公开(公告)号：DE59302410D1

公开(公告)日：1996-06-05

申请号：DE59302410

申请日：1993-02-15

Applicant: BASF AG

Inventor： KERSTING MEINOLF DR ,  KERTH JUERGEN DR ,  HUNGENBERG KLAUS-DIETER DR ,  MUELLER PATRIK DR ,  KOELLE PETER DR

IPC: C08F4/658 ,  C08F2/34 ,  C08F2/40 ,  C08F4/60 ,  C08F4/642 ,  C08F10/00 ,  C08F210/16 ,  C08F297/08 ,  D01F6/30

Abstract: >A process for the preparation of propylene-ethylene copolymers by two-step polymerisation from the gas phase in an agitated fixed bed by means of a Ziegler-Natta catalyst system which, in addition to a titanium-containing solids component, also contains, as cocatalyst, an aluminium compound, where the Ziegler-Natta catalyst system used is one which, after the reaction of the titanium-containing solids component with the cocatalyst, is deactivated by reaction with carbon dioxide.

公开(公告)号：AT129257T

公开(公告)日：1995-11-15

申请号：AT91109075

申请日：1991-06-04

Applicant: BASF AG

Inventor： SCHWAGER HARALD DR ,  KOELLE PETER DR ,  SCHLUND RUEGER DR ,  ZOLK RALF DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  HUNGENBERG KLAUS-DIETER DR ,  SCHOENE WERNER DR

IPC: C08F4/654 ,  C08F2/34 ,  C08F2/38 ,  C08F4/60 ,  C08F4/649 ,  C08F10/06 ,  C08F110/00 ,  C08F110/06 ,  C08L23/10 ,  C08L23/12

Abstract: Polymers of propylene having a molecular weight ratio Q (w/n) of from 6 to 30 are obtainable by Ziegler-Natta polymerisation in the presence of hydrogen as molecular weight regulator, and are particularly suitable for the production of films and mouldings.

公开(公告)号：DE4406963A1

公开(公告)日：1995-09-07

申请号：DE4406963

申请日：1994-03-03

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DR ,  FISCHER DAVID DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  BRINTZINGER HANS-HERBERT PROF ,  BARSTIES ELKE ,  ROELL WERNER DR

IPC: C07F7/00 ,  C07F7/08 ,  C07F7/10 ,  C07F7/22 ,  C07F7/30 ,  C07F9/72 ,  C07F9/90 ,  C07F17/00 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/642 ,  C08F4/659 ,  C08F4/68 ,  C08F10/00 ,  C07C13/28 ,  C07C23/18 ,  C08F4/76 ,  C08L23/02

公开(公告)号：ES2073083T3

公开(公告)日：1995-08-01

申请号：ES91115408

申请日：1991-09-12

Applicant: BASF AG

Inventor： SCHLUND RUEGER DR ,  HUNGENBERG KLAUS-DIETER DR ,  MUELLER MICHAEL WOLFGANG DR ,  KERTH JUERGEN DR ,  ZOLK RALF DR

IPC: C08F2/34 ,  C08F2/38 ,  C08F2/42 ,  C08F4/649 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

公开(公告)号：AT123500T

公开(公告)日：1995-06-15

申请号：AT91115408

申请日：1991-09-12

Applicant: BASF AG

Inventor： SCHLUND RUEGER DR ,  HUNGENBERG KLAUS-DIETER DR ,  MUELLER MICHAEL WOLFGANG DR ,  KERTH JUERGEN DR ,  ZOLK RALF DR

IPC: C08F2/34 ,  C08F2/38 ,  C08F2/42 ,  C08F4/649 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06

公开(公告)号：DE4206369A1

公开(公告)日：1993-09-02

申请号：DE4206369

申请日：1992-02-29

Applicant: BASF AG

Inventor： KERSTING MEINOLF DR ,  KERTH JUERGEN DR ,  HUNGENBERG KLAUS-DIETER DR ,  MUELLER PATRIK DR ,  KOELLE PETER DR

IPC: C08F4/658 ,  C08F2/34 ,  C08F2/40 ,  C08F4/60 ,  C08F4/642 ,  C08F10/00 ,  C08F210/16 ,  C08F297/08 ,  D01F6/30

Abstract: >A process for the preparation of propylene-ethylene copolymers by two-step polymerisation from the gas phase in an agitated fixed bed by means of a Ziegler-Natta catalyst system which, in addition to a titanium-containing solids component, also contains, as cocatalyst, an aluminium compound, where the Ziegler-Natta catalyst system used is one which, after the reaction of the titanium-containing solids component with the cocatalyst, is deactivated by reaction with carbon dioxide.

