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公开(公告)号:DE50100259D1
公开(公告)日:2003-06-26
申请号:DE50100259
申请日:2001-02-12
Applicant: BASF AG
Inventor: DISTELDORF WALTER DR , PETERS JARREN DR , MORSBACH BERND , KUMMER MATTHIAS DR , RUEHL THOMAS DR
IPC: B01D3/14 , C07C51/573 , C07C63/00 , C07C63/16
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公开(公告)号:DE59610115D1
公开(公告)日:2003-03-13
申请号:DE59610115
申请日:1996-11-02
Applicant: DAIMLER CHRYSLER AG , BASF AG
Inventor: HARTWEG DR , ROITZHEIM DR , SEIBOLD ANDREA , WALZ DR , FETZER DR , MORSBACH BERND
IPC: B01D53/86 , B01D53/94 , B01J23/00 , B01J23/72 , B01J23/76 , B01J23/80 , B01J23/84 , B01J23/847 , B01J23/85 , B01J23/89 , B01J35/04 , F01N3/035 , F01N3/08 , F01N3/20 , F01N13/02
Abstract: The operation of a purification apparatus for flowing gases comprises passing the gas stream through a filter body having a catalyst, a reducing agent being added to the gas before entering the catalyst. The flow direction (1) of the gas according to the treating stretch in the catalyst of the filter body (2), reducing agent added to the flowing gas, and contact with the catalyst of the filter body (2) are maintained. Also claimed is the purification apparatus comprising a feed device for the reducing agent, which is added to the gas while flowing through the filter body (2).
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公开(公告)号:AU2002244704A1
公开(公告)日:2002-08-28
申请号:AU2002244704
申请日:2002-02-06
Applicant: BASF AG
Inventor: RUHL THOMAS , KUMMER MATTHIAS , PETERS JARREN , DISTELDORF WALTER , MORSBACH BERND
IPC: C07D307/89 , B01D3/14 , C07C51/44 , C07C51/573 , C07C63/16
Abstract: The invention relates to a method for the production of phthalic anhydride to a specification, using a distillative purification of crude phthalic anhydride, by introduction of crude phthalic anhydride into a distillation column, operating at reduced pressure, withdrawal of the low-boiling fraction from the head, or near the head of the column and withdrawal of the phthalic anhydride, which meets the specification, from a side-tap on the column, whilst operating the column at a reflux ratio x, with 1:1.7
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公开(公告)号:CA2428575A1
公开(公告)日:2002-05-16
申请号:CA2428575
申请日:2001-11-13
Applicant: BASF AG
Inventor: DISTELDORF WALTER , SCHWIRTEN KURT , MORSBACH BERND , GOLFIER GUNTHER
Abstract: The invention relates to a method for producing esters of an acid component chosen from the multibasic C4-C10-carboxylic acids and an alcohol component chosen from C3-C12-alkanols or -alkanediols whose alkyl chain can be interrupted by 1 to 3 oxygen atoms. Sad method comprises the following steps: a) a mixture consisting essentially of the acid component or an anhydride thereof and the alcohol component is heated to boiling in a reaction zone in the presence of an esterification catalyst; b) the vapours containing alcohol and water are separated into a fragment that is rich in alcohol and a fragment that is rich in water by rectification; and c) the alcohol-rich fraction is fed back into the reaction zone, while the water-rich fraction is extracted from the process. The inventive method is simple to carry out and allows the rapid adjustment of an essentially quantitative conversion.
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公开(公告)号:ES2159896T3
公开(公告)日:2001-10-16
申请号:ES97954415
申请日:1997-12-17
Applicant: BASF AG , DAIMLER CHRYSLER AG
Inventor: FETZER THOMAS , MORSBACH BERND , KUMBERGER OTTO , HARTWEG MARTIN , ROITZHEIM ROLF-DIRC , SEIBOLD ANDREA
Abstract: PCT No. PCT/EP97/07091 Sec. 371 Date Jun. 16, 1999 Sec. 102(e) Date Jun. 16, 1999 PCT Filed Dec. 17, 1997 PCT Pub. No. WO98/26858 PCT Pub. Date Jun. 25, 1998A process for the catalytic reduction of NOx, the reduction taking place in the presence of a catalyst which comprises (a) from 20 to 97 wt % of A2O3, (b) from 1 to 40 wt % of CuO, (c) from 1 to 50 wt % of ZnO, (d) from 1 to 40 wt % of Ag, (e) from 0 to 2 wt % of Pt, (f) from 0 to 20 wt % of oxides of rare earth metals, elements of the 3rd subgroup of the Periodic Table of the Elements or mixtures thereof, based on the total weight of the components (a) to (e), which adds up to 100 wt %, wherein, in each case, up to half the weight of the component (a) may be replaced by Fe2O3, Cr2O3, Ga2O3 or mixtures thereof, of the component (b) by CoO, of the component (c) by MgO, of the component (d) by Au and of the component (e) by Pd, Ru, Os, Ir, Rh, Re or mixtures thereof, is used for reducing NOx, especially in combustion off-gases, the components (a), (b) and (c) forming a spinel which is doped with the components (d), (e) and (f).
