21.
    发明专利
    未知

    公开(公告)号:FI121121B

    公开(公告)日:2010-07-15

    申请号:FI973393

    申请日:1997-08-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00500 Sec. 371 Date Aug. 19, 1997 Sec. 102(e) Date Aug. 19, 1997 PCT Filed Feb. 7, 1996 PCT Pub. No. WO96/26318 PCT Pub. Date Aug. 29, 1997Aqueous alkyldiketene dispersions which contain a C14-C22-alkyldiketene and from 1 to 10% by weight of a polymeric protective colloid contain, as the protective colloid (a) copolymers of (1) N-vinylpyrrolidone and (2) at least one quaternized N-vinylimidazole or a substituted quaternized N-vinylimidazole as polymerized units in a molar ratio of from 80:20 to 5:95 and have a K value of at least 20 (according to H. Fikentscher in 0.5 M aqueous sodium chloride solution at a polymer concentration of 0.1% by weight and at 25 DEG C.) or (b) condensates which are obtainable by (1) partial amidation of polyethyleneimines with monocarboxylic acids and, if required (2) condensation of the partially amidated polyethyleneimines with at least bifunctional crosslinking agents which have a halohydrin, glycidyl, aziridine or isocyanate unit or a halogen atom as a functional group to give crosslinked, amidated polyethyleneimines which have a viscosity of at least 100 mPa.s in 20% strength by weight aqueous solution at 20 DEG C., or mixtures of (a) and (b) and are used as engine size in the production of paper, board and cardboard and for rendering cellulosic fibers water-repellent.

    Modifying starch with cationic polymers and use of the modified starches as dry-strength agent

    公开(公告)号:NZ514892A

    公开(公告)日:2003-08-29

    申请号:NZ51489200

    申请日:2000-03-23

    Applicant: BASF AG

    Abstract: A method for modifying starch by heating the starch in an aqueous medium to temperatures greater than the pasting temperature of the starch in the presence of (a) a polymer cationization agent selected from the group consisting of polymers with molecular weights up to 1 million containing vinylamine units, polyethylene imines, polydiallyldimethylammonium chlorides, condensates of dimethylamine with epichlorohydrin or dichloroalkanes, condensates of dichloroethane and ammonia and mixtures of the above mentioned compounds, and (b) polymer dehydrators for paper selected from the group consisting of water-soluble, crosslinked polyamidoamines that are optionally grafted with ethylene imine, polymers with molecular weights of greater than 1 million containing acrylamide and/or methacrylamide units, polymers with molecular weights of greater than 1 million containing vinylamine units and mixtures of said compounds. Also disclosed are reaction products obtained by the inventive method and the use of the reaction products as dry-strength agents in the production of paper, board and paperboard.

    27.
    发明专利
    未知

    公开(公告)号:AT221594T

    公开(公告)日:2002-08-15

    申请号:AT96937229

    申请日:1996-10-25

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/04638 Sec. 371 Date May 4, 1998 Sec. 102(e) Date May 4, 1998 PCT Filed Oct. 25, 1996 PCT Pub. No. WO97/17491 PCT Pub. Date May 15, 1997Aqueous alkyldiketene dispersions comprising an alkyldiketene, cationic starch having an amylopectic content of at least 95% by weight and as anionic dispersants (a) from 0.05 to 1.0% by weight of ligninsulfonic acid, condensates of naphthalenesulfonic acid and formaldehyde, sulfonated polystyrene, salts and mixtures of said polymers and (b) from 0.05 to 1.5% by weight of sulfuric monoesters of alcohols having at least 10 carbon atoms, phosphoric monoesters or diesters of alcohols having at least 10 carbon atoms, sulfuric monoesters of alkoxylated alcohols having at least 10 carbon atoms, phosphoric monoesters or diesters of alkoxylated alcohols having at least 10 carbon atoms, C12-C30-alkylsulfonic acids, salts and mixtures of said compounds can be used as body size in the manufacture of paper, paperboard and cardboard and for making cellulose fibers hydrophobic.

    29.
    发明专利
    未知

    公开(公告)号:ES2153587T3

    公开(公告)日:2001-03-01

    申请号:ES96925686

    申请日:1996-07-09

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/02991 Sec. 371 Date Jan. 21, 1998 Sec. 102(e) Date Jan. 21, 1998 PCT Filed Jul. 9, 1996 PCT Pub. No. WO97/04014 PCT Pub. Date Feb. 6, 1997Graft polymers are obtainable by free radical polymerization of (A) monomers or monomer mixtures comprising (a) from 1 to 100% by weight of N-vinylcarboxamides of the formula where R1 and R2 are each H or C1-C6-alkyl, (b) from 0 to 99% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule, in the presence of (B) polymers which contain units of vinyl esters of saturated C1-C4-carboxylic acids and/or vinyl alcohol units, or of mixtures which contain these polymers and polymers having at least 3 alkylene oxide units or polytetrahydrofuran, in a weight ratio (A):(B) of from 95:5 to 10:90 and, if required, subsequent elimination of the group from the polymerized monomers (I) of the graft polymer with formation of units of the formula and the graft polymers described above are used in the production of paper, board and cardboard as dry and wet strength agents, as retention and drainage aids and as promoters in diketene sizing and as starch cationization agents, as dispersants for pigments and as creping assistants in the production of tissue papers.

    30.
    发明专利
    未知

    公开(公告)号:AT198605T

    公开(公告)日:2001-01-15

    申请号:AT96925686

    申请日:1996-07-09

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/02991 Sec. 371 Date Jan. 21, 1998 Sec. 102(e) Date Jan. 21, 1998 PCT Filed Jul. 9, 1996 PCT Pub. No. WO97/04014 PCT Pub. Date Feb. 6, 1997Graft polymers are obtainable by free radical polymerization of (A) monomers or monomer mixtures comprising (a) from 1 to 100% by weight of N-vinylcarboxamides of the formula where R1 and R2 are each H or C1-C6-alkyl, (b) from 0 to 99% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule, in the presence of (B) polymers which contain units of vinyl esters of saturated C1-C4-carboxylic acids and/or vinyl alcohol units, or of mixtures which contain these polymers and polymers having at least 3 alkylene oxide units or polytetrahydrofuran, in a weight ratio (A):(B) of from 95:5 to 10:90 and, if required, subsequent elimination of the group from the polymerized monomers (I) of the graft polymer with formation of units of the formula and the graft polymers described above are used in the production of paper, board and cardboard as dry and wet strength agents, as retention and drainage aids and as promoters in diketene sizing and as starch cationization agents, as dispersants for pigments and as creping assistants in the production of tissue papers.

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