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公开(公告)号：KR101766451B1
公开(公告)日：2017-08-08
申请号：KR1020150187210
申请日：2015-12-28
Applicant: 한국에너지기술연구원
IPC: B01J37/00 , B01J35/02 , B01J35/10 , B01J23/75 , B01J23/745 , B01J23/755 , B01J32/00 , B01J35/08
Abstract: 본발명은시트(sheet) 형태의다공성메탈폼 구조체의기공에일정한형상으로가공된촉매를가압수단으로압착하여충전시켜단위다공성메탈폼 하우징촉매구조체를제조하고, 이를적층하거나말아서롤 형태로제조하는다공성메탈폼 하우징촉매구조체의제조방법및 상기방법으로제조된다공성메탈폼 하우징촉매구조체에관한발명이다. 본발명에따른다공성메탈폼 하우징촉매구조체의기공에는상기촉매표면의일부가상기다공성메탈폼 구조체와직접접촉할수 있는상태로충전되어발열및 흡열반응시에도촉매의탈리없이안정적이고높은반응성을가지는장점이있다.
Abstract translation: 本发明中，其通过填充和压制以恒定的形状，以在片材（片材）的研磨的催化剂的多孔金属泡沫结构的形式，所述孔作为加压装置产生单元多孔金属泡沫壳体中的催化剂结构和层叠或辊以辊的形式制备它 本发明涉及一种制造多孔金属泡沫塑料外壳催化剂结构的方法和一种通过上述方法生产的多孔金属泡沫塑料外壳催化剂结构。 优点部分被充电到一个状态，其中它可以与多孔金属泡沫结构中直接接触稳定，高度反应性的，而不会在多孔金属泡沫壳体的孔中的催化剂表面上的发热和吸热反应，根据本发明的催化剂结构，即使当催化剂的解吸 有。
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公开(公告)号：KR101541599B1
公开(公告)日：2015-08-04
申请号：KR1020130113585
申请日：2013-09-25
Applicant: 한국에너지기술연구원
CPC classification number: Y02E10/542 , Y02P70/521
Abstract: 본발명은전해질수용액의염료감응태양전지및 이의제조방법을개시한다. 본발명에따르는전해질수용액의염료감응태양전지및 이의제조방법에의하면, 살리실릭기를가진염료가결합된광전극의음극계전극을준비하는단계와, 상기음극계전극에전해질수용액을도포하는단계및 백금상대전극의양극계전극을준비하여상기음극계전극과대향하고밀봉하는단계를포함하는것을특징으로하는데, 이에의할때, 전해질수용액에서용해되지아니하여내구성이우수하고, 물과친화적이어서친환경적이며, 외부에서침투하는수분에안정적이고, 특히장기안정성이우수하다.
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公开(公告)号：KR1020150034835A
公开(公告)日：2015-04-06
申请号：KR1020130113585
申请日：2013-09-25
Applicant: 한국에너지기술연구원
CPC classification number: Y02E10/542 , Y02P70/521 , H01L31/18 , H01L31/04
Abstract: 본발명은전해질수용액의염료감응태양전지및 이의제조방법을개시한다. 본발명에따르는전해질수용액의염료감응태양전지및 이의제조방법에의하면, 살리실릭기를가진염료가결합된광전극의음극계전극을준비하는단계와, 상기음극계전극에전해질수용액을도포하는단계및 백금상대전극의양극계전극을준비하여상기음극계전극과대향하고밀봉하는단계를포함하는것을특징으로하는데, 이에의할때, 전해질수용액에서용해되지아니하여내구성이우수하고, 물과친화적이어서친환경적이며, 외부에서침투하는수분에안정적이고, 특히장기안정성이우수하다.
Abstract translation: 公开了具有电解质溶液的染料敏化太阳能电池及其制造方法。 根据本发明的用电解质溶液制造染料敏化太阳能电池的方法包括制备具有水杨基的光电极的负极的步骤; 将电解质溶液施加到负极上; 并准备铂对电极的正电极，将正极与负电极对置并密封正极，由此制造不溶于电解液中的染料敏化太阳能电池以具有优异的耐久性， 环保，对外界渗透的水分稳定，长期稳定性特别优异。
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Patent Agency Ranking
公开(公告)号：KR101483430B1
公开(公告)日：2015-01-19
申请号：KR1020140099079
申请日：2014-08-01
Applicant: 한국에너지기술연구원
IPC: B01J23/745 , B01J37/08 , B01J37/16
Abstract: 본 발명은 철계 촉매 및 이의 제조방법에 관한 것으로, 상기 철계 촉매는 철수산화물, 철산화물 및 철탄화물을 포함하고, 상기 철계 촉매에 함유된 철 원자수 100%에 대하여, 상기 철수산화물에 함유된 철 원자수 48 내지 57%, 상기 철산화물에 함유된 철 원자수 18 내지 29%, 상기 철탄화물에 함유된 철 원자수 14 내지 34%를 포함할 수 있다.
