公开(公告)号：WO2022084033A1

公开(公告)日：2022-04-28

申请号：PCT/EP2021/077492

申请日：2021-10-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： CIACCIA, Eleonora ,  CIARAFONI, Marco ,  CATHELIN, Caroline ,  DE CAPUA, Alberta ,  PRINI, Giansiro ,  PO, Daniele ,  CAPUTO, Tiziana ,  PANTALEONI, Roberto ,  DI CAPUA, Alessia

IPC: C08L23/14 ,  C08F210/06 ,  C08F2/00 ,  C08L23/12

Abstract: A polypropylene composition comprising: A) from 76 wt% to 95 wt% of a propylene homopolymer having: - fraction soluble in xylene at 25°C comprised between 2.0 wt% and 4.5 wt%; - melt flow rate (MFR L according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) ranging from 60.0 to 110.0 g/10 min; B) from 5 wt% to 24 wt%, of a copolymer of propylene and ethylene containing from 75 wt% to 90.0 wt%, of ethylene derived units; wherein in the polypropylene composition: the content of ethylene derived units in the fraction soluble in xylene at 25°C is lower than - the content of ethylene derived units of component B) and ranges from 51.0 wt% to 74.0 wt%, the polypropylene composition has at least two melting points, the higher ranging from 156.0 °C to 166.0 °C and the lower ranging from 90.0 °C to 125.0°C; and the sum of the amounts of component A) and B) being 100 wt%.

公开(公告)号：WO2022002514A1

公开(公告)日：2022-01-06

申请号：PCT/EP2021/064705

申请日：2021-06-01

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FERRARO, Gianpiero ,  CAVALIERI, Claudio ,  CATHELIN, Caroline ,  CIACCIA, Eleonora ,  CIARAFONI, Marco ,  MONTALETTI, Ambra ,  DE CAPUA, Alberta ,  PANTALEONI, Roberto ,  CAPUTO, Tiziana ,  PRINI, Giansiro ,  NARDIN, Alberto

IPC: C08L23/14 ,  C08L2203/14 ,  C08L23/142 ,  C08L2308/00 ,  C08L2314/02

Abstract: A polypropylene composition comprising: from 70 wt% to 90 wt% of a propylene 1-hexene copolymer containing from 1.0 wt% to 5.0 wt% of 1-hexene derived units and a polydispersity index (PI) comprised between 9.2 and 21.3; from 10 wt% to 30 wt%, of a copolymer of propylene and ethylene containing from 45.0 wt% to 65.0 wt%, of ethylene derived units; the sum A) + B) being 100.

公开(公告)号：WO2019166223A1

公开(公告)日：2019-09-06

申请号：PCT/EP2019/053512

申请日：2019-02-13

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MASSARI, Paola ,  FELISATI, Andrea ,  IZZI, Marco ,  CAVALIERI, Claudio ,  TARTARI, Davide ,  CAMURATI, Isabella Maria Vittoria ,  CAPUTO, Tiziana

IPC: C08L23/12 ,  B32B27/32

Abstract: A multilayer film comprising at least one core layer comprising a polypropylene composition comprising: A) From 90 wt% to 50 wt%; of a propylene homopolymer; B) From 10 wt% to 50 wt%; of a propylene ethylene copolymer having: i) xylene soluble fraction at 25°C ranging from 14 wt% to 27 wt% ii) intrinsic viscosity of the fraction soluble in xylene at 25°C ranging from 1.0 to 2.4 dl/g; iii) melt flow rate ranging from 1.0 g/10 min to 4.0 g/10 min; iv) an ethylene content ranging from 5.0 wt% to 12.0 wt% the sum of A) and B) being 100wt%.

公开(公告)号：WO2018134007A1

公开(公告)日：2018-07-26

申请号：PCT/EP2017/082977

申请日：2017-12-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： BALESTRA, Enrico ,  CAPUTO, Tiziana ,  COVEZZI, Massimo ,  DORINI, Maurizio ,  MAZZUCCO, Antonio ,  MEI, Gabriele ,  RINALDI, Riccardo

IPC: B01J8/18 ,  B01J8/24 ,  C08F2/00 ,  C08F2/01 ,  C08F10/00

Abstract: A fluid is fed into a polymer bed of a fluidized bed gas phase polymerization reactor by introducing it into the polymer bed through a distributor protruding into the fluidized bed zone of the reactor and terminating with a discharge end positioned so that the following equation is fulfilled: d/D > 0.002 wherein d is the distance of the distributor's discharge end from the wall of the reactor, and D is the diameter of the reactor in the fluidized bed zone.

