公开(公告)号：DE102005053231A1

公开(公告)日：2007-05-10

申请号：DE102005053231

申请日：2005-11-06

Applicant: BASF AG

Inventor： NEUMANN DIRK ,  KOCH MICHAEL ,  SCHINDLER GOETZ-PETER ,  BENFER REGINA ,  KAIBEL GERD ,  WAGNER HANS-GUENTER ,  PAESLE PETER

IPC: C07C4/18 ,  B01J23/62 ,  C07C4/20 ,  C07C5/41 ,  C07C15/00

公开(公告)号：DE10150556A1

公开(公告)日：2003-04-17

申请号：DE10150556

申请日：2001-10-15

Applicant: BASF AG

Inventor： KOCH MICHAEL ,  SCHWAB EKKEHARD ,  TRUEBENBACH PETER ,  SCHAEFER HARALD

IPC: C10G65/16 ,  C07C5/03 ,  C10G45/08 ,  C10G45/38 ,  C07B31/00 ,  C07B35/02 ,  C07B35/06 ,  C07C5/02 ,  C07C9/00 ,  C10G45/00

公开(公告)号：AU1699002A

公开(公告)日：2002-05-21

申请号：AU1699002

申请日：2001-11-02

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS ,  KOCH MICHAEL ,  SCHULZ GERHARD ,  WEIGL HAGEN ,  MAAS STEFFEN

IPC: C07B61/00 ,  C07C29/141 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24 ,  C07C45/78 ,  C07C47/19

Abstract: In a process for the catalytic hydrogenation of a polymethylolalkanal or a monomethylolalkanal of the formula (I) where R may be identical or different and are each a substituted or unsubstituted aliphatic hydrocarbon having from 1 to 22 carbon atoms, an aryl or arylalkyl group having from 6 to 22 carbon atoms or a methylol group, in the presence of a copper-containing catalyst, the hydrogenation feed comprising the polymethylolalkanal or monomethylolalkanal has a total content of metal ions of groups 3 to 14 of the Periodic Table of the Element of up to 5 ppm.

公开(公告)号：DE19963442A1

公开(公告)日：2001-07-05

申请号：DE19963442

申请日：1999-12-28

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS ,  KRATZ DETLEF ,  STAMMER ACHIM ,  HAAKE MATHIAS ,  KOCH MICHAEL ,  SCHULZ GERHARD

IPC: C07B61/00 ,  C07C29/141 ,  C07C29/80 ,  C07C29/90 ,  C07C31/22 ,  C07C29/88 ,  C07C31/18

Abstract: The invention relates to a method, whereby the colour number of polyhydric alcohols, in particular, trihydroxymethylpropane, can be significantly improved by hydrogenation. The method is characterized in that an alcohol is used in the hydrogenation, which has been previously purified by distillation. The conventional catalysts for hydrogenation are used as catalysts, preferably copper, nickel, palladium or ruthenium.

公开(公告)号：DE102005053229A1

公开(公告)日：2007-05-10

申请号：DE102005053229

申请日：2005-11-06

Applicant: BASF AG

Inventor： NEUMANN DIRK ,  KOCH MICHAEL ,  SCHINDLER GOETZ-PETER ,  BENFER REGINA ,  KAIBEL GERD ,  WAGNER HANS-GUENTER

IPC: C07C4/18 ,  B01J23/46 ,  C07B35/06 ,  C07C4/20 ,  C07C15/00

公开(公告)号：BRPI0412987A

公开(公告)日：2006-10-03

申请号：BRPI0412987

申请日：2004-07-07

Applicant: BASF AG

Inventor： KOCH MICHAEL ,  WARTINI ALEXANDER ,  MAAS STEFFEN ,  SIRCH TILMAN ,  DERNBACH MATTHIAS

IPC: B01J21/06 ,  B01J23/46 ,  B01J35/00 ,  B01J35/10 ,  B01J37/06 ,  B01J37/14 ,  B01J37/18 ,  C07C29/88 ,  C07C29/38

Abstract: Removal of trialkylammonium formates (TAAF) from methylolalkanes obtained by condensation of formaldehyde with higher aldehydes involves decomposing the TAAF at elevated temperature on a titanium dioxide- supported ruthenium-containing catalyst in presence of a hydrogen-containing gas. An independent claim is also included for such a catalyst in which commercially-available titanium dioxide is treated before or after shaping to form the support with 0.1-30 wt.% of an acid in which the TiO 2 is difficultly soluble.

