公开(公告)号：DE10148511A1

公开(公告)日：2003-04-10

申请号：DE10148511

申请日：2001-10-01

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F2/38 ,  C08F212/08 ,  C08F220/04 ,  C08F220/44 ,  C08F236/06 ,  C08F236/10 ,  C09D5/02 ,  C09D109/06 ,  C09D109/08 ,  C09D125/10 ,  D21H19/58

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by means of radical aqueous emulsion polymerisation of a monomer mixture M containing styrene, butadiene, and optionally up to 30 wt. %, in relation to 100 wt. % of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene. The reaction is carried out in a polymerisation vessel according to a monomer supply method, in the presence of a regulator system comprising, in relation to 100 wt. % of monomers, between 0.02 and 0.5 wt. % of at least one hydrocarbon KW having between 6 and 20 C atoms and being selected from compounds forming a pentadienyl radical or a 1-phenylallyl radical by means of abstraction of a hydrocarbon atom, an alpha -methylstyrene dimer, and between 0.3 and 2 wt. % of an organic compound S with at least one SH group. The inventive method is characterised in that at least 30 %, preferably at least 50 %, especially at least 80 %, and ideally the entire amount (or more than 95 %) of the hydrocarbon KW is present in the polymerisation vessel.

公开(公告)号：CA2461948C

公开(公告)日：2011-03-15

申请号：CA2461948

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F212/08 ,  C08F2/38 ,  C08F220/04 ,  C08F220/44 ,  C08F236/06 ,  C08F236/10 ,  C08F291/00 ,  C09D5/02 ,  C09D109/06 ,  C09D109/08 ,  C09D125/10 ,  D21H17/35 ,  D21H19/58

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by means of radical aqueous emulsion polymerisation of a monomer mixture M containing styrene, butadiene, and optionally up to 30 wt. %, in relation to 100 wt. % of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene. The reaction is carried out in a polymerisation vessel according to a monomer supply method, in the presence of a regulator system comprising, in relation to 100 wt. % of monomers, between 0.02 and 0.5 wt. % of at least one hydrocarbon KW having between 6 and 20 C atoms and being selected from compounds forming a pentadienyl radical or a 1-phenylallyl radical by means of abstraction of a hydrocarbon atom, an .alpha.-methylstyrene dimer, and between 0.3 and 2 wt. % of an organic compound S with at least one SH group. The inventive method is characterised in that at least 30 %, preferably at least 50 %, especially at least 80 %, and ideally the entire amount (or more than 95 %) of the hydrocarbon KW is present in the polymerisation vessel.

公开(公告)号：CA2461672C

公开(公告)日：2011-03-15

申请号：CA2461672

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  KROENER HUBERTUS

IPC: C08F212/08 ,  C08F2/38 ,  C08F236/06

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by carrying out a radical aqueous emulsion polymerization of a monomer mixture M containing: 40 to 80 wt. % of styrene depicted as Monomer M1; 20 to 60 wt. % of butadiene depicted as monomer M2, and; 0 to 40 wt. %, with regard to 100 wt. % of the monomers, of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene. The polymerization is carried out according to a monomer feeding method in the presence of 0.05 to 0.5 wt. %, with regard to 100 wt. % of the monomers, of at least one hydrocarbon KW selected among compounds having 6 to 20 C atoms that form a pentadienyl radical or a 1-phenylallyl radical when a hydrogen atom is abstracted, and the .alpha.-methylstyrene dimer. The inventive method is characterized in that the monomers to be polymerized are introduced within three hours of the polymerization reaction.

公开(公告)号：CA2357510C

公开(公告)日：2010-04-06

申请号：CA2357510

申请日：2001-09-20

Applicant: BASF AG

Inventor： SCHADLER VOLKER ,  MANDERS LAMBERTUS ,  ETTL ROLAND ,  WIRTH THOMAS

IPC: C08F212/08 ,  C08F2/22 ,  C08F2/38 ,  C08F212/10 ,  C08F236/10 ,  D21H17/35 ,  D21H19/36 ,  D21H19/58

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising - styrene, - butadiene, and if desired - up to 30% by weight, per 100% by weight of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene; by a monomer feed technique, said process comprising supplying to the polymerization reaction in the course thereof a regulator system comprising, based on 100% by weight of monomers, - from 0.02 to 0.4% by weight of terpinolene and - from 0.5 to 2% by weight of an organic compound S containing at least one SH group.

公开(公告)号：AT327266T

公开(公告)日：2006-06-15

申请号：AT02777269

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  KROENER HUBERTUS

IPC: C08F2/38 ,  C08F212/08 ,  C08F236/06

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC selected from compounds having 6 to 20 carbon atoms which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from alpha-methylstyrene dimer comprises supplying the monomers to be polymerized to the polymerization reaction over the course of 3 hours.