公开(公告)号：WO2016146578A1

公开(公告)日：2016-09-22

申请号：PCT/EP2016/055445

申请日：2016-03-14

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MARZOLLA, Roberta ,  MASSARI, Paola ,  MARTINI, Nicoletta ,  CIARAFONI, Marco ,  CAPUTO, Tiziana

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/08 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/651 ,  C08F4/6545 ,  C08F4/6465 ,  C08F2/001

Abstract: A propylene, ethylene, 1-butene terpolymer containing: a) from 1.8 wt% to 5.9 wt% of ethylene derived units; b) from 2.0 wt% to 4.5 wt% of 1 butene derived units; wherein: i) the ratio C2wt%/C4wt% ranges from 0.9 to 1.3; wherein C2wt% is the weight per cent of ethylene derived units and C4wt% is the weight per cent of 1-butene derived units; ii) the Melt flow rate ranges from 1.0 to 30.0 g/10 min, iii) the xylene soluble fraction at 25°C is comprised between 10 wt% and 30 wt%.

Abstract translation: 一种丙烯，乙烯，1-丁烯三元共聚物，其含有：a）1.8重量％至5.9重量％的乙烯衍生单元; b）2.0重量％至4.5重量％的1-丁烯衍生单元; 其中：i）C2wt％/ C4wt％的比例为0.9-1.3; 其中C2wt％是乙烯衍生单元的重量百分数，C4wt％是1-丁烯衍生单元的重量百分数; ii）熔体流动速率范围为1.0至30.0g / 10min，iii）25℃下的二甲苯可溶级分为10重量％至30重量％。

公开(公告)号：WO2015086213A1

公开(公告)日：2015-06-18

申请号：PCT/EP2014/072985

申请日：2014-10-27

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MARZOLLA, Roberta ,  CAPUTO, Tiziana

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  B32B27/32 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/08 ,  C08F2500/03 ,  C08F2500/26

Abstract: A propylene ethylene 1-butene terpolymer wherein: (i) the content of ethylene derived units ranges from 1.1 wt% to 1.9 wt%, (ii) the content of 1-butene ranges from 5.0 wt% to 9.0 wt%, (iii) the melting point (Tm) of the non nucleated terpolymer ranges from 125°C to 137°C; (iv) the xylene soluble fraction at 25°C is lower than 8.0 wt%.

Abstract translation: 丙烯乙烯-1-丁烯三元共聚物，其中：（i）乙烯衍生单元的含量范围为1.1重量％至1.9重量％，（ii）1-丁烯的含量为5.0重量％至9.0重量％，（iii） 非成核三元共聚物的熔点（Tm）为125〜137℃; （iv）25℃的二甲苯可溶成分低于8.0重量％。

公开(公告)号：WO2014198459A1

公开(公告)日：2014-12-18

申请号：PCT/EP2014/059201

申请日：2014-05-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： DESTRO, Mara ,  CIARAFONI, Marco ,  MASSARI, Paola ,  CAPUTO, Tiziana ,  BÖHM, Thomas

IPC: B65D1/02 ,  C08F210/06

CPC classification number: C08F210/06 ,  B65D65/38 ,  C08F210/02 ,  C08F210/08 ,  C08F2500/12

Abstract: A container comprising a propylene, ethylene, 1-butene terpolymer wherein in the terpolymer: i) the content of ethylene derived units ranges from 0.5 wt% to 1.8 wt%; ii) the content of 1-butene derived units ranges from 3.5 wt% to 6.5 wt%; iii) the ratio C2wt%/C4wt% ranges from 0.12 to 0.22; wherein C2wt% is the weight per cent of ethylene derived units and C4wt% is the weight per cent of 1-butene derived units; iv) the total content of ethylene and 1-butene derived units is comprised between 4.2 wt% and 7.5 wt%; v) the melt flow rate,MFR measured according to ISO 1133,230° C, 2.16 kg ranges from 20 to 80 g/10 min; vi) the xylene soluble fraction at 25°C is lower than 7.0 wt%; vii) the melting point is higher than 140°C.

Abstract translation: 一种包含丙烯，乙烯，1-丁烯三元共聚物的容器，其中在三元共聚物中：i）乙烯衍生单元的含量为0.5重量％至1.8重量％; ii）1-丁烯衍生单元的含量为3.5wt％至6.5wt％; iii）C2wt％/ C4wt％的比率范围为0.12至0.22; 其中C2wt％是乙烯衍生单元的重量百分数，C4wt％是1-丁烯衍生单元的重量百分数; iv）乙烯和1-丁烯衍生单元的总含量在4.2wt％和7.5wt％之间; v）熔体流动速率，根据ISO 1133,230℃测量的MFR，2.16kg，范围为20至80g / 10min; vi）25℃的二甲苯可溶级分低于7.0wt％; vii）熔点高于140℃。