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公开(公告)号:DE19924339A1
公开(公告)日:2000-11-30
申请号:DE19924339
申请日:1999-05-27
Applicant: BASF AG
Inventor: THIL LUCIEN , BREITSCHEIDEL BORIS , DISTELDORF WALTER , DORNIK KNUT , MORSBACH BERND
Abstract: New mixtures (I) of dicarboxylic acid diesters with isomeric nonanols consist of adipate or phthalate diester mixtures having 1H-NMR spectra (obtained in CDCl3) with specific ratios of surface areas below the resonance signals for particular chemical shifts towards TMS. The ratio of the surface area for shifts of 1.0-2.0 ppm to that for shifts of 0.5-1.0 ppm is 1.20-5.00 for the adipate diesters; and the ratio of the surface area for shifts of 1.1-3.0 ppm to that for shifts of 0.5-1.1 ppm is 1.00-4.00 for the phthalate diesters; An Independent claim is included for mixtures (II) of isomeric nonanols which either: (i) form (I) as defined above on esterification with adipic or phthalic acid; or (ii) are obtained by hydroformylation of a mixture of isomeric octenes in presence of a cobalt catalyst and hydrogenation of the product, where the isomeric octene mixture is obtained by contacting a hydrocarbon mixture containing butenes with a heterogeneous catalyst containing a nickel oxide.
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公开(公告)号:DE19918051A1
公开(公告)日:2000-10-26
申请号:DE19918051
申请日:1999-04-21
Applicant: BASF AG
Inventor: THIL LUCIEN , BREITSCHEIDEL BORIS , DISTELDORF WALTER , ZELLER EDGAR , WALTER MARC , MORSBACH BERND
Abstract: New mixtures (I) of dicarboxylic acid diesters with isomeric nonanols consist of adipate or phthalate diester mixtures having 1H-NMR spectra (obtained in CDCl3) with specific ratios of surface areas below the resonance signals for particular chemical shifts towards TMS. The ratio of the surface area for shifts of 1.0-2.0 ppm to that for shifts of 0.5-1.0 ppm is 1.20-5.00 for the adipate diesters; and the ratio of the surface area for shifts of 1.1-3.0 ppm to that for shifts of 0.5-1.1 ppm is 1.00-4.00 for the phthalate diesters; An Independent claim is included for mixtures (II) of isomeric nonanols which either: (i) form (I) as defined above on esterification with adipic or phthalic acid; or (ii) are obtained by hydroformylation of a mixture of isomeric octenes in presence of a cobalt catalyst and hydrogenation of the product, where the isomeric octene mixture is obtained by contacting a hydrocarbon mixture containing butenes with a heterogeneous catalyst containing a nickel oxide.
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公开(公告)号:CZ9904445A3
公开(公告)日:2000-06-14
申请号:CZ444599
申请日:1998-05-30
Applicant: DAIMLER CHRYSLER AG , BASF AG
Inventor: HARTWEG MARTIN , FERZER THOMAS , MORSBACH BERND , KUMBERGER OTTO
CPC classification number: F01N3/0842 , B01D53/9422 , B01D2255/1023 , B01D2255/2042 , B01D2255/2047 , B01D2255/20707 , B01D2255/20723 , B01D2255/20761 , B01D2255/20776 , B01D2255/2092 , B01D2255/50 , B01D2255/91 , B01J23/005 , B01J23/80 , F01N3/0814 , Y10S502/524
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公开(公告)号:CZ444599A3
公开(公告)日:2000-06-14
申请号:CZ444599
申请日:1998-05-30
Applicant: DAIMLER CHRYSLER AG , BASF AG
Inventor: HARTWEG MARTIN , FERZER THOMAS , MORSBACH BERND , KUMBERGER OTTO
Abstract: A storage catalyst includes (1) a component that has a catalytic reducing action for nitrogen oxides at least in the presence of hydrocarbons, and (2) a component that stores NOx at least at temperatures of below 100° C. The catalytically active component is of the general chemical formula AaBbO4, where A is one or more divalent metals and B is one or more trivalent metals, and where a+b 0. The reaction enthalpy or the chemical activity between the catalytically active component and the NOx-storing component is low at least up to temperatures of 600° C.
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公开(公告)号:CZ168898A3
公开(公告)日:1998-11-11
申请号:CZ168898
申请日:1996-12-11
Applicant: BASF AG
Inventor: FETZER THOMAS , MORSBACH BERND , HARTWEG MARTIN , ROITZHEIM RALF-DIRC , SEIBOLD ANDREA , WALZ LEONHARD
Abstract: PCT No. PCT/EP96/05532 Sec. 371 Date Jun. 2, 1998 Sec. 102(e) Date Jun. 2, 1998 PCT Filed Dec. 11, 1996 PCT Pub. No. WO97/21482 PCT Pub. Date Jun. 19, 1997NOx, where x is 1 and 2, in exhaust gases is reduced over heterogeneous catalysts with hydrocarbons, carbon monoxide, hydrogen or mixtures thereof in the presence of oxygen from 100 to 650 DEG C. and an absolute pressure of from 0.5 to 50 bar by a process in which the heterogeneous catalysts used are bimodal or polymodal compounds of the general formula IA1-xM2O4(I),which, if required, are doped with rare earth metals, noble metal, titanium, vanadium, molybdenum, tungsten or mixtures thereof, and where A is magnesium, calcium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, tin or mixtures thereof, M is aluminum, gallium, indium, tin, chromium, manganese, iron, cobalt, nickel, copper, zinc or mixtures thereof and x is from 0 to 0.99, whose oxygen atoms are in a cubic close packed arrangement and A is present in the tetrahedral sites and M in the octahedral sites, it also being possible for A to occupy octahedral sites if an equivalent amount of M occupies tetrahedral sites.
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