [Image] ACTIVITY : Plant Antifungal. No details of tests for antifungal activity are given. MECHANISM OF ACTION : None given.
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公开(公告)号:DE102005007160A1
公开(公告)日:2006-08-24
申请号:DE102005007160
申请日:2005-02-16
Applicant: BASF AG
Inventor: GEWEHR MARKUS , DIETZ JOCHEN , GROTE THOMAS , BLETTNER CARSTEN , GRAMMENOS WASSILIOS , HUENGER UDO , MUELLER BERND , SCHIEWECK FRANK , SCHWOEGLER ANJA , LOHMANN JAN KLAAS , RHEINHEIMER JOACHIM , SCHAEFER PETER , STRATHMANN SIEGFRIED , STIERL REINHARD
IPC: C07D231/14 , A01N43/56
Abstract: The present invention relates to pyrazolecarboxanilides I in which the variables are as defined below: n is zero or 2; m is 2 or 3; X1 is fluorine or chlorine; X2 is halogen; Y is CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, methoxy or methylthio; p is zero or 1; R1 is fluorine, chlorine, bromine, C1-C4-alkyl or C1-C4-haloalkyl; R2 is hydrogen or halogen; R3 is hydrogen, methyl or ethyl; W is O or S; with the proviso that, if a) W=O, R1=methyl and R3 is hydrogen, R2 is not fluorine, or b) W=O, n=0, m=2, p=0, R2 and R3 are hydrogen, R1 is not trifluoromethyl or difluoromethyl, to processes for preparing these compounds, to compositions comprising them and to methods for using them for controlling harmful fungi.
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公开(公告)号:CA2577041A1
公开(公告)日:2006-03-16
申请号:CA2577041
申请日:2005-09-02
Applicant: BASF AG
Inventor: STRATHMANN SIEGFRIED , BLETTNER CARSTEN , SCHOEFL ULRICH , GEWEHR MARKUS , TORMO I BLASCO JORDI , SCHERER MARIA , STIERL REINHARD , MUELLER BERND , SCHIEWECK FRANK , GRAMMENOS WASSILIOS , JABS THORSTEN , SPEAKMAN JOHN-BRYAN , GROTE THOMAS , HUENGER UDO , RHEINHEIMER JOACHIM , SCHAEFER PETER , SCHWOEGLER ANJA , DIETZ JOCHEN
IPC: C07D487/04 , A01N43/90 , C07D239/00 , C07D249/00
Abstract: 6-Phenyl-7-aminotriazolopyrimidines of the formula I in which the substituents are as defined below: R 1 is hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or phenyl, naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle, which comprises one to four heteroatoms from the group consisting of O, N and S, R 2 is alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or phenyl, naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle which comprises one to four heteroatoms from the group consisting of O, N and S, R 3 ,R 4 ,R 5 ,R 6 ,R 7 are hydrogen or one of the groups mentioned under R 2 , R 4 , together with R 3 or R 6 , may also form a five- or six-membered saturated or unsaturated ring which, in addition to carbon atoms, may comprise one to three further heteroatoms from the group consisting of O, N and S as ring members; R 2 with R 3 , R 4 with R 5 , R 6 with R 7 may in each case together, with formation of spiro groups, also form a C 2 -C 5 -alkylene, or alkenylene or alkynylene chain which may be interrupted by one to three heteroatoms from the group consisting of O, N and S; p is zero or 1; L is halogen, alkyl, haloalkyl, alkoxy, cyano, nitro, amino, alkylamino, dialkylamino, alkylcarbonylamino, C(O)-R, S(O) n -R; where n is zero, 1 or 2; R is hydrogen, alkyl, haloalkyl, alkoxy, alkenyloxy, alkynyloxy, amino, alkylamino, dialkylamino; m is 1, 2, 3, 4 or 5; X is halogen, cyano, alkyl, alkoxy, alkenyloxy, alkynyloxy or haloalkoxy; Y is oxygen or sulfur; Z is hydrogen, alkyl, haloalkyl, cycloalkyl, alkylcarbonyl, cycloalkylcarbonyl, alkenyl, haloalkenyl, cycloalkenyl, alkynyl, haloalkynyl, phenyl, naphthyl, a five- to ten-membered saturated, partially unsaturated or aromatic heterocycle which comprises one to four heteroatoms from the group consisting of O, N and S; or Z together with R 4 or R 6 may also form a five- or six-membered saturated or unsaturated ring which, in addition to carbon atoms and Y, may comprise one or two further heteroatoms from the group consisting of O, N and S as ring members the groups R 1 to R 7 , Z and R may be substituted according to the description; processes for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.
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公开(公告)号:CA2573929A1
公开(公告)日:2006-02-16
申请号:CA2573929
申请日:2005-07-28
Applicant: BASF AG
Inventor: SCHOEFL ULRICH , STIERL REINHARD , SCHERER MARIA , STRATHMANN SIEGFRIED , SCHIEWECK FRANK , SCHWOEGLER ANJA , NAVE BARBARA , SCHAEFER PETER , RHEINHEIMER JOACHIM , GROTE THOMAS , HUENGER UDO , MUELLER BERND , NIEDENBRUECK MATTHIAS , GRAMMENOS WASSILIOS , DIETZ JOCHEN , BLETTNER CARSTEN
IPC: A01N43/90 , A01N37/50 , A01N43/30 , A01N43/32 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/653 , A01N43/84 , A01N47/04 , A01N47/14 , A01N47/24 , A01N47/38 , A01N57/12 , A01N59/20
Abstract: Fungicidal mixtures, comprising as active components 1) a 5-chloro-6-phenyl-7-heterocyclylaminotriazolopyrimidine of the formula I, in which D together with the nitrogen atom forms a pyrrolidine, piperidine or azepine ring, which rings are unsubstituted or substituted by one or two methyl groups or by an ethyl, propyl or butyl group; and L is methyl, fluorine or chlorine; and 2) at least one active compound II selected from the following groups: A) azoles; B) strobilurins; C) acylalanines; D) amine derivatives; E) anilinopyrimidines; F) dicarboximides; G) cinnamides and analogs; H) antibiotics; K) dithiocarbamates; L) heterocyclic compounds according to the description; M) sulfur and copper fungicides; N) nitrophenyl derivatives; O) phenylpyrroles; P) sulfenic acid derivatives; Q) other fungicides according to the description; or R) growth retardants; in a synergistically effective amount, novel triazolopyrimidines, methods for controlling harmful fungi using compounds or mixtures of a compound I with an active compound of groups A) to R) and the use of the compounds I with the active compounds of groups A) to R) for preparing such mixtures, and also compositions comprising these compounds or mixtures.
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