본 발명에 의하면, 철계 촉매의 상분율을 최적으로 조절함으로써, 탄소 수가 5 이상인 탄화수소의 생산성을 높이고, CO
2 의 선택도 및 CH
4 , C
2 -C
4 탄화수소의 선택도를 낮출 수 있어 피셔-트롭쉬 합성 공정에 유용하게 적용할 수 있다.Abstract translation: 铁基催化剂及其制造方法技术领域本发明涉及铁系催化剂及其制造方法，其中，所述铁系催化剂含有：氢氧化铁，氧化铁和碳化铁，可以含有氢氧化铁中含有的铁原子数的48〜57％，18〜 相对于铁基催化剂中含有的100％的铁原子，铁氧化物中含有的铁原子中含有29％的铁原子和铁碳原子中含有14〜34％的铁原子。 本发明可以有效地应用于费 - 托合成方法，因为可以提高具有五个或更多个碳原子的烃的生产率，并且可以通过最佳地调节CO 2的选择性和CH_4和C_2-C_4烃的选择性来降低 根据本发明的铁基催化剂的相分数。
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公开(公告)号：KR1020140114633A
公开(公告)日：2014-09-29
申请号：KR1020130029169
申请日：2013-03-19
Applicant: 한국에너지기술연구원
CPC classification number: B01J23/78 , B01J27/22 , B01J37/16 , B01J2523/00 , C10G2/332 , B01J2523/13 , B01J2523/17 , B01J2523/41 , B01J2523/842
Abstract: The present invention relates to a method for producing a hydrocarbon compound using Fischer-Tropsch synthesis and a hydrocarbon compound produced through the same. The method of the present invention comprises: a reducing step of feeding a first gas including CO_2 and CO in a first reactor in which an iron catalyst is filled in order to be reduced; and a producing step of producing a hydrocarbon compound by reacting a second gas including H_2 and CO in a second reactor filled with the iron catalyst reduced in the reducing step. Accordingly, the reducing properties of the iron catalyst are improved so that the productivity of C5 or more hydrocarbon is increased and the selectivity of Co_2 and the selectivity of CH_4, C_2-C_4 hydrocarbon can be decreased.
Abstract translation: 本发明涉及使用费 - 托合成法制备烃化合物的方法和通过其制备的烃化合物。 本发明的方法包括：在第一反应器中加入包含CO_2和CO的第一气体以在其中填充铁催化剂以便还原的还原步骤; 以及通过在填充有还原步骤中还原的铁催化剂的第二反应器中使包含H 2和CO的第二气体反应来生产烃化合物的制备步骤。 因此，提高了铁催化剂的还原性能，提高了C5以上烃的生产率，可以降低Co_2的选择性和CH_4，C_2-C_4烃的选择性。
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38.发明授权선택적 합성오일 생성을 위한 피셔-트롭쉬 반응용 금속 구조체 기반 코발트계 촉매 및 그 제조 방법, 이 금속 구조체 기반 코발트계 촉매를 이용한 선택적 합성 오일 제조 방법 有权用于通过FISCHER-TROPSCH合成反应选择性合成合成油的金属泡沫结构的钴催化剂及其制备方法，使用钴催化剂在金属泡沫结构上的合成油的制造方法
公开(公告)号：KR101373823B1
公开(公告)日：2014-03-11
申请号：KR1020130126228
申请日：2013-10-22
Applicant: 한국에너지기술연구원
CPC classification number: B01J31/28 , B01J21/04 , B01J21/08 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/005 , B01J29/0333 , B01J29/06 , B01J29/40 , B01J29/46 , B01J31/06 , B01J35/0006 , B01J35/0013 , B01J35/006 , B01J35/04 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1076 , B01J37/0018 , B01J37/0045 , B01J37/0201 , B01J37/0217 , B01J37/0219 , B01J37/0225 , B01J37/023 , B01J37/0232 , B01J37/0244 , B01J37/0246 , B01J37/088 , B01J37/14 , B01J2229/186 , B01J2229/20 , B01J2231/62 , B01J2531/005 , C10G2/331 , C10G2400/22
Abstract: The present invention relates to a cobalt-based catalyst on the basis of a metal structure for a Fischer-Tropsch reaction for manufacturing selective synthetic oil, a manufacturing method thereof, and a method for manufacturing selective synthetic oil using the cobalt-based catalyst on the basis of the metal structure. The purpose of the present invention is to provide: the cobalt-based catalyst on the basis of the metal structure, capable of thinly and uniformly coating a catalytic sol pulverized after mixing zeolite, cobalt and a support on