Thermoplastic moulding materials
    24.
    发明专利

    公开(公告)号:AU1981200A

    公开(公告)日:2000-07-03

    申请号:AU1981200

    申请日:1999-12-16

    Applicant: BASF AG

    Abstract: Thermoplastic molding compositions comprising(A) 5 to 98%-wt., based on components (A) through (E), of at least one elastomeric graft copolymer,(B) 1 to 90%-wt., based on components (A) through (E), of a further copolymer,(C) 1 to 70%-wt., based on components (A) though (D), of an elastomeric block copolymer composed ofat least one block CA (hard phase) having copolymerized units of a vinylaromatic monomer, andat least one elastomeric block C(B/A) (soft phase) having copolymerized units of a vinylaromatic monomer, and of a diene,(D) 0 to 300%-wt., based on components (A) through (C), of a polycarbonate, and(E) 0 to 30%-wt., based on components (A) through (E), of conventional additives and processing aids,are useful for producing films, moldings or fibers.

    25.
    发明专利
    未知

    公开(公告)号:ES2140974T3

    公开(公告)日:2000-03-01

    申请号:ES97919315

    申请日:1997-04-03

    Applicant: BASF AG

    Abstract: Elastomeric block copolymers comprising at least one hard block A composed of styrene monomers and at least one elastomeric block (B/A) composed of styrene monomers and dienes, the glass transition temperature Tg of the block A being more than 25° C. and that of block (B/A) being less than 25° C. and the phase volume ratio of block A to block (B/A) being chosen so that the proportion of the hard phase in the total block copolymer is from 1 to 40% by volume and the amount by weight of the diene is less than 50% by weight, and the relative proportion of 1,2 linkages of the polydiene, based on the sum of 1,2- and 1,4-cis/trans linkages, being below 15%, are prepared by anionic polymerization by means of a lithium alkyl in a nonpolar solvent in the presence of a soluble potassium salt and are used for the production of shaped articles.

    27.
    发明专利
    未知

    公开(公告)号:DE59603291D1

    公开(公告)日:1999-11-11

    申请号:DE59603291

    申请日:1996-06-20

    Applicant: BASF AG

    Abstract: A molding material as based on from 60 to 98% by weight of a hard matrix A comprising polymerized or copolymerized units of at least one vinylaromatic monomer or at least one vinylaromatic monomer and at least one polar comonomer and from 2 to 40% by weight, the percentages in each case being based on the molding material comprising A and B, of a soft phase B formed from a hydrogenated or unhydrogenated block copolymer prepared by anionic polymerization and comprising a vinylaromatic monomer V and a diene D, having at least one random or quasi-random block (V/D) of vinylaromatic monomer and diene and containing from 10 to 80% by weight, based on the soft phase B, of occlusions of matrix material (a) formed during the polymerization of the hard matrix A in the presence of the block rubber, and said molding material is used for the production of films, sheets or moldings.

    Polymer mixtures comprised of styrene polymers

    公开(公告)号:AU3143399A

    公开(公告)日:1999-09-27

    申请号:AU3143399

    申请日:1999-03-03

    Applicant: BASF AG

    Abstract: Polymer mixtures compriseP1) from 1 to 85% by weight of an elastomeric block copolymer which has been built up from hard blocks S made from vinylaromatic monomers and from random soft blocks B/S made up from dienes and from vinylaromatic monomers, and which contains at least the block structure S-B/S-S, where the diene content is less than 50 percent by weight and the proportion of the soft phase formed from the blocks B/S is at least 60 percent by weight, based in each case on the entire block copolymer,P2) from 5 to 89% by weight of a block copolymer differing from P1) and made from vinylaromatic monomers and from dienes,P3) from 10 to 94% by weight of glass-clear or impact-modified polystyrene or mixtures thereof, andP4) from 0 to 84% by weight of other additives,where the total of components P1) to P4) is 100%.

    Elastomeric polymer mixture with good tearing resistance and stiffness for fiber, film and molded article

    公开(公告)号:DE19810141A1

    公开(公告)日:1999-09-16

    申请号:DE19810141

    申请日:1998-03-10

    Applicant: BASF AG

    Abstract: Polymer mixture includes elastomeric block copolymer with hard blocks S of vinyl aromatic monomers and statistical soft blocks B/S of dienes and vinyl aromatic monomers with a block structure(s) of S-B/S-S, whereby the diene content is at most 50 wt.% and the soft phase of B/S blocks comprises at least 60 wt.%. Polymer mixture comprises: (A) 1-85 wt.% elastomeric block copolymer with hard blocks S of vinyl aromatic monomers and statistical soft blocks B/S of dienes and vinyl aromatic monomers with a block structure(s) of S-B/S-S, whereby the diene content is at most 50 wt.% and the soft phase of B/S blocks comprises at least 60 wt.%; (B) 5-89 wt.% of a different block diene-vinyl aromatic monomers copolymer; (C) 10-94 wt.% transparent or impact polystyrene; and (D) 0-84 wt.% additives. An Independent claim is included for fibers, films and molded articles made from the above polymer mixture.

    30.
    发明专利
    未知

    公开(公告)号:BR9711401A

    公开(公告)日:1999-08-17

    申请号:BR9711401

    申请日:1997-09-09

    Applicant: BASF AG

    Abstract: Thermoplastic molding compositions comprisingA) a graft polymer comprising1) an elastomeric graft core, obtainable by copolymerization of one or more C1-C10-alkyl acrylates, and a monomer with crosslinking effect, and2) a graft shell comprising a styrene compound or a C1-C8-alkyl acrylate or methacrylate, or a mixture of the styrene compound and the C1-C8-alkyl acrylate or methacrylate, andB) a thermoplastic polymer comprisingC) an elastomeric block copolymer in which all or virtually all of the olefinic double bonds have been hydrogenated, comprising at least one block A, which forms a hard phase and contains, in its polymer chain, units of a vinylaromatic monomer, and/or a block B, which forms a first elastomeric (soft) phase and contains diene monomers, and at least one elastomeric block B/A, which forms a soft phase, and contains, randomly in its polymer chain, units of both a vinylaromatic monomer and a diene, where the glass transition temperature Tg of the block A is above 25° C. and that of the block B/A is below 25° C. and the phase-volume ratio of block A to block B/A is chosen so that the proportion of the hard phase in the entire block copolymer is from 1 to 40% by volume and the proportion by weight of the diene is less than 50% by weight.

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