公开(公告)号：AT338740T

公开(公告)日：2006-09-15

申请号：AT02801897

申请日：2002-10-18

Applicant: BASF AG

Inventor： KOCH MICHAEL ,  WARTINI ALEXANDER ,  SIRCH TILMAN ,  DERNBACH MATTHIAS

IPC: C07C29/90 ,  C07C29/88 ,  C07C31/22

Abstract: A method for removing trialkyl ammonium formate from a methylol alkanes obtained by condensation of formaldehyde with a higher aldehyde. The invention is characterized in that trialkyl ammonium formate is decomposed at a high temperature using catalysts containing at least one metal from groups 8-12 of the classification of elements in the presence of gas containing hydrogen. The method makes it possible to separate trialkyl ammonium formate according to the organic Cannizzaro method and according to the hydrogenation method.

公开(公告)号：DE102004033557A1

公开(公告)日：2006-02-16

申请号：DE102004033557

申请日：2004-07-09

Applicant: BASF AG

Inventor： HAUNERT ANDREA ,  PINKOS ROLF ,  KRUG THOMAS ,  SIRCH TILMAN ,  KOCH MICHAEL ,  TEBBEN GERD-DIETER

IPC: C07C29/136 ,  C07C31/20

Abstract: The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).

公开(公告)号：CA2435918A1

公开(公告)日：2002-08-08

申请号：CA2435918

申请日：2002-01-29

Applicant: BASF AG

Inventor： STROEZEL MANFRED ,  PETERSEN HERMANN ,  MUELLER HANS-JOACHIM ,  KOCH MICHAEL ,  SCHREYER PETER ,  SCHWAB EKKEHARD ,  HAAKE MATHIAS

IPC: B01J21/18 ,  B01J23/44 ,  B01J32/00 ,  B01J35/02 ,  B01J35/06 ,  B01J35/10 ,  C07B35/02 ,  C07C29/17 ,  C07C51/487 ,  C07C63/26

Abstract: The invention relates to a method for cleaning crude terephthalic acid by means of catalytic, hydrogenating aftertreatment using a catalyst material containing at least one hydrogenation metal applied to a carbon carrier consisting of carbon fibres. The invention also relates to a catalyst consisting of the at least one catalyst material containing the at least one hydrogenation metal applied to the carbon fibres, the BET surface of the carbon carrier being

公开(公告)号：AT364587T

公开(公告)日：2007-07-15

申请号：AT01993593

申请日：2001-11-02

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS ,  KOCH MICHAEL ,  SCHULZ GERHARD ,  WEIGL HAGEN ,  MAAS STEFFEN

IPC: C07C29/141 ,  C07B61/00 ,  C07C31/20 ,  C07C31/22 ,  C07C31/24 ,  C07C45/78 ,  C07C47/19

Abstract: In a process for the catalytic hydrogenation of a polymethylolalkanal or a monomethylolalkanal of the formula (I) where R may be identical or different and are each a substituted or unsubstituted aliphatic hydrocarbon having from 1 to 22 carbon atoms, an aryl or arylalkyl group having from 6 to 22 carbon atoms or a methylol group, in the presence of a copper-containing catalyst, the hydrogenation feed comprising the polymethylolalkanal or monomethylolalkanal has a total content of metal ions of groups 3 to 14 of the Periodic Table of the Element of up to 5 ppm.