the surface of the metal structure so as to prevent heating during the Fischer-Tropsch reaction, and, at the same time, to allow selective production of the synthetic oil having carbon chains shorter than a wax region using a spray coating method; the manufacturing method thereof; and the method for manufacturing selective synthetic oil. The present invention is characterized by inventing a method for manufacturing the cobalt-based catalyst on the basis of the metal structure for a Fischer-Tropsch reaction for manufacturing selective synthetic oil, the catalyst thereof, and the synthetic oil manufactured the same, wherein the method comprises the steps of: manufacturing cobalt-oxide/metal-oxide support catalyst powder by burning mixed powder obtained through melting and impregnation between cobalt hydrate salt and a metal-oxide support; manufacturing hybrid catalyst powder by mixing the cobalt-oxide/metal-oxide support catalyst powder and zeolite powder; manufacturing a hybrid catalyst sol through pulverization after mixing the hybrid catalyst powder with an organic binder and an inorganic binder; coating the metal structure the surface of which is treated with alumina through the ALD process by spraying the hybrid catalyst sol; and performing a heat treatment on the metal structure on which the hybrid catalyst sol is sprayed. [Reference numerals] (S100) Step of manufacturing cobalt-oxide/metal-oxide support catalyst powder by burning mixed powder obtained through melting and impregnation between cobalt hydrate salt and a metal-oxide support; (S200) Step of manufacturing hybrid catalyst powder by mixing the cobalt-oxide/metal-oxide support catalyst powder and zeolite powder; (S300) Step of manufacturing a hybrid catalyst sol through pulverization after mixing the hybrid catalyst powder with an organic binder and an inorganic binder; (S400) Step of coating a metal structure the surface of which is treated with alumina through an atomic layer deposition by spraying the hybrid catalyst sol; (S500) Step of performing a heat treatment on the metal structure on which the hybrid catalyst sol is sprayed
Abstract translation: 本发明涉及一种基于用于制造选择性合成油的费 - 托反应的金属结构的钴基催化剂及其制备方法，以及使用该钴基催化剂的选择性合成油的制备方法 金属结构的基础。 本发明的目的是提供：基于金属结构的钴基催化剂，能够在将金属结构的表面上混合沸石，钴和载体之后，粉碎的催化剂溶胶薄均匀地涂覆，以便 以防止费 - 托反应期间的加热，同时使用喷雾法选择性地生产比蜡区短的碳链的合成油; 其制造方法; 和选择性合成油的制造方法。 本发明的特征在于，基于用于制造选择性合成油的费 - 托反应的金属结构，其催化剂和制造该钴基催化剂的合成油，制造该钴基催化剂的方法，其中该方法 包括以下步骤：通过燃烧通过在水合钴盐和金属氧化物载体之间熔融和浸渍获得的混合粉末来制备氧化钴/金属氧化物载体催化剂粉末; 通过混合氧化钴/金属氧化物载体催化剂粉末和沸石粉末制造混合催化剂粉末; 在混合催化剂粉末与有机粘合剂和无机粘合剂混合后，通过粉碎制造混合催化剂溶胶; 通过喷涂混合催化剂溶胶，通过ALD工艺涂覆其表面用氧化铝处理的金属结构; 对其上喷涂有混合催化剂溶胶的金属结构进行热处理。 （附图标记）（S100）通过在钴酸水合物盐和金属氧化物载体之间通过熔融和浸渍获得的混合粉末来制造氧化钴/金属氧化物载体催化剂粉末的步骤; （S200）通过将氧化钴/金属氧化物载体催化剂粉末和沸石粉末混合来制造混合催化剂粉末的工序; （S300）将混合催化剂粉末与有机粘合剂和无机粘合剂混合后，通过粉碎制造混合催化剂溶胶的工序; （S400）通过喷雾混合催化剂溶胶，通过原子层沉积涂覆其表面用氧化铝处理的金属结构的步骤; （S500）对喷涂有混合催化剂溶胶的金属结构进行热处理的工序
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公开(公告)号：KR101945434B1
公开(公告)日：2019-02-08
申请号：KR1020160158871
申请日：2016-11-28
Applicant: 한국에너지기술연구원
IPC: G02F1/15 , H01L31/042 , H01L31/0224 , H01B5/14 , H01B1/02 , C09K9/02
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