公开(公告)号：DE4128829A1

公开(公告)日：1993-03-04

申请号：DE4128829

申请日：1991-08-30

Applicant: BASF AG

Inventor： KERTH JUERGEN DR ,  HEMMERICH RAINER DR ,  KOELLE PETER DR ,  MUELLER PATRIK DR

IPC: C08F4/658 ,  C08F4/02 ,  C08F4/60 ,  C08F4/647 ,  C08F4/652 ,  C08F10/00 ,  C08F10/06

公开(公告)号：DE4027809A1

公开(公告)日：1992-03-05

申请号：DE4027809

申请日：1990-09-01

Applicant: BASF AG

Inventor： ZOLK RALF DR ,  KERTH JUERGEN DR ,  KOELLE PETER DR ,  SCHWAGER HARALD DR

IPC: C08F4/646 ,  C08F4/647 ,  C08F10/06 ,  C08L23/10

Abstract: System (I) is based on (A) Ti-contg. solid component contg. (A1) Ti-cpd. (A2) Mg cpd. of formula Mg(OR1)X R1 = 1-10C alkyl, 6-10 C aryl, or alkylaryl or 5-7 membered cycloalkyl, opt. contg. 1-4C alkyl gps. X = Cl or Br, (A3) halogen (A4) carboxylic acid derivs. (B) Al cpd. and opt. (C) other electron donor cpds. Also claimed are (i) prepn. of (I) by (1) suspending finely divided carrier material in (II) in liq. alkane at 10-120 deg.C. (2) treating suspension with 0.1-10 M soln. of (A2) in liq. alkane (3) adding to this mixt. after 30-120 minutes at 10-150 deg.C 0.2-5 mol halogen or hydrogen halide per mol. Mg of (A2) (4) after 60-300 minutes treating reaction prod. at 10-150 deg.C with per mol. Mg 0.1-5 mol 1-8C alkanol 1-20 mol halide or alcoholate of 3- or 4-valent Ti and 0.01-1 mol. (A4), (5) filtering off solid (I) and washing (I) with liq. alkane, and (ii) prepn. of polymers (III) of propylene (IV) by polymerisation at 20-150 deg.C and 1-100 bar using (I). USE/ADVANTAGE - Prodn. of (IV) homopolymers and copolymers with minor amts. of other 2-12C alpha, beta-unsatd. olefinic cpds. (I) have higher productivity and improved stereospecificity partic. in gas phase polymerisation, (III) have very small proportion of fines (less than 0.2mm) low Cl content, and good mechanical properties. (6pp Dwg.No.0/0)

公开(公告)号：DE4019053A1

公开(公告)日：1991-12-19

申请号：DE4019053

申请日：1990-06-15

Applicant: BASF AG

Inventor： SCHWAGER HARALD DR ,  KOELLE PETER DR ,  SCHLUND RUEGER DR ,  ZOLK RALF DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR

IPC: C08F4/654 ,  C08F2/34 ,  C08F2/38 ,  C08F4/60 ,  C08F4/649 ,  C08F10/06 ,  C08F110/00 ,  C08F110/06 ,  C08L23/10 ,  C08L23/12

Abstract: Polymers of propylene having a molecular weight ratio Q (w/n) of from 6 to 30 are obtainable by Ziegler-Natta polymerisation in the presence of hydrogen as molecular weight regulator, and are particularly suitable for the production of films and mouldings.

公开(公告)号：DE3863875D1

公开(公告)日：1991-08-29

申请号：DE3863875

申请日：1988-09-09

Applicant: BASF AG

Inventor： KERTH JUERGEN DR ,  ZOLK RALF DR ,  HEMMERICH RAINER DR

IPC: C08F4/58 ,  C08F4/60 ,  C08F4/64 ,  C08F4/658 ,  C08F10/00 ,  C08F10/06