New phenyl carbamate derivatives
    22.
    发明专利

    公开(公告)号:DE19745650A1

    公开(公告)日:1999-04-22

    申请号:DE19745650

    申请日:1997-10-16

    Applicant: BASF AG

    Abstract: Substituted oxy- or oxymethylenephenyl-oxazolidine and -oxazolidinedione derivatives (I) are new. They are prepared from new activated phenyl-oxazolidine derivatives (IIA) and activated phenyl-oxazolidinedione derivatives (IVB), which in turn are obtained via new substituted nitrobenzene and aniline derivatives (1), phenyl isocyanates (2) and substituted anilides (3). Substituted oxy- or oxymethylenephenyl-oxazolidine and -oxazolidinedione derivatives (I) are new: Y = halo; 1-4C alkyl; 1-4C haloalkyl; or 1-4C alkoxy; n = 0-2; E = group of formula (a) or (b): Ra = halo; CN; 1-4C alkyl or 1-4C alkoxy optionally substituted by halo; 3-6C alkenyloxy, 3-6C alkynyloxy; 3-6C cycloalkyl; S(O)m-1-4C alkyl; or NRaRb; m = 0-2; Ra and Rb = H; 1-4C alkyl; 3-6C alkenyl; or 3-6C alkynyl; Rb = 1-4C alkyl; 1-4C haloalkyl; 3-6C cycloalkyl; or optionally substituted arylmethylene; T = O or oxymethylene; Z' = X; N=CWR ; or N=C(R )-C(R )=NOR ; X = optionally substituted heterocyclyl, aryl, heteroaryl, arylmethylene or heteroarylmethylene; W = optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl or heteroaryl; R = H; CN; 1-4C alkyl; 1-4C haloalkyl; 1-4C alkoxy; 1-4C alkoxy-1-4C alkyl; or 3-6C cycloalkyl; R = H; CN; halo; C(Rd)=NOR3; W; OW; SW or NRcW; Rc = H; alk yl; alkenyl; or alkynyl; Rd = H or alkyl; R = H; or optionally substituted alkyl, alkenyl or alkynyl. Independent claims are also included for: (A) activated phenyl-oxazolidine derivatives of formula (IIA); (B) activated phenyl-oxazolidinedione derivatives of formula (IVB); (C) substituted nitrobenzene and aniline derivatives of formula (1); (D) phenyl isocyanates of formula (2); and (E) Substituted anilides (3). L = OH; CH3; CH2L'; or L'; L' = nucleophilic leaving group; La = CH3; CH2L'; NO2; alkylsulphonate; or arylsulphonate; Q = NH2 or NO2; T' = OZ'; CH2O-X; or CH2O-N=C(R )-C(R )=NOR ; Z' = N=CWR or N=C(R )-C(R )=NOR ; E asterisk = NH-C(O)-NH-OH; NH-C(O)-O-NH-C(O)-OR; NH-C(S)-R'; or NH-C(NOH)-R'; R = 1-4C alkyl; R' = 1-4C alkyl; 1-4C haloalkyl; or 3-6C cycloalkyl.

    New and known substd. alkylthio-pyridine derivs.

    公开(公告)号:DE19531148A1

    公开(公告)日:1997-02-27

    申请号:DE19531148

    申请日:1995-08-24

    Applicant: BASF AG

    Abstract: Control of fungi using substd. alkylthio-pyridine derivs. (I) and their salts and N-oxides is claimed. R -R = H, CN, NO2 or halo; 1-4C alkyl or 1-4C alkoxy (both opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkoxy-CO or Ar; Ar = aryl, aryloxy or heteroaryl (all opt. ring substd. by 1-3 of halo, CN or NO2; 1-4C alkyl or 1-4C alkoxy (both opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkoxy-CO or 1-4C acyl); m = 0-2; Alk = 1,2-ethylene or 1,3-propylene having any H atom opt. replaced by: (a) alkyl, haloalkyl, alkenyl, haloalkenyl or alkynyl (all having up to 8C and opt. substd. by 1-3 of CN, 1-4C alkoxy (opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxycarbonyl, 3-7C cycloalkyl or 5-7C cycloalkenyl); or (b) 3-7C cycloalkyl or 5-7C cycloalkenyl (both opt. substd. by 1 or more halo or opt. substd. by 1-3 of CN, halo, 1-4C alkyl (opt. substd. by halo) or 1-4C alkoxy); X = O, S or NR ; R = H, 1-8C alkyl or 3-7C cycloalkyl; R = (a) aryl, heteroaryl or aryl-1-4C alkyl (all opt. ring substd. by 1-3 of CN, NO2, halo, 1-4C alkyl or 1-4C alkoxy (opt. substd. by halo), 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkoxy-CO, 1-4C alkylsulphinyl, 1-4C alkylsulphonyl, 1-4C acyl or Ar); or (b) 3-7C cycloalkyl or 5-7C cycloalkenyl (both opt. substd. by 1 or more halo or opt. substd. by 1-3 of CN, halo, 1-4C alkyl or 1-4C alkoxy (opt. substd. by halo), 1-4C alkoxy-1-4C alkyl, 1-4C alkylthio, 1-4C alkoxy-carbonyl, 3-7C cycloalkyl, 5-7C cycloalkenyl or Ar).

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