公开(公告)号：DE50012666D1

公开(公告)日：2006-06-01

申请号：DE50012666

申请日：2000-10-18

Applicant: BASF AG

Inventor： KRISTEN OLIVER ,  MANDERS LAMBERTUS ,  MECKING STEFAN ,  BAUERS M ,  MUELHAUPT ROLF

IPC: A61K47/32 ,  C08F10/02 ,  C08F2/22 ,  C08F4/60 ,  C08F4/70 ,  C08F4/72 ,  C08F4/80 ,  C08F10/00 ,  C09D5/00 ,  C09D123/04 ,  C09J123/04 ,  D06N7/00 ,  D21H19/22 ,  D21H21/16

公开(公告)号：CA2461947A1

公开(公告)日：2003-04-10

申请号：CA2461947

申请日：2002-09-30

Applicant: BASF AG

Inventor： SCHAEDLER VOLKER ,  GASCHLER WOLFGANG ,  MANDERS LAMBERTUS ,  KROENER HUBERTUS ,  WIRTH THOMAS

IPC: C08F2/22 ,  C08F2/38 ,  C08F212/00 ,  C08F212/08 ,  C08F236/00 ,  C08F236/10 ,  C08F291/00 ,  C08F236/06

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by the radical aqueous emulsion-polymerisation of a monom er mixture M, containing: between 40 and 80 wt. % styrene as monomer M1; betwee n 20 and 60 wt. % butadiene as monomer M2 and between 0 and 40 wt. %, (in relation to l00 wt. % monomers), of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene, according to a monomer feed process in the presence of between 0.05 and 0.5 wt. %, (in relation to l00 wt. % monomers), of at least one hydrocarbon KW comprising between 6 and 20 C atom s, selected from compounds, which form a pentadienyl or a 1-phenylallyl radical during the abstraction of a hydrogen atom, or from .alpha.-methylstyrene dimers. Said method is characterised in that at least 30 % of the hydrocarbo n KW is already present in the polymerisation vessel and the residual quantity of the hydrocarbon KW is fed to the polymerisation reaction during the cours e of the latter.

公开(公告)号：CA2461672A1

公开(公告)日：2003-04-10

申请号：CA2461672

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  KROENER HUBERTUS

IPC: C08F2/38 ,  C08F212/08 ,  C08F236/06

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by carrying out a radical aqueous emulsion polymerization of a monomer mixture M containing: 40 to 80 wt. % of styrene depicted as Monomer M1; 20 to 60 wt. % of butadiene depicted as monomer M2, and; 0 to 40 wt. %, with regard to 100 wt. % of the monomers, of ethylenically unsaturate d comonomers M3 that differ from styrene and butadiene. The polymerization is carried out according to a monomer feeding method in the presence of 0.05 to 0.5 wt. %, with regard to 100 wt. % of the monomers, of at least one hydrocarbon KW selected among compounds having 6 to 20 C atoms that form a pentadienyl radical or a 1-phenylallyl radical when a hydrogen atom is abstracted, and the .alpha.-methylstyrene dimer. The inventive method is characterized in that the monomers to be polymerized are introduced within three hours of the polymerization reaction.

公开(公告)号：AU2002338296A1

公开(公告)日：2002-10-28

申请号：AU2002338296

申请日：2002-04-06

Applicant: BASF AG

Inventor： CHOWDHRY MUBARIK MAHMOOD ,  SCHMID MARKUS ,  KRISTEN MARC OLIVER ,  MANDERS LAMBERTUS

IPC: C08F2/16 ,  C08F2/24 ,  C08F4/60 ,  C08F4/69 ,  C08F4/70 ,  C08F4/78 ,  C08F4/80 ,  C08F10/02 ,  C08F110/02 ,  C08F10/00

公开(公告)号：CA2461947C

公开(公告)日：2011-05-24

申请号：CA2461947

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F2/22 ,  C08F212/08 ,  C08F2/38 ,  C08F212/00 ,  C08F236/00 ,  C08F236/06 ,  C08F236/10 ,  C08F291/00

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by the radical aqueous emulsion-polymerisation of a monomer mixture M, containing: between 40 and 80 wt. % styrene as monomer M1; between 20 and 60 wt. % butadiene as monomer M2 and between 0 and 40 wt. %, (in relation to l00 wt. % monomers), of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene, according to a monomer feed process in the presence of between 0.05 and 0.5 wt. %, (in relation to l00 wt. % monomers), of at least one hydrocarbon KW comprising between 6 and 20 C atoms, selected from compounds, which form a pentadienyl or a 1-phenylallyl radical during the abstraction of a hydrogen atom, or from .alpha.-methylstyrene dimers. Said method is characterised in that at least 30 % of the hydrocarbon KW is already present in the polymerisation vessel and the residual quantity of the hydrocarbon KW is fed to the polymerisation reaction during the course of the latter.