公开(公告)号：WO2014090552A1

公开(公告)日：2014-06-19

申请号：PCT/EP2013/074555

申请日：2013-11-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GALVAN, Monica ,  NEUMANN, Andreas ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  COLLINA, Gianni ,  CAPUTO, Tiziana ,  SQUARZONI, Stefano ,  MAZZUCCO, Antonio

IPC: B32B1/08 ,  B32B27/32 ,  C08F210/06 ,  C08J5/18 ,  F16L9/12 ,  C08F10/00

CPC classification number: C08F10/14 ,  B32B1/08 ,  B32B27/08 ,  B32B27/32 ,  B32B2307/558 ,  B32B2597/00 ,  C08F210/06 ,  C08J5/18 ,  C08J2323/14 ,  C08L2314/02 ,  F16L9/12 ,  C08F4/651 ,  C08F2/001 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/21 ,  C08F4/6492 ,  C08F4/6548

Abstract: A terpolymer containing propylene, ethylene and 1-hexene obtainable by the step of copolymerizing propylene, ethylene and 1-hexene in the presence of a catalyst system comprising the product obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum hydrocarbyl compound, and (c) optionally an external electron donor compound, wherein in the terpolymer (i) the content of 1-hexene derived units ranges from 0.5 to 5.0 wt%; (ii) the content of ethylene derived units is higher than 1.4 t% and fulfils the following relation (1): C2

Abstract translation: 含有丙烯，乙烯和1-己烯的三元共聚物可通过在催化剂体系存在下共聚合丙烯，乙烯和1-己烯的步骤获得，所述催化剂体系包含通过使以下组分接触获得的产物：（a）包含镁的固体催化剂组分 卤化物，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种以相对于供体总量为40至90摩尔％的量存在，并且选自琥珀酸盐和另一种 选自1,3二醚，（b）铝烃基化合物和（c）任选的外电子给体化合物，其中在三元共聚物（i）中，1-己烯衍生单元的含量为0.5-5.0重量％; （ii）乙烯衍生单元的含量高于1.4t％，满足以下关系（1）：C2

公开(公告)号：WO2013083576A1

公开(公告)日：2013-06-13

申请号：PCT/EP2012/074391

申请日：2012-12-05

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MARZOLLA, Roberta ,  GALVAN, Monica ,  CAPUTO, Tiziana

IPC: C08F2/00 ,  C08F2/34 ,  C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/08 ,  C08F210/16 ,  C08F2500/26 ,  C08F2/001 ,  C08F4/6492

Abstract: A propylene ethylene 1-butene terpolymer wherein: (i) the content of ethylene derived units ranges from 0.5 wt% to 2.0 wt%, (ii) the content of 1-butene rangesfrom 5.0 wt% to 8.0 wt%, (iii) the melting point (Tm) ranges from 136°C to 148°C; wherein said terpolymer is obtained with a polymerization process carried out in a gas-phase polymerization reactor comprising at least two interconnected polymerization zones.

Abstract translation: 丙烯乙烯-1-丁烯三元共聚物，其中：（i）乙烯衍生单元的含量为0.5重量％至2.0重量％，（ii）1-丁烯的含量为5.0重量％至8.0重量％，（iii） 熔点（Tm）范围为136℃至148℃; 其中所述三元共聚物通过在包含至少两个互连聚合区的气相聚合反应器中进行的聚合方法获得。

公开(公告)号：WO2011080128A1

公开(公告)日：2011-07-07

申请号：PCT/EP2010/070122

申请日：2010-12-17

Applicant: Basell Poliolefine Italia s.r.l. ,  CAPUTO, Tiziana ,  GALVAN, Monica ,  MAZZUCCO, Antonio ,  MASSARI, Paola

Inventor： CAPUTO, Tiziana ,  GALVAN, Monica ,  MAZZUCCO, Antonio ,  MASSARI, Paola

IPC: C08F10/00 ,  C08J5/10 ,  C08K5/00

CPC classification number: C08J7/123 ,  C08F10/00 ,  C08F210/06 ,  C08J2323/02 ,  C08K5/0075 ,  C08K5/1515 ,  C08F210/16 ,  C08F2500/26 ,  C08F2/34 ,  C08F2/005

Abstract: A process for the production of a corona-treated polyolefin film comprising the gas-phase polymerization of one or more α-olefins in the presence of a polymerization catalyst and an antistatic agent having a molecular weight higher than 500, said antistatic agent being fed at any stage of the polymerization process in an amount from 30 to 500 ppm weight based on the weight of the produced polyolefin.

Abstract translation: 一种电晕处理的聚烯烃膜的制造方法，包括在聚合催化剂和分子量高于500的抗静电剂的存在下，一种或多种α-烯烃的气相聚合，所述抗静电剂以 基于所制备的聚烯烃的重量，聚合过程的任何阶段的量为30至500